气液固三相相平衡热力学模型与计算方法

原油中含有大量的高分子有机固相物质，因此，要准确地描述油气体系相平衡，必须对气液固三相相平衡进行研究，在对高分子有机烃类沥青沉降机理有了一定的认识的基础上，提出了大的交互作用系数，可以描述沥青与原油中轻质不相容性的程度。根据对油气烃类混合物体系的一般性认识与提出的沥青组分特征化方法，导出了与之相应的有其自身特殊性的气液沥青三相相平衡物料平衡方程组，用考虑沥青沉降三相闪蒸数值算法，对沥青沉降进行有效的理化模拟计算，此外，结合实例分析，给出了沥青质参考逸度的计算，饱和压力和沉降量的拟合方法。     

Separating n-alkane mixtures by exploiting differences in the adsorption capacity within cages of CHA, AFX and ERI zeolites

The saturation capacity of n-alkanes in CHA, AFX and ERI zeolites, that consist of cages separated by windows, decreases with increasing carbon number. The major aim of the present communication is to demonstrate the possibility of separating n-alkane mixtures relying on differences in saturation capacities. To investigate this possibility, Configurational-Bias Monte Carlo simulations for adsorption of C3–nC6, nC4–nC6, and nC5–nC6 mixtures in CHA, AFX and ERI were carried out for equimolar bulk fluid phase. These mixture simulations show that for operation at fluid phase fugacities below about 1 MPa, the adsorbed phase in equilibrium with the bulk vapor phase is predominantly the alkane with the longer chain length, i.e. nC6. However, for operation at pressures in excess of 1 MPa, the adsorbed phase in equilibrium with the bulk liquid phase is richer in the component with the smaller chain length. In some cases, the nC6 is practically excluded from the zeolite.     

Numerical study on PEMFC’s geometrical parameters under different humidifying conditions

Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance.     

On the Performance of Ozone Generators Working with Dielectric Barrier Discharges

The parameters, which determine the performance of ozone generators, are efficiency and maximum ozone concentration. The efficiency from oxygen has been found to be nearly independent on the kind of barrier discharge arrangement (volume, surface, coplanar), while the ozone concentration saturation level depends on the specific design of the generator. These phenomena are explained with features of the discharge process and the properties of chemical reactions, respectively. The importance of a limit in the energy density of the discharge is highlighted.     

注气井井筒结垢预测研究

在油田开发过程中,油、气、水和泥浆在地层或管道中流动,当达到一定条件时,油垢、水垢或泥垢便会产生。在实际生产过程中,油垢和泥垢通常伴随着水垢而生成,所以对水垢结垢趋势的预测研究显得至关重要。介绍了Oddo-Tomos饱和指数法的理论预测模型,以及在生产过程中利用Oddo-Tomos饱和指数法预测油田结垢趋势的方法,阐述并分析了油田结垢对油田开采的影响。研究结果可为下一步的生产作业提供理论依据。     

基于切换模型的无人直升机偏航通道系统辨识方法?

针对直升机偏航通道中舵机控制量的饱和非线性问题,提出基于切换模型的无人直升机偏航通道系统辨识方法。首先分析无人机偏航通道的特征,建立包含饱和单元的切换模型。其次通过扫频实验采集辨识所需的数据,并在频域下采用遗传算法辨识得到切换模型的所有参数。再根据实验数据分析辨识模型的残差序列,得到系统的残差模型,并利用该残差模型修正辨识得到的无人机偏航通道模型,进一步提高模型的准确度。最后通过实验数据分析文中模型的准确性,并利用该模型设计无人机飞行控制器。实验结果也证明模型的有效性。     

基于粒子群优化的交叉口公交优先控制研究

以四相位单交叉口为研究对象,计算推导交叉口的延误计算模型,包括公交优先相位减少的延误以及非公交优先相位增加的延误。模型以减少人总延误最大为控制目标,采用粒子群算法优化求解,从而得到最优的绿信比,并通过仿真算例验证算法的有效性。     

Stability analysis of a class of digital filters utilizing single saturation nonlinearity

A novel criterion for the global asymptotic stability of a class of digital filters utilizing single saturation nonlinearity is presented. An example showing the effectiveness of the present criterion is given.     

Saturation in multivariate simultaneous approximation

In this paper we present a new result on the saturation of sequences of linear operators in a multivariate and simultaneous setting. Specifically, a small o saturation result is obtained for the partial derivatives of the classical Bernstein bivariate operators on the unit simplex. Solutions of boundary value problems for certain partial differential equations of elliptic type play an important role.     

A Reducing Saturation Method for DMSP/OLS Nighttime Light Image Combining Landsat Data

Defense Meteorological Satellite Program/Operational Linescan System(DMSP/OLS)is one of the data sources,which can effectively reflect human activities of earth surfaces.During the past decade,DMSP/OLS had been extensively applied in urban extraction and extension study.In the recent year,the Vegetation Adjusted NTL Urban Index(VANUI)has been proposed and had proven to be a simple,convenient and high precision desaturation index to extract urban area.In VANUI method,negative values of imagery were directly eliminated to remove water body,which not only removed the bridge over the river and building but also extracted the aquaculture areas along the coast,thus,this method reduced the extraction accuracy.This paper proposed a new index\|RwNTLI,combining DMSP/OLS nighttime light data and the vegetation index (NDVI)and water index (MNDWI)which were constructed by Landsat data.In this study,Guangzhou was taken as experimental area.By comparing the VANUI index with the ability to identify ground objects as well as the ability to alleviate saturation regions,the result showed RwNTLI index could effectively solve the problem of VANUI as well as eliminate saturation effect of nighttime light imagery.Among them,the correlation between RwNTLI index and RCNTL is better than that of VANUI index and RCNTL.Therefore,RwNTLI index is a simple and effective index of luminous desaturation,which has more advantages than VANUI index in describing the characteristics of night lights of urban areas and will have higher application value in urban built\|up areas in the future.