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Ionic liquids (ILs), also referred to as molten salts, have found application as electrolytes for batteries and super-capacitors,
in electroplating baths, as designer solvents, and as reaction media. A few of the desired properties of a super-capacitor
electrolyte are nonflammability, thermal stability, and electrochemical stability. ILs containing aromatic cations have been
shown to have low viscosity which results in a high electrochemical conductivity. There is a delicate balance between increasing
the thermal stability, or decreasing the melting point, and increasing the electrochemical conductivity of the IL. This study
focuses on pyridinium fluorohydrogenate, [pyridine · H+][H2F3]−. Pyridinium fluorohydrogenate has been synthesized by the reaction of pyridine and anhydrous hydrofluoric acid. This IL has
a relatively high electrical conductivity (~98 mS · cm−1 at 23 °C), a wide electrochemical window, and a boiling point of 186 °C. A stable gel can also be formed by combining [pyridine · H+][H2F3]− and a super absorbent polymer such as polyacrylic acid. The gel adds mechanical stability to the matrix while not greatly
affecting the conductivity of the IL. 相似文献
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《International Journal of Hydrogen Energy》2023,48(75):29119-29141
Current work presents the first report on the modification of zirconia (ZrO2) by doping it with the lanthanides oxides i.e. [samarium, europium, and thulium] forming a [Sm/Eu/Tm] co-doped ZrO2 system. Lanthanide doping tailored the structure of host material by causing considerable bandgap energy shrinkage from 4.04 to 3.57 eV and reduction in the crystallite size from 67.92 to 45.23 nm. Profound electro-catalytic potential was reflected analyzed via linear sweep voltammetry showing the excellent of developed catalytic towards H2 evolution with lower overpotential i.e. 133 mV and Tafel slope of 119.3 mV dec−1. While for O2 evolution, the electro-catalyst succeeded in gaining overpotential and Tafel slope values of 310 mV and 294.8 mV dec−1, respectively. With such values, this material has surpassed the conventional electro-catalysts and is proved to be an excellent hydrogen producing electro-catalyst. The electrical charge storage potential was analyzed for [Sm/Eu/Tm] co-doped ZrO2 decorated nickel foam electrode for development into a super-capacitor. This electrode was impressively stable for 10 cycles after 20 days checked through cyclic voltammetry. Furthermore, an augmented specific capacitance of 447 F g−1 was achieved by the doped electrode when compared with the pristine one approaching 83.69 F g−1. The electrical energy storage capacity of [Sm/Eu/Tm] co-doped ZrO2 is even higher than the conventionally used metal oxides. In terms of the interfacial electrode-electrolyte, electrochemical impedance spectroscopy was done expressing the excellent ionic diffusion and electrochemically active sites for [Sm/Eu/Tm] co-doped ZrO2 electrode with minimal resistance. The developed doped system was used a spacer layer in a cesium lead halide perovskite solar cells having planar architecture. The spacer layer containing solar cell device succeeded in gaining a power conversion efficiency of 16.31% and a fill factor of 78% evaluated via photo-current measurements carried out under artificial solar irradiance. The impressively higher fill factor shows the effective passivation and scaffolding by the [Sm/Eu/Tm] co-doped ZrO2. The associated device was also marked by negligible hysteresis. Chrono-potentiometry and chrono-amperometry expressed commendable accelerated service lives for 100 min inside an electrolyte. The lanthanide co-doped ZrO2 is an effective material for the utilization in energy systems associated with the electro-catalysis of water, charge storage electrode for super-capacitors, and photovoltaic solar to electrical energy conversion. 相似文献
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超级电容器是近年出现的一种介于电池与电解电容器之间的新型绿色储能元件,具有电容器功率密度高、寿命长、无需维护及充放电迅速等特性。为了推动超级电容器在电力控制系统的应用范围,通过工程实践介绍超级电容器在FTU控制系统中的应用原理和实际效果。 相似文献
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城轨车辆车载超级电容储能系统主要参数的选择 总被引:1,自引:0,他引:1
为了给城轨车辆车载超级电容储能系统主要参数的选择提供理论依据,本文将建立超级电容储能系统的仿真模型,选择超级电容储能系统的主要参数。然后通过matlab/simulink软件仿真,验证参数选择的合理性。 相似文献
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Dale A.C. BrownsonDimitrios K. Kampouris Craig E. Banks 《Journal of power sources》2011,196(11):4873-4885
Energy production and storage are both critical research domains where increasing demands for the improved performance of energy devices and the requirement for greener energy resources constitute immense research interest. Graphene has incurred intense interest since its freestanding form was isolated in 2004, and with the vast array of unique and highly desirable electrochemical properties it offers, comes the most promising prospects when implementation within areas of energy research is sought. We present a review of the current literature concerning the electrochemical application of graphene in energy storage/generation devices, starting with its use as a super-capacitor through to applications in batteries and fuel cells, depicting graphene's utilisation in this technologically important field. 相似文献
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Mairaj ud din Mufti Shameem Ahmad LoneShiekh Javed Iqbal Muzzafar AhmadMudasir Ismail 《Electric Power Systems Research》2009
A fuzzy-logic controlled super-capacitor bank (SCB) for improved load frequency control (LFC) of an interconnected power system is proposed, in this paper. The super-capacitor bank in each control area is interfaced with the area control bus through a power conversion system (PCS) comprising of a voltage source converter (VSC) and a buck-boost chopper. The fuzzy controller for SCB is designed in such a way that the effects of load disturbances are rejected on a continuous basis. Necessary models are developed and control and implementation aspects are presented in a detailed manner. Time domain simulations are carried out to demonstrate the effectiveness of the proposed scheme. The performance of the resulting power system under realistic situation is investigated by including the effects of generation rate constraint (GRC) and governor dead band (DB) in the simulation studies. 相似文献