全文获取类型
收费全文 | 8748篇 |
免费 | 931篇 |
国内免费 | 171篇 |
专业分类
电工技术 | 420篇 |
综合类 | 467篇 |
化学工业 | 4428篇 |
金属工艺 | 285篇 |
机械仪表 | 135篇 |
建筑科学 | 505篇 |
矿业工程 | 180篇 |
能源动力 | 1140篇 |
轻工业 | 644篇 |
水利工程 | 6篇 |
石油天然气 | 175篇 |
武器工业 | 70篇 |
无线电 | 131篇 |
一般工业技术 | 735篇 |
冶金工业 | 346篇 |
原子能技术 | 17篇 |
自动化技术 | 166篇 |
出版年
2024年 | 62篇 |
2023年 | 123篇 |
2022年 | 239篇 |
2021年 | 367篇 |
2020年 | 352篇 |
2019年 | 290篇 |
2018年 | 226篇 |
2017年 | 334篇 |
2016年 | 276篇 |
2015年 | 291篇 |
2014年 | 535篇 |
2013年 | 525篇 |
2012年 | 622篇 |
2011年 | 696篇 |
2010年 | 489篇 |
2009年 | 490篇 |
2008年 | 449篇 |
2007年 | 591篇 |
2006年 | 503篇 |
2005年 | 418篇 |
2004年 | 366篇 |
2003年 | 305篇 |
2002年 | 237篇 |
2001年 | 219篇 |
2000年 | 203篇 |
1999年 | 156篇 |
1998年 | 123篇 |
1997年 | 87篇 |
1996年 | 69篇 |
1995年 | 38篇 |
1994年 | 35篇 |
1993年 | 37篇 |
1992年 | 33篇 |
1991年 | 9篇 |
1990年 | 9篇 |
1989年 | 14篇 |
1988年 | 8篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1981年 | 3篇 |
1951年 | 5篇 |
排序方式: 共有9850条查询结果,搜索用时 15 毫秒
1.
Polyaryloxydiphenylsilanes were prepared from phosphorus‐containing diols and diphenydichlorolsilane through solution polymerization. With a stoichiometric imbalance in feed monomers, the resulting polymers exhibited moderate melting points and good processing properties. The polymers prepared showed initial decomposition temperatures above 340 °C, excellent thermal stability, high char yields at 850 °C and very high limited oxygen index values of 56–59. The polymers' char yields and their (P + Si) contents showed linear relationships. © 2003 Society of Chemical Industry 相似文献
2.
This paper presents the current understanding of the flame retardant mechanism of Casico?. The study includes the flame retardant effect of each individual component: ethylene–acrylate copolymer, chalk and silicone elastomer, as well as the formation of an intumescent structure during heating. The flame retardant properties were investigated by cone calorimetry and oxygen index tests. To obtain insight into the flame retardant mechanism, heat treatment under different conditions has also been performed. The results indicate that the flame retardant mechanism of Casico is complex and is related to a number of reactions, e.g. ester pyrolysis of acrylate groups, formation of carbon dioxide by reaction between carboxylic acid and chalk, ionomer formation and formation of an intumescent structure stabilized by a protecting char. Special emphasis is given to the formation of the intumescent structure and its molecular structure as evaluated from 13C MAS‐NMR and 29Si MAS‐NMR, ESCA and XRD analysis. After treatment at 500°C the intumescent structure consists mainly of silicon oxides and calcium carbonate and after treatment at 1000°C the intumescent structure consists of calcium silicate, calcium oxide and calcium hydroxide. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
3.
Atilla Bilgin 《国际能源研究杂志》2002,26(11):987-1000
Flame front surface area and enflamed volume (the volume enclosed with flame front) is theoretically analysed for a spark‐ignition engine, having cylindrical disc‐shaped combustion chamber with two spark plugs located axisymmetrically on cylinder head, between cylinder axis and cylinder wall. Spherical flame front assumption is used. A computer code is developed based on purely geometric consideration of the flame development process in combustion chamber, and is used to investigate the effects of variations of spark plugs' locations on geometric features of the flame front. A comparison has also been made with a spark‐ignition engine having one spark plug at the same location. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
4.
介绍了一种新型双族流平焰烧嘴的设计思路、结构参数及工业试验结果。其结构特点是每个部件都易装易卸,其煤气旋流器的位置可根据煤气压力变化进行调节,无需稳焰器就可保证煤气压力在较大范围波动时,都可形成稳定的平展火焰。 相似文献
5.
Flame retardant and the degradation mechanism of high impact polystyrene/Fe-montmorillonite nanocomposites 总被引:1,自引:1,他引:0
High impact polystyrene/Fe-montmorillonite (HIPS/Fe-MMT) nanocomposites were successfully prepared by melting intercalation.
The nanostructures of HIPS/Fe-MMT were testified by X-ray diffraction (XRD) and transmission electron microscope (TEM). Corresponding
to pure HIPS, the thermal stability of HIPS/Fe-MMT nanocomposites was notably improved. The peaks of heat release rate (PHRR)
and the mass loss rate (MLR) were significantly reduced after the formation of the HIPS/Fe-MMT nanocomposites from cone calorimetry.
And nanocomposites PHRR was further lower with the increase of Fe-MMT content in the range of 1 to 5 wt%. The degradation
mechanism of HIPS and HIPS/Fe-MMT nanocomposites was conducted by pyrolysis gas chromatography mass spectrometry (Py-GC-MS).
And the reason of the enhancement of thermal stability maybe is that structural iron is the operative site for radical trapping
in the Fe-MMT and the nanostructure enhances the interaction of the chains of the HIPS. 相似文献
6.
Polyurethane coatings are highly flammable, and because of their widespread applications on different substrates (wood, steel, and building materials), there is a need to increase their fire‐safety properties. Intumescent additives sharply suppress the flammability properties of polyurethane coatings. Two problems accompany intumescent additives: their high loading percentage and incompatibility with polyurethane coatings. In this research, we succeeded in increasing the compatibility by mixing intumescent additives with a butyl acrylate polymer and in lowering the flame‐retardant additive loading (up to 20%) by incorporating newly modified montmorillonite. The flammability properties of the new intumescent coatings were characterized with a cone calorimeter. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
7.
磷氮阻燃腈纶结构性能及阻燃机理研究 总被引:5,自引:0,他引:5
研究了含磷酸二氢铵和脲复合阻燃剂的共混阻燃腈纶的结构和性能。研究表明,在纤维成形加工过程中,部分阻燃剂聚合生成聚磷酸铵和聚脲,阻燃剂以微粒状均匀分散并包埋在纤维内部;阻燃剂的加入使纤维高序区大分子间等距离排列的规整性和片状结构单元等距离平行排列的程度降低,热稳定性亦略有下降;但纤维的宏形态结构及物理机械性能没有明显变化;磷氮阻燃腈纶具有良好的阻燃性和阻燃耐久性,经碱洗20次、水洗30次后,阻燃剂的磷和氮的保留率分别高达82.9%和89.5%,纤维的LOI值仍在26%以上。 相似文献
8.
9.
A series of phosphorus‐containing, wholly aromatic thermotropic copolyesters from acetylated 2‐(6‐oxide‐6H‐dibenz〈c,e〉〈1,2〉oxa phosphorin‐6‐yl)‐1,4‐dihydroxy phenylene, p‐acetoxybenzoic acid, terephthalic acid, and isophthalic acid were prepared by melting polycondensation. The structure and basic properties of the polymers, such as the glass‐transition temperature (Tg), melting temperature (Tm), thermal stability, crystallinity, and liquid crystallinity, were investigated with Fourier transform infrared, elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis, wide‐angle X‐ray diffraction, and hot‐stage polarizing optical microscopy. The copolyesters had relatively high Tg values ranging from 183 to 192°C. The Tm values obtained from DSC curves for samples P‐20 and P‐25 were 290 and 287°C, respectively (where the number in the sample name indicates the molar fraction of the phosphorus‐containing monomer in the reactants). The initial flow temperatures of other samples observed with hot‐stage polarizing microscopy were 271–290°C. The 5% degradation temperatures in nitrogen ranged from 431 to 462°C, and the char yields at 640°C were 41–52%. All the copolyesters, except P‐40, were thermotropic and nematic. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1278–1284, 2002 相似文献
10.