纳米级BaAl_2O_4微粉的制备和性质

分别用溶胶 -凝胶法、低温固相反应法 ,制得了纳米级BaAl2 O4微粉 ,用电镜观察了其形貌和粒径的大小 ,用X-射线衍射仪进行了物相分析 ,测定了其纯度与晶型 ,讨论了制备方法与粒度大小的相互影响     

纳米技术在生物传感器中的应用

介绍了纳米技术在生物传感器中的应用，重点阐述当前发展方向的前沿。     

用环境友好催化剂合成丙酸异丁酯的研究

报道了以固载杂多酸盐TiSiW12O40/TiO2为环境友好催化剂，对以丙酸和异丁醇为原料合成丙酸异丁酯的反应条件进行了研究。实验表明：TiSiW12O40/TiO2是合成丙酸异丁酯的良好催化剂，最佳反应条件为：n（醇）：n(酸）=1.2:1，催化剂用量为反应物料总质量的2.0%。反应时间1.0h，反应温度106-125℃，上述条件下，丙酸异丁酯的收率可达79.1%。     

纳米材料对PBT合成的催化性能研究

用溶胶－凝胶法制备TiO2及TiO2/SiO2复合纳米材料，作为PBT（聚对苯二甲酸丁二酯）合成的催化剂，与现在普通使用的催化剂钛酸丁酯进行了比较和研究。结果发现，TiO2/SiO2复合纳米材料催化性能最好，纳米TiO2次之。     

Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES

Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes…     

TiSiW12O40/TiO2催化合成丙酸正丙酯

研究了固载杂多酸盐TiSiW12O40/TiO2催化丙酸与正丙醇的酯化反应，探讨了催化剂用量，反应时间及醇酸摩尔比对酯收率的影响。当醇酸摩尔比为1.3:1，催化剂的量为醇酸总质量的1.5%。反应时间为1.0h，酯产率可达71.4%以上，采用该催化剂合成丙酸正丙酯不仅酯化反应温度低，反应时间较短，催化剂用量少，而且可较好地回收利用，可降低成本；因此，TiSiW12O40/TiO2是合成丙酸正丙酯的优良催化剂，具有良好的应用前景。     

我国纳米科技的现状与展望

本文概述了纳米科技的沿革，及其在国内外发展的情况，并就我国如何进一步发展纳米科技提出了自己的想法。     

消光剂TiO_2悬浮液配制工艺优化

讨论了在配制过程中减少凝聚粒子形成的有效措施。分散系统由分散器和弱搅拌组成 ,悬浮液初始浓度为 5 0 % ,分散时间应在 0 .5h以上。莫诺泵最佳转速在 85r min左右 ,球磨后TiO2 大粒子通过离心机分离出去 ,使产品中的大于 10 μm的凝聚粒子数小于 0 .4个 mg。     

铸型尼龙改性的研究进展

铸型尼龙产品广泛地用于各种机械零件，改性后的铸型尼龙，可克服其自身的缺点，满足工业应用的要求。文章就我国近年来在铸型尼龙改性研究方面的情况及不同的改性方法做了详细的介绍。     

Gas-phase selective oxidation of toluene on TiO2–sepiolite supported vanadium oxides: Influence of vanadium loading on conversion and product selectivities

Gas-phase selective oxidation of toluene has been carried out on vanadium oxide systems (5–20 wt.% of V₂O₅, equivalent to 0.4–1.7 theoretical monolayers) supported on TiO₂–sepiolite (with titania loading around the theoretical monolayer, 12 wt.%) and on sepiolite. A study has been made on both the influence of vanadia loading and of the support on the catalytic behaviour of the supported vanadium systems. The reducibility by H₂ TPR was also studied as well as the acid and basic/redox sites from the results of conversion of the 2-propanol test reaction of the solids. Benzaldehyde, benzoic acid and several coupling products were the main ones detected, attaining over 50% selectivity towards the benzaldehyde and benzoic acid products at a total conversion around 10%. The activity and selectivity to the selective products exhibited by vanadium systems supported on mixed support were superior to those exhibited by the systems supported on sepiolite and increased notably in both series with the increase in vanadium loading. The best catalytic behaviour exhibited by the vanadium systems supported on mixed support, which also exhibited the highest density of sites capable of being reduced (as well as their reducibility) and of those responsible for propanone formation, could be attributed not only to the different balance of the vanadia species existing in the two supports (monomeric + oligomeric/polymeric), but also to such other factors as the nature of the support and, concretely, its chemical composition.