丝网印刷氧化石墨烯对锂离子电池LiNi1/3Co1/3Mn1/3O2 三元正极的改性及性能影响

通过丝网印刷方法,在由LiNi_1/3Co_1/3Mn_1/3O₂、导电添加剂和聚偏氟乙烯制成的电极表面涂覆了一层薄薄的氧化石墨烯。在充电截止电压为4.3 V的条件下进行了循环性能和倍率性能测试。结果表明：未改性电极在恒电流充放电测试中容量下降且极化增加,而包覆改性后电极的容量衰减程度和极化增加速度降低。这是由于氧化石墨烯涂层抑制了LiNi_1/3Co_1/3Mn_1/3O₂电极和电解质之间的部分副反应,使得改性电极的循环稳定性和倍率性能显著提高,为提升LiNi_1/3Co_1/3Mn_1/3O₂电极性能提供了一种环境友好且非常有效的方法。     

ZnO纳米锥光致发光性及印刷ZnO纳米锥场发射性能研究

利用物理热蒸发法制备大规模的蒲公英状的ZnO纳米锥,利用荧光光谱仪对ZnO纳米锥进行了光致发光性能测试.针对现有的丝网印刷碳纳米管(CNTs)薄膜需要各种后处理工艺后才能改善其场发射特性的问题,提出了一种不需任何后处理丝网印刷ZnO纳米锥的浆料配制工艺.用该工艺制备的丝网印刷ZnO纳米锥的场发射特性测试表明,ZnO纳米锥与制浆剂质量比为3∶5的薄膜的开启场强最低为2.25V/μm(电流密度为1μA/cm2),在4.6V/μm场强下,阳极荧光粉的发光点亮度高且分布均匀.说明该方法成本低,工艺简单,无需任何后处理,在ZnO纳米锥场发射显示器的制作中有很好的实际应用价值.     

用于AC-PDP保护层的六硼化镧薄膜的制备与性能研究

采用丝网印刷法在PDP的传统Mg O保护层上制备了六硼化镧薄膜。改变工艺参数,测试了La B6/Mg O薄膜的表面形貌和光学性能,并对透明的La B6/Mg O薄膜在Xe/Ne混合气体中的放电性能进行了测试。实验结果表明,采用400目丝网和球磨后的La B6粉末有利于提高La B6/Mg O薄膜的透过率,相比于原有的Mg O衬底,透过率达到90%以上。放电测试结果表明,印刷了La B6薄膜的Mg O+La B6样品的放电性能优于传统的Mg O保护层,其中着火电压降低了7%左右,放电延迟降低了9%左右。     

一种基于酶传感器的血酒精便携式检测仪的研究

介绍了一种直接测定末梢血酒精浓度的检验仪器。基于丝网印刷技术制备一次性碳电极,用Nafion固定麦尔多拉蓝(Meldola’sblue,MB)作为电子介体,通过交联法用戊二醛将乙醇脱氢酶(ADH)和氧化型辅酶Ⅰ(NAD+)固定于Nafion-MB修饰的电极上,制成检测ADH催化酒精产生电化学反应形成的电流的末梢血酒精一次性生物传感器。以单片机EM78P458为中央处理控制器,负责检测生物传感器反应输出的电流,并对信号进行放大、处理和显示。实验结果表明:血酒精酶传感器便携式检测仪与自动生化分析仪测得血酒精浓度值的相关性良好。提供了一种准确检测血酒精浓度的新技术和途径。     

乙基纤维素对二氧化钛薄膜性能的影响研究

研究了乙基纤维素(M70)含量对染料敏化太阳电池电极质量、电池性能的影响规律。研究发现适当的M70可以明显改善TiO2电极质量,提高电池性能。但过多的乙基纤维素含量,会降低电池的开路电压和短路电流,对电池性能的提高不利。当乙基纤维素含量为0.5g,染料敏化太阳电池光电转换效率最高,达到5.6%(Jsc=15.04mA/cm2,Voc=0.73V,FF=0.53)。     

Product design: Formulation of a screen-printable sintering-type conductive paste

Due to the complexity of the screen-printing operation and the rheological behaviors of the screen-printable paste, such a paste is usually formulated by trial-and-error. In this report, a systematic procedure, based on heuristics and mechanistic models, for the design of a screen-printable paste is developed. The procedure is demonstrated by a case study of the formulation of a conductive paste of copper particles.     

分段圆型碳纳米管阴极结构的三极FED制作

利用钠钙平板玻璃形成阴极板;结合丝网印刷技术在阴极板上制作了分段圆型碳纳米管阴极结构。烧结固化的银浆层用于分别构成矩形底电极和圆型底电极,其良好的导电性能确保阴极电势能够被顺利传导给碳纳米管。对矩形底电极采取了分段条形电极形式,多个分段条形电极整体排列在阴极板表面,形成分段条形电极矩阵,改进的矩形底电极能够有效降低整体显示器的无效电压降;而制作的圆型碳纳米管层和圆型底电极用于提高碳纳米管的场发射性能。结合分段圆型碳纳米管阴极,研制了三极结构的场致发射显示器。该显示器具有良好的场致发射特性和高的图像发光亮度,能够正确显示简单的字符图像,其开启场强为2.16 V/μm。     

Printable,Down/Up-Conversion Triple-Mode Fluorescence Responsive and Colorless Self-Healing Elastomers with Superior Toughness

Expanding the practical application range of self-healing materials has become an important challenge for developing smart materials. Herein, the synthesis of printable, triple-mode fluorescence responsive, and colorless self-healing elastomers, formed by the combination of disulfide cross-linked polyurethane (PU) polymers, carbon dots (CDs) down-conversion fluorescence materials, and lanthanide ions doped upconversion fluorescence materials. The PU elastomers with optimal mechanical properties and good restorability (recover large strain of 500% after relaxation at room temperature (R.T.) for 2 h) are selected to incorporate CDs for fabricating fluorescence responsive elastomers (denoted as PU-CDs). Significantly, the prepared PU-CDs exhibit not only superior tensile strength and toughness (20.95 MPa and 85.13MJ m^–3, respectively) than the previously reported R.T. self-healing elastomers but also show good self-healing properties and achieve blue fluorescence emissions under the ultraviolet excitation. Furthermore, a series of dual-mode fluorescence patterns based on formulated core@shell structural upconversion inks are prepared on the transparent PU-CDs elastomers by a directly screen-printing method. Self-healing and integrating a series of fluorescence patterns and damaged electrical patterns can also be accomplished successfully. The designed self-healing materials provide new ideas and important guidance for developing and applying the next generation of smart materials.     

Tunable chromaticity and enhanced luminous efficacy of white LEDs with phosphor-in-glass coating via multilayer screen-printing

The phosphor-in-glass (PiG) coating was fabricated via multilayer screen-printing and low-temperature sintering. The PiG coating consisted of Eu₂O₃-doped P₂O₅-ZnO-B₂O₃ (PZB) glass, Y₃Al₅O₁₂:Ce³⁺ (YAG:Ce) yellow phosphor, and CaAlSiN₃:Eu²⁺ (CASN:Eu) red phosphor. Eu₂O₃ and CASN:Eu were used to provide red emission for tunable chromaticity of white light-emitting diodes (LEDs), and surprisingly, the luminous efficacy was also enhanced. The impact of the variation in the B₂O₃ content on the PZB glass and the effect of Eu₂O₃, YAG: Ce, and CASN:Eu on the luminescent properties of the PiG coating were investigated. The glass matrix with 8 mol% B₂O₃ showed the lowest transition temperature and a suitable coefficient of thermal expansion. The spectra showed that the coating can be excited by blue light and produce yellow light and red light. The spatial distribution of the PiG coating was inspected by scanning electron microscopy, and it was observed that only a low erosion of phosphor by the glass matrix occurred. Furthermore, the white LEDs devices were constructed with the PiG coating on the blue LED chips. This method showed a decreased correlated colour temperature of 5137, a increased colour rendering index of 82.8 and an improvement in the luminous efficacy. The PiG coating for tunable chromaticity and enhanced luminous efficacy of white LEDs shows potential for application.     

新型三极碳纳米管场发射器件的研究

采用催化剂高温分解方法制备了碳纳米管薄膜阴极。利用优质云母板作为绝缘材料．结合简单的丝网印刷工艺制作了新型的栅极结构。详细地给出了新型三极碳纳米管场发射器件的制作工艺．对场致发射的机理进行了初步的讨论。采用这种新型的栅极结构．不仅极大地降低了总体器件成本．同时避免了碳纳米管薄膜阴极的损伤．提高了器件的制作成功率。所制作的三极结构平板场发射器件具有良好的场致发射特性和栅极控制能力。