Spray dryer processed graphene oxide/reduced graphene oxide for high-performance supercapacitor

This study deals with the utility of mini spray dryer process to improve the dispersibility, of graphene oxide(GO) and its application for high-performance supercapacitor. Initially, the neutral solution of GO was obtained using the modified Hummer's method. After this, the prepared GO solution was processed by mini spray dryer to obtain a more purified, lighter, and dispersed form of GO which is named as spray dryer processed GO (SPGO). The SPGO thus obtained showed excellent dispersibility behavior with various solvents, which is not found in case of conventional oven drying. Furthermore, utility of SPGO and its reduced form (r-SPGO) for supercapacitor applications have been investigated. Results obtained from the cyclic voltammetry(CV) analysis, impedance, and charge-discharge behavior of supercapacitor fabricated using r-SPGO shows enhanced features. Therefore, the simple spray dried GO and its reduced form, that is, r-SPGO can be utilized as a potential candidate for the supercapacitor application. Herein, as synthesized SPGO exhibited the specific capacitance of 12.07 and 37.6 F/g with PVA-H₃PO₄ and 1 mol/L H₃PO₄, respectively, at a scan rate of 5 mV/s. On the other hand, reduced form of SPGO, that is, r-SPGO showed the specific capacitance of 27.16 and 230 F/g with PVA-H₃PO₄ and 1 mol/L H₃PO₄, respectively.     

Changes in the physical properties of honey powder during storage

Honey powders produced by spray drying with the addition of Arabic gum and sodium caseinate were characterised in terms of the influence of storage time on the following physical properties: particle size, moisture content, water activity, bulk density, flowability and hygroscopicity. The storage affected those properties; after 12 weeks of storage, particle size decreased (except Arabic gum powder treated as a control sample), moisture content and water activity increased, hygroscopicity decreased. Changes in bulk density, particle size and moisture content caused the rise of Hausner ratio value; however, the powders were still characterised by a very good flow properties and low cohesiveness. The colour of reconstituted powders was also affected by storage; in most of samples, the darkening, reduction in redness and yellowness were observed. Colour parameters were the most stable in powders obtained with the addition of 2% w/w of sodium caseinate.     

综采工作面粉尘防治问题分析与技术改进

针对新桥煤矿2301综采工作面机载喷雾系统喷雾效果差、喷雾耗水量大造成煤质含水量超标、喷嘴雾化程度不高、喷嘴容易发生堵塞等问题,提出了高压喷雾系统设计方案,选择了1.2mm的锥形引射喷嘴和1.5mm的扇形引射喷嘴。采用固定水泵供水方式,结合工作面实际情况,计算出喷雾总用水量247.5L/min,提高了喷雾射程,提升了除尘效果。     

Investigation of flame spray synthesized La1-xSrxCoO3 perovskites with promotional catalytic performances on CO oxidation

To enhance the activity of catalysts for CO removal, the perovskite-type catalysts La_1-xSr_xCoO₃ (x = 0, 0.2, 0.4, 0.6, and 0.8) with different Sr²⁺ doping amount were synthesized by flame spray synthesis (FSS) method. The perovskite-type catalyst synthesized by FSS has a much larger specific surface area (SSA) than that prepared by other conventional methods. The SSA of catalyst increases with the increase of Sr²⁺ doping amount and the SSA of La_0.2Sr_0.8CoO₃ reaches 31.65 m²/g. Compared with other conventional methods, FSS method significantly improves the activity of catalyst and makes it close to the performances of catalysts with surface modification. The substitution of La³⁺ by Sr²⁺ promotes the generation of secondary phase Co₃O₄ and SrCO₃. The catalytic activity of La_1-xSr_xCoO₃ increases with the addition of Sr²⁺, which results from the increasing active sites and oxygen vacancies. Interestingly, La_0.4Sr_0.6CoO₃ performs the highest activity for CO oxidation and the CO conversion reaches 50% at 148.6 °C and 90% at 165.9 °C. The oxidation of CO over La_1-xSr_xCoO₃ catalyst may follow a combination of MvK and L-H mechanisms according to the experimental results of H₂-TPR. Moreover, the catalyst exhibits good catalytic activity in consecutive oxidation cycles. In consecutive oxidation experiments with La_0.4Sr_0.6CoO₃, the CO conversion reaches 50% at 168.8 °C and 90% at 197.8 °C in the eighth oxidation cycle. These results prove that FSS method can further improve the activity of catalysts and is suitable for the preparation of efficient catalysts.     

Improving Wear Resistance of the Ni-base Thermal Spray-Welding Coating Using Rare Earths

ＩｍｐｒｏｖｉｎｇＷｅａｒＲｅｓｉｓｔａｎｃｅｏｆｔｈｅＮｉｂａｓｅＴｈｅｒｍａｌＳｐｒａｙＷｅｌｄｉｎｇＣｏａｔｉｎｇＵｓｉｎｇＲａｒｅＥａｒｔｈｓＺｈａｉＧｕａｎｇｊｉｅ（翟光杰）（ＩｎｓｔｉｔｕｔｅｏｆＰｈｙｓｉｃｓ，ＡｃａｄｅｍｉｃａＳｉ...     

喷射轧制Fe-4.5%Si硅钢片的组织和性能

采用喷射成形和轧制工艺制备了厚度为0.5mm的Fe-4.5%Si高硅钢片，并对其密度、显微组织和电磁性能进行了测试分析，研究结果表明：在最佳的喷射成形和轧制工艺条件下，所制备硅钢片的磁感应强度B25为1.544T、B50为1.641T；铁损P1050为1.437W/kg、P1550为3.43W/kg，说明喷射成形轧制技术可以制备出高磁感应强度、低铁损的高硅钢片。     

侯马冶炼厂奥斯麦特熔炼炉炉渣恶化的处理

介绍侯马冶炼厂奥斯麦特熔炼炉3次炉渣恶化的原因，采取的措施和结果。粉煤灰积存，生料堆积和风料比失当造成炉渣SiO2含量升高，Fe含量降低是炉渣恶化的主要原因，添加高铁造渣成分调整渣组成或不加料浸沿喷枪正常熔炼状态操作，将生料中的铁氧化造渣，提高炉温，改善炉渣性质，使炉况恢复正常。     

一种洁净的、非接触性的新型粘合剂喷洒技术

介绍了Robatech公司开发的PFC喷嘴。这种喷嘴为标准化组件，具有较大的适用性，既适用于新厂配套，也适用于老设备改造。     

Microstructures formed by spray freezing of food fats

The spray-freezing of two food fats, tripalmitin (PPP) and cocoa butter (CB) and mixtures thereof, has been modeled experimentally using a novel single droplet freezing apparatus configured so that temperature profiles or samples for microstructure analysis can be obtained. For 2 mm diameter droplets suspended in a cold air flow at temperatures around 2–15°C, initial cooling rates were on the order of 10 K s⁻¹ and the temperature profiles could be correlated directly to DSC data collected at 20 K min⁻¹, indicating that minimal supercooling of the materials occurred in the droplet form. Microstructure analysis confirmed that PPP crystallized preferentially in mixtures, and that the surface structure was very sensitive to storage conditions. The bulk structure was much less sensitive, and the internal microstructure of the PPP droplets revealed distinct nucleation sites, which were absent from the CB: These persisted in the mixtures up to 50 wt%. X-ray analysis indicated that the fats crystallized in their more stable forms, namely, β for PPP and Form V/V1 in CB.     

钠冷快堆中喷雾钠火的计算分析

根据钠冷快堆中喷雾钠火的特点建立了理论模型，编制了SSPRAY程序。该程序模拟钠喷雾燃料过程中钠滴的运动、钠和氧气的燃烧反应、热量传递和质量传递等瞬态过程。用该程序计算了气体和墙壁温度、气体压力、氧气摩尔份额、喷雾流燃烧速率和热量热递速率等主要参数。利用AI实验数据和美国SPRAY－3A的计算结果对程序进行了验证，结果符合较好。