A novel way to treat refractory waste: Sonication followed by wet oxidation (SONIWO)

The effectiveness of the hybrid system sonication followed by wet oxidation (SONIWO) to treat otherwise refractory waste has been demonstrated. In such a hybrid system homogeneous CuSO₄ catalyst was found to be very efficient.     

济钢转炉煤气储存加压系统存在缺陷及处理措施

济钢燃气厂针对济钢转炉煤气储存加压系统的设备现状，组织了一次设备大修，大修后煤气柜升降速度提高到了1．0m/min，并解决了加压机前负压等问题。     

湿法停炉保护优点多 建议采用YZ—101防腐阻垢剂作为湿法炉保护剂

介绍了湿法炉保护的作用原理,YZ—101防腐阻垢剂的使用方法、注意事项以及使用后所带来的经济效益。     

硫氰酸钠湿纺腈纶设备的孔蚀与防护

本文重点讨论了硫氰酸钠湿纺腈纶设备因钝化膜缺陷和Cl-侵入而产生孔蚀的机理及环境因素对孔蚀的影响,并针对产生孔蚀的主要原因提出了防护措施。     

覆膜滤料的滤尘性能测试方法研究

由于覆膜滤料的结构和性能有别于普通滤料，因而普通滤料的滤尘性能测试方法不完全适用于覆滤料。本文作者在总结实践经验的基础上，提出了在覆膜滤料的滤尘性能测试中应注意的一些问题和应增加的测试项目。     

Production of phosphoric acid with low content of impurities

The present work is to study the possibility for controlled distribution of the impurities when they are decomposed by sulphuric acid to wet phosphoric acid and phosphogypsum, as well as generating technological conditions for production of clean wet phosphoric acid and its derivatives - phosphoric fertilizers, food phosphates and other phosphoric products.A coefficient of distribution D_A is introduced as a general criterion for elements dispersion. The study includes relationships between the weight ratio sulphuric acid/natural phosphate and D_A; the period of decomposition and D_A; the particle's size content of the natural phosphate and D_A. The obtained experimental data and relationships about the influence of the above discussed technological parameters on dispersion of more than 23 elements allow for control of that process in wet phosphoric acid and phosphogypsum by selecting specific technological conditions. Thus, depending on the requirements of acid's consumers and procedures for secondary processing of phosphogypsum to end-products, a selective decomposition of the natural phosphates to phosphoric acid and phosphogypsum can be carried out with content of the impurities in those products varying in narrow limits.     

Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

Toward A Mechanistic Understanding of Re-Infiltration in Naturally Fractured Reservoirs with Surfactant-Aided Gravity Drainage Process

Surfactant-aided gravity drainage is an improved oil recovery technique for water-invaded zone in fractured carbonate reservoirs, which are mostly oil-wet or mixed-wet rocks. The re-infiltration mechanism in water-invaded zone has a considerable effect on oil vertical movement in gravity drainage processes. In this work, a mechanistic understanding of re-infiltration in surfactant-aided gravity drainage, in comparison to oil–water gravity drainage is presented using an experimentally and numerically validated model. A column model is constructed from three matrix blocks. These blocks are separated from each other by horizontal fractures. A storage tank is considered on top of the model to store depleted oil from matrix blocks. The stacked-blocks model for re-infiltration is validated and verified to simulate water and chemical flooding using a mesh independency study and experimental flooding data in a composite core experiment. Using this model, several analyses are performed to investigate effects of rock and fluid properties, rock saturation functions, wettability alteration, surfactant adsorption, and capillary continuity on re-infiltration.     

关于输气管线内衬聚乙烯管可防止其腐蚀的商榷

本文参照德国一实例，即利用多种类型PE衬层，在一定温差及有气体扩散阻挡层和无气体扩散阻挡层的条件下，详细地叙述了高压酸性气体对其进行长期渗透作用的试验。结果显示：水蒸气和腐蚀性气体（如H2S）的渗透作用是不能忽视的，甚至当PE层为5mm时亦有一定渗透性；此外，在衬层底部尚产生了化学腐蚀作用，从而促使人们必须考虑须正确选择PE下边的防腐底层。     

机械活化-湿化学合成LiMn2O4的组成、结构与表征

以MnO2和LiOH·H2O为原料,采用机械活化与湿化学集成的方法,在水溶液中直接合成了结晶态的尖晶石锂锰氧化物.当锂含量介于3.78%～4.35%之间时,所得锂锰氧化物为纳米级球形粉末,以尖晶石结构为主,含极少量的Mn3O4杂相;在300～800℃温度范围内热处理后,Mn3O4杂相消失,尖晶石结构更趋完善.所合成的含锂5.80%的高锂样品则以LiMnO2层状结构为主,含少量Mn3O4杂相,其SEM形貌为片状;在300～700℃下热处理8 h后,层状LiMnO2转变成尖晶石LiMn2O4,Mn3O4杂相峰明显减弱并随热处理温度的升高而消失;当温度升高至700～800℃时,开始出现缺锂的Li1-xMn2O4相.结果表明:该法制备锂锰氧化物可实现锂、锰、氧在原子级水平的均匀混合,所得产物的热稳定性能良好,其化学计量组成与结构易于调整和控制.