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排序方式: 共有1260条查询结果,搜索用时 31 毫秒
1.
Yang Liu Liang-ming Pan Hong-bo Liu 《International Journal of Hydrogen Energy》2021,46(27):13923-13935
Relatively low efficiency is the biggest obstacle to the popularization of water electrolysis, which is a particularly feasible way to produce super-pure hydrogen. Imposing a magnetic field can increase the hydrogen production efficiency of water electrolysis. However, the enhancement's detailed mechanism still lacks an insightful understanding of the bubbles' micro vicinity. Our recent work aims to understand why the micro-magnetohydrodynamic (MHD) convection hinders single bubbles' detachment on the microelectrode. A water electrolysis experiment by microelectrode is performed under an electrode-normal magnetic field, and dynamic analysis of the single bubble growing on microelectrodes is performed. The variation of bubble diameter with time in the presence or absence of the magnetic field was measured, and the forces acting on the bubble were quantified. The result shows that the micro-MHD convection, induced by Lorentz force, can give rise to a downward hydrodynamic pressure force that will not appear in large-scale MHD convection. This force can be of the same magnitude as the surface tension, so it dramatically hinders bubbles' detachment. Besides, the Kelvin force provides a new potential way for further improving the efficiency of water electrolysis. 相似文献
2.
《Journal of the European Ceramic Society》2021,41(15):7868-7877
In this work, 0.5TRPO•0.5Gd2Zr2O7 ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr2+ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms. 相似文献
3.
An original procedure has been established for estimating the overall volumetric mass transfer coefficient using the oxygen concentration curves resulting from the usual gassing-in and gassing-out method. This procedure was applied to experimental data obtained in a small scale bubble column using both tap water and a coalescence-inhibiting liquid mixture that represents the coalescence behavior of biological media. It is based on the analysis of the characteristics times of the system, including those of the hydrodynamics of the two phases, the sensor dynamics and the system inertia when the gas composition is modified. A numerical procedure was developed to estimate the characteristic time of the system inertia ti, using the assumption that this inertia is nearly independent of superficial gas velocity UG. The calculations confirmed that the optimized ti value was nearly independent of UG and of the coalescence behavior of the liquid phase. Additionally, the resulting KLaL values for tap water were closer to the correlation of Shah et al. [1982. Design parameters estimations for bubble column reactors. A.I.Ch.E. Journal 28, 353-379] than those of other conventional models. Finally, the original procedure was also reported to reduce significantly the square sum deviation between the predicted and the measured oxygen response curves. 相似文献
4.
M. Kemiha 《Chemical engineering science》2006,61(12):4041-4047
The present work aims at understanding the behavior of individual bubbles in non-Newtonian fluids. By means of a Particle Image Velocimetry (PIV) device, the complete flow field around either a single non-spherical bubble rising in polyacrylamide (PAAm) solutions or a solid sphere settling down in the same fluids shows for the first time the similar coexistence of three distinct zones: a central downward flow behind the bubble or the sphere (negative wake), a conical upward flow surrounding the negative wake zone, and an upward flow zone in front of the bubble or the sphere. This excludes then the possible influence of the interface deformation on the negative wake. A theoretical lattice Boltzmann scheme coupled to a sixth-order Maxwell model was developed for computing the complex flow field around a solid sphere. The good agreement with the experimental measurements provides evidence that the physical mechanism responsible for the negative wake in such fluids could be related to the fluid's viscoelastic properties. 相似文献
5.
The influence volume approach (IVA) is often utilized for modeling the mass transfer process dictating bubble growth dynamics in physical foaming. However, the assumed concentration profile in the IVA method is only valid when the changes in dissolved gas concentration are small (less than 5%). In addition, the validity of the IVA method is difficult to justify in chemical foaming applications because of the difficulties involved in defining the dissolved gas concentration profile.In the present work, we define two distinct stages of bubble growth for physical foaming. These two stages are termed as free and limited expansion and are controlled by the bubble nucleation rate. Bubble nucleation is assumed to occur only in the free expansion stage. In this stage, the bubble pressure drops substantially from an initially high pressure in the supersaturated state while the dissolved gas concentration changes very little. The second stage of our two-stage mass transfer model is termed the limited expansion stage and accounts for bubble growth in the late stages of foam evolution, when the pressure changes become small. However, in the limited stage of bubble growth the dissolved gas concentration drops significantly, as the available dissolved gas is depleted. To summarize our two-stage mass transfer model of foam expansion, the pressure difference between the bubble phase and the liquid phase is the primary mechanism for driving mass transfer in the early (free) stages of foam growth and the concentration difference is the driver for bubble growth in the late (limited) stages of growth. The first stage can be regarded as the nucleation stage and it is relatively short; while the second stage can be regarded as the bubble growth stage and is much longer. Most of the bubble volume expansion takes place in the second stage.The concentration gradient at the bubble edge, which is often ignored in other models, is analyzed in detail in this paper. The details of our novel mass transfer model are also presented. 相似文献
6.
本文在热态条件下,研究了鼓泡浆液反应器的气含率、反应器直径为0.098m,物系组成为氮气-液体石腊-石英砂。考察了气速、压力、温度、静床高及固体引入等因素对气含率的影响。对于53μm粒子的三相浆态体系,气含率与表观气速关系式为εG=0.053uG^1.2。 相似文献
7.
In the present paper, nonlinear features and analytical results for the chaotic bubbling from a submerged orifice are described. A chain of air bubbles was produced from the single orifice of in diameter and micro-convection induced by the bubble generation was recorded using hot-probe anemometer located close to the orifice. The air flow rate was varied widely from q=100 to and the aspects of bubbling were observed by high-speed video. The nonlinear analysis is performed for the time series data of hot-probe anemometer especially in the range of q=435-. The calculated largest Lyapunov exponent shows that with increase of air volume flow rate, the time period for the process of liquid flow to lose stability becomes shorter and at high air flow rate such as , it is shorter than the time period between subsequent bubbles. To explain such chaotic behaviors of bubbling, a simple model has been proposed. The model simulates the process of interaction between the elastic bubble wall and liquid. Simulation results compared well with the analytical results of experimental data. Summarizing, it is concluded that one of the reasons for chaos appearance is the nonlinear character of interaction between an elastic bubble wall and the liquid stream. 相似文献
8.
Bubble temperatures at 95 kPa over the entire composition range are measured for the five binary systems formed by 1,2-dimethylbenzene with 2-propanol, 1-butanol, 2-butanol, 2- methylpropan-1-ol, and 2-methylpropan- 2-ol. A Swietoslawski - type ebulliometer was used for the measurements. The composition versus temperature measurements are well represented by the Wilson model. 相似文献
9.
All experiments of pressure fluctuations were carried out in a bubble column with a moderately large column of 0.376 m ID.
The recently developed technique of wavelet packet transform based on localized wavelet functions is applicable to analysis
of the fluctuating signals. The time series of pressure fluctuation signals have been analyzed by means of wavelet packet
transform components, decomposition through best basis algorithm and timefrequency representation. By resorting to this technique,
the objects in bubbly flow regime have fine scales and frequencies than ones in churn-turbulent flow regime. Thus, this wavelet
packet transform method enables us to obtain the frequency content of local complex flow behaviors in a bubble column. 相似文献
10.
Multi-scale finite element modelling using bubble function method for a convection-diffusion problem
Due to the multi-scale nature of the convection-diffusion equation the standard Galerkin method fails to predict accurate and stable results. A multi-scale finite element method based on the bubble function approach has been developed and applied to this problem. Finite element formulations based on the discontinuous weighting functions including the streamline upwind Petrov-Galerkin (SUPG) method are also evaluated. The results show that the multi-scale method provides stable and accurate results and matches very well the analytical solution. 相似文献