Preparation of high-activity coal char-based catalysts from high metals containing coal gangue and lignite for catalytic decomposition of biomass tar

The potential of using high metals containing coal gangue and lignite to prepare high-activity coal char-based catalysts is investigated for effective biomass tar decomposition. Loose structure and rough surface are formed for these char-based catalysts with heterogeneous distribution of a large number of inorganic particles. In the biomass tar decomposition, the performance of the coal char-based catalysts is significantly influenced by the content of the metals in the raw materials and coal gangue char (GC) with the ash content as high as 50.80% exhibits the highest activity in this work. A high biomass tar conversion efficiency of 93.5% is achieved at 800 °C along with a significant increase in the fuel gas product. During the five-time consecutive tests, the catalytic performance of GC increases a little at the second or third times reuse and remains relatively stable, showing the remarkable stability of the catalyst in biomass tar decomposition applications.     

Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash

Ceramics with mullite whiskers were prepared from coal fly ash and Al₂O₃ raw materials, with AlF₃ used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF₃ addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF₃, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm³ and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources.     

综放工作面防治水技术应用实践

为解决21000工作面采空区及顶板涌水问题,根据工作面出水点的不同情况,采取了集水器导水、老塘设挡水堰截水、挖排水沟疏水等多项治水措施,经统计排水量达33~42m3/h,有效控制了水情,确保了工作面正常生产。     

电站隧洞岩爆岩石的微观破坏力学机制分析

分析总结西南某电站辅助隧洞的岩爆发育特征,然后用扫描电镜技术(SEM)对岩爆岩石断口进行微观断裂形貌研究,并总结其破坏力学机制,最终建立起岩爆岩石的微观断裂方式和破坏力学机制与宏观岩爆特征及其烈度的关系。     

On Burst Length Distribution and Preemption Probabilities in OBS Networks with Burst Segmentation

Recently, preemption techniques have attracted considerable attention as a means to provide differentiated quality of service in optical burst switching (OBS) networks. This paper is focused on the analysis of preemption probabilities for bursts within the same priority class. As proposed by Vokkarane and Jue ((2003)* IEEE J Select Areas Commun 21(7): 1198–1209) an incoming burst will preempt the burst in service, within the same priority class, if the residual length of the burst in service is smaller than the incoming burst length. For a general case with wavelength conversion, the preemption probability of contending bursts with a generic service distribution, not necessarily exponential, is analyzed. First, we show that the size distribution for the preempting bursts is shifted to larger values, in comparison to the original burst size distribution. Second, we obtain an upper and lower bound for the preemption probability. Finally, the asymptotic behavior of the OBS switch is analyzed showing that preemption will always occur for a very large number of wavelengths.     

小波变换分离太阳射电频谱图中的纤维结构

太阳射电爆发纤维精细结构是太阳射电爆发活动中一类重要的观测现象,利用二维小波变换对纤维精细结构动态频谱图进行处理,分离频谱图中的纤维结构。首先对原始频谱图实行多层小波变换,由低频分量重构原始图像,就可得到爆发的背景信息,令原始频谱图减去背景并经过阈值处理后,便可将原始频谱图中的纤维结构很好地分离出来。     

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我国是煤资源大国，长期来在采煤的同时，抽放排空大量煤层瓦斯，不仅浪费大量资源，还严重污染大气。利用煤层瓦斯发电是解决煤层瓦斯放空的重要途径 。文章介绍一种全新的有别于传统 发动机的瓦斯内燃机空燃自动混合控制装置，其中包括：煤层瓦斯的理化特性、装置的结构、工作原理及工作过程，阐述了结构参数对发动机性能的影响。经过在中心瓦斯工区内燃发动机组群上安装试运行，结果表明：该装置可以适用于高、中、低不同浓度的煤层瓦斯，性能稳定、可靠，达到了设计性能指标，完全满足燃气,内燃机组的使用要求，并取得了很好的经济效益、生态效益和环保效益。     

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2002年AAPG年会于3月10－13日在美国休斯顿隆重召开。根据会议论文，介绍了国外天然气勘探与研究最新进展及发展趋势，其中包括：生物气、海域及深水区有利含气区带、际上新老气区带等常规天然气，以及煤层气、深盆气、天然气水合物等非常规天然气的最新勘探与研究进展。     

Synthesis, Characterization, and Formation Process of Na-X Zeolite from Coal Fly Ash

Using the SiO₂ and Al₂O₃ components of the amorphous phase in coal fly ash (Fa), Fa was converted to Na-X zeolites in NaOH-NaAlO₂ solutions by stirring at 35°C for 72 hr and then aging at 85°C for a given period. The molar ratio SiO₂/Al₂O₃ of the starting materials was controlled from 2.0 to 13.2. The resulting materials were characterized by various means. Increasing the SiO₂/Al₂O₃ ratio of the starting material increased the degree of crystallinity of faujasite, exhibiting a maximum at SiO₂/Al₂O₃ = 8.0. The faujasite formed was identified as Na-X zeolite with Si/Al = 1.20. The amorphous phase in Fa was dissolved during the stirring to form a precursor of zeolite, such as amorphous aluminosilicate. The Na-X zeolite was formed by aging for 24 hr, and the degree of crystallinity of this material was increased with the increasing aging period. The cation exchange capacity and specific surface area were increased with the increasing degree of crystallinity of the Na-X zeolites.