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1.
《International Journal of Hydrogen Energy》2022,47(32):14570-14579
With a growing interest in hydrogen as energy carrier, the efficient purification of hydrogen from gaseous mixtures is very important. This paper addresses the separation of hydrogen using Carbon Molecular Sieves Membranes (CMSM), which show an attractive combination of high permeability, selectivity and stability. Supported CMSM containing various amounts of aluminium have been prepared from novolac and aluminium acetyl acetonate (Al(acac)3) as carbon and alumina precursors. The thickness of the CMSM layers depend on the content of Al(acac)3 in the dipping solution, which also has influence in the pore size and pore size distribution of the membranes. The permeation properties of the membranes against the Al content in the membrane follows a volcano shape, where the membrane containing 4 wt (%) of Al(acac)3 has the best properties and was stable during 720 h for hydrogen at 150 °C and 6 bar pressure difference. All the CMSM have permeation properties well above the Robeson Upper limit. 相似文献
2.
Thomas RAINER 《景观设计学(英文)》2021,9(1):112
The ability of landscape architectural projects to mitigate the worst effects of climate change will depend upon designed ecological systems. These systems will be built with plants. Despite the recognition of ecology as an essential driver of landscapes, the professionals of landscape architecture too often lack the knowledge and practical skills to create robust vegetative systems. New approaches and tools are required. This article outlines principles and methods for designing biodiverse plant systems for urban sites. Planting methods that increase species richness, functional diversity, and spatial complexity are emphasized as a way of developing more resilient plantings. Selecting species with similar evolutionary adaptions to stress, disturbance, and competition—as well as creating multi-layered compositions of diverse plant morphologies—allows designers to create compatible, long-lived plant mixes. To balance the increased visual complexity of diverse plant mixes, the article explores design techniques to make plantings more appealing to the public. The strategies explored here are based on the projects, experience, and research of Phyto Studio, a Washington, D.C. based studio. The methods build on work described in the author’s book, Planting in a Post-Wild World, an exploration of how to create designed plant communities. 相似文献
3.
现行的政府单一主导、政府与开发
商合作的社区更新模式与业主的自主更新需
求产生了矛盾。针对现有研究对社区更新的
系统性缺乏关注的问题,本文从整体视角出
发,通过构建“参与主体—程序设计—法规
政策—资金调配”四维框架,分析现行社区
更新模式与业主自主更新需求产生冲突的内
在机制。在优化现有模式的基础上,提出三
种适应业主自主更新需求的理论模式。桂华
邨业主自主更新失败的实践案例证明了本文
所提出的四维框架的重要性。最后,从政府
视角对我国社区更新机制提出优化建议。 相似文献
4.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
5.
Marcia Cristina Kaezer Fran a Rosane Aguiar da Silva San Gil Jean-Guillaume Eon 《Catalysis Today》2003,78(1-4):105-115
γ-Al2O3 supported vanadium oxides were modified by tungsten and molybdenum oxides in order to improve dispersion and selectivity towards olefins in propane oxidative dehydrogenation (ODH). Both vanadium–tungsten and vanadium–molybdenum catalysts were obtained by adsorption of mixed isopolyanions (VW5O195−, V2W4O194−, VMo5O195− and V2Mo4O194−) from aqueous solutions. The isopolyanion solutions were characterized by UV-Vis and 51V NMR spectroscopy. Vanadium, vanadium–tungsten and vanadium–molybdenum precursors and catalysts were also characterized by UV-Vis (diffuse reflectance) and solid state 51V NMR spectroscopy. An improved selectivity to propene in the presence of tungsten and molybdenum in VOx/γ-Al2O3 was observed and attributed to dilution of vanadium by tungsten or molybdenum oxides on the γ-Al2O3 surface. 相似文献
6.
针对实时CSCW系统中的迟加入问题,提出了一个改进的多“迟加入Server”算法。该算法能够有效的解决让“迟加入Client”可靠加入到协同工作的问题。通过实例验证了该算法的有效性,为进行更高效的协同工作提供了支持。 相似文献
7.
Koji Kamei Kunihiko Fujita Eva Jettmar Sen Yoshida Kazuhiro Kuwabara 《Interacting with computers》2002,14(6):438-759
In this paper, we present and discuss Community Organizer, a system designed to support network communities. The main characteristic of Community Organizer is the use of spatial representations for the relationships among community members including the communications exchanged among these members. These spatial representations reflect the degree of closeness of interests and concerns among the members, and are intended to provide users with clues on how to form network communities. In order to investigate the effectiveness of the proposed spatial representations, we conducted experiments with two different versions of the software. One version offered meaningful spatial representations while the other version did not. The subjects who used the former software version felt a greater sense of ‘community’, enjoyed using the software more, and actively used it longer than the subjects using the latter software version (control condition). These results indicated that the proposed spatial representations are effective in supporting network community formation. 相似文献
8.
On the basis of Odum's ecological economic measure of emergy as embodied solar energy, a system account of biomass resource exploitation by agriculture in China 2004 is developed in this paper, which supplements a former study on corresponding long-term historical trends during 1978 to 2000 (Chen et al., 2006. Emergy-based analysis of the Chinese agriculture. Agriculture, Ecosystems and Environment 115, 161–173). The aggregate fluxes and indicators for biomass resource exploitation in China 2004 are calculated and illustrated when compared with those for 2000 to elucidate the latest status of the Chinese agriculture as the exploitation sector for biomass resource. Data sources and algorithm are presented in detail as basic references for related analysis involving the ecological economy of biomass exploitation in agriculture. 相似文献
9.
农业重组微生物生物安全研究进展 总被引:2,自引:2,他引:0
综述了近年来农业重组微生物的研究现状和进展 ,详细介绍农业重组微生物环境释放的监控方法以及对环境的冲击作用 ,对一些有关生物安全研究的热点问题进行了探讨 相似文献
10.
Min-Seok Park Vladislav P. Vislovskiy Jong-San Chang Yong-Gun Shul Jin S. Yoo Sang-Eon Park 《Catalysis Today》2003,87(1-4):205-212
Alumina-supported vanadium oxide, VOx/Al2O3, and binary vanadium–antimony oxides, VSbOx/Al2O3, have been tested in the ethylbenzene dehydrogenation with carbon dioxide and characterized by SBET, X-ray diffraction, X-ray photoelectron spectroscopy, hydrogen temperature-programmed reduction and CO2 pulse methods. VSbOx/Al2O3 exhibited enhanced catalytic activity and especially on-stream stability compared to VOx/Al2O3 catalyst. Incorporation of antimony into VOx/Al2O3 increased dispersion of active VOx species, enhanced redox properties of the systems and formed a new mixed vanadium–antimony oxide phase in the most catalytically efficient V0.43Sb0.57Ox/Al2O3 system. 相似文献