Modelling diffusion-controlled kinetics in equilibrium and driven alloys

Summary We introduce a very simple model for thermally activated atomic migration on a lattice, and several techniques to handle it. For thermodynamical systems, the model can be used for simulating decomposition paths taking into account relevant metallurgical features. Close to equilibrium, the simplest mean-field approximation of the model can be linearized with respect to the departure from equilibrium; one then gets a microscopic interpretation of classical phenomenological coefficients, such as mobility, interfacial transfer coefficient, rate constants for the coupled relaxation of concentration and order fields. Further away from the equilibrium, the nonlinearities can be taken into account in a consistent way. For driven alloys, i.e. alloys submitted to external forcing, forced atomic migration is added to the model and new features emerge: the model is supported by several experimental results some of which confirmed its predictions a posteriori.     

Oxidation Performance of Fe-Al/WC Composite Coatings Produced by High Velocity Arc Sprayed at 650 ℃

Fe-Al intermetallics with remarkable high-temperatureintensity and excellent erosion,high-temperatureoxidation and sulfuration resistance are potential lowcost high-temperature structural material.ProducingFe-Al/WC composite coating by high velocity arcspraying(HVAS)on structural materials would notonly obviate the problems faced in fabrication of thesealloys into useful shapes,but also allow the effectiveuse of their outstanding high-temperature performance,which might thus promisingly mak…     

Oxidation performance of Fe-Al/WC composite coatings produced by high velocity arc sprayed at 800 ℃

Fe-Al/WC intermetallic composite coatings were prepared by high velocity arc spraying (HVAS) technology on 20G steel and the oxidation performance of Fe-Al/WC composite coatings was studied. The results demonstrate that the kinetics curve of oxidation approximately follows the logarithmic law and the oxidation velocity of Fe-Al/WC composite coatings is less than that of 20G steel after 5 h. The composition of oxidized coating is mainly composed of Al2O3, Fe2O3, Fe3O4 and FeO. These phases distribute unevenly. The protective Al2O3 film firstly forms and preserves the coatings from further oxidation.     

钢-铝铅半固态铸轧复合界面研究

针对钢-铝铅半固态复合界面的特点,采用界面铁铝化合物比率对钢-Al-28Pb半固态铸轧复合界面进行了定量研究,并且利用人工神经网络技术建立了界面铁铝化合物比率与复合参数(如钢板预热温度、Al-28Pb半固态浆料固相率、铸轧速度等)之间的关系模型.结果表明:与复合界面最大界面剪切强度相对应的界面铁铝化合物比率为71.5%,也就是说,合理的钢-Al-28Pb半固态铸轧复合界面应由71.5%的铁铝化合物构成.     

Si元素对Fe-Al基阻尼合金微观组织和内耗性能的影响

制备了含Si量分别为0％、0．6％和1．2％的三种Fe-5．8Al合金,并研究了这三种合金在900℃退火2 h 空冷后的微观组织特征和内耗行为,解释了Si含量及析出相对Fe-Al合金阻尼性能的影响机理,并提出了该系合金的阻尼机制。     

固溶处理对Fe-5Al-2Mo减振合金阻尼性能的影响

实验研究了固溶处理温度对Fe-5Al-2Mo减振合金阻尼性能的影响。结果表明，该合金的阻尼性能受固溶处理温度影响较大，900-1000℃固溶处理后的合金的阻尼性能较好。     

Fe－Al合金有序无序相变的电子理论研究

利用余氏理论长程有序相的键能公式，并根据计算的键结构和键能，分析了Ｆｅ－Ａｌ合金中的有序无序相变机理。     

用正电子湮没方法探讨Fe-Al合金的热处理工艺

正电子湮没方法已经成为金属研究的一种手段,但是由于正电子在介质中感知范围很小,目前主要用来分析金属和合金的微观结构。为了探索该方法在生产过程中的实用性。本文用它研究和分析了Fe-22at.-%Al合金的热处理制度。     

时效处理对Fe-5.5Al-2Mo和Fe-7Al-0.5Ti合金阻尼性能的影响

研究了Fe-5．5Al-2Mo及Fe-7Al-0．5Ti减振合金的时效特点，并深入分析了温度为475℃不同时间时效处理对其阻尼性能的影响。结果表明，合金在时效处理时，其晶粒大小及形状保持稳定；其最大阻尼性能δmax随时效时间的延长也保持在0．08～0.12。     

Fe-Al合金中与Al反位置原子弛豫有关的内耗峰

利用内耗方法对Fe47Al53合金中Al反位置原子的运动特征进行了研究,在410℃附近观察到了一个与合金热历史相关的弛豫型内耗峰.在快冷样品中内耗峰高度明显高于慢冷样品时内耗峰的高度;而对于快冷样品,升温测量时内耗峰高度又明显高于随后的降温测量时内耗峰的高度,内耗峰高度表明该内耗峰与快冷时残留的缺陷有关.由于该内耗峰激活能为1.88 eV,与Fe47Al53合金中Fe空位的迁移能相当,因而该峰应产生于应力诱导下Al反位置原子在Fe空位之间的运动.