激光熔覆专用铁基合金粉末的研究进展

指出了目前防止熔覆层开裂所采取的主要措施中存在的问题,阐述了激光熔覆和热喷涂对于所用合金粉末性能要求之异同,评述了激光熔覆专用铁基合金粉末的研制现状,提出了成分与组织设计的新思想。     

Preparation of Plate Fe_(60)Co_8Zr_(10)Mo_5W_2B_(15) Bulk Amorphous Alloy and Its Fracture Toughness

1Introduction Duwez[1]synthesizedthefoilAu Siamorphousalloyforthefirsttimewithrapidsolidification,whichinitiatedthepreparationofamorphousalloysintheprocessofalloysolidification,andthereaftertheresearchonamorphousal loysdevelopedrapidly.Since1980s,withthec…     

一种制备磁性粉末的新技术--均匀颗粒成型法

采用均匀颗粒成型法（Uniform Dropler Spray-UDS）制备Fe基合金粉末，该方法制备的颗粒粒度分布均匀，性能一致，大大优于传统的粉末制备方法（如破碎法、气雾化），具有广阔的应用前景。本文分析了粉末制备过程中颗粒尺寸的影响因素，结果表明：颗粒的大小主要取决于坩埚底部小孔、坩埚内外气体压强差以及振荡频率三个独立变量。     

电脉冲快速退火对铁基非晶合金性能的影响

采用大电流交流脉冲对非晶Ｆｅ７８Ｂ１３Ｓｉ９合金进行了去应力退火。初步探讨了电脉冲加热对加热速率和该合金内应力释放、退火脆化以及最终软磁性影响的基本规律。结果表明：电脉冲加热可以得到远高于常规退火的加热速率，选择合适工艺参数可使非晶合金内应力释放９０％，软磁性（Ｈ＿ｃ和Ｂ＿ｓ）达常规退火后的９５％以上，与此同时使合金的延性（断裂应变ε＿ｆ）维持在０．９以上，从而有望实现非晶合金磁性与延性的合理配合。     

含硼金刚石的金属包膜成分及其物相的研究

本文采用铁基触媒加入硼铁的方法，在高温高压条件下合成了含硼金刚石，利用电子探针（EPMA），透射电子显微镜（TEM）两种检测手段，分析了含硼金刚石金属包膜的微观组织结构，化学组成成分，各组成成分的物相及其可能形成的原因。研究结果表明：金属包膜的成分及其物相由正交立方结构的（Fe,Ni）3C，面心立方的γ-（Fe,Ni），面心立方的Fe23（C，B）。及少量的FeB,Ni3B组成，这些成份主要来源于原材料，其含量在高温压过程中是瞬间变化的。     

Effect of heat treatment on the microstructure and hardness of C-Cr-W-Mo-V-RE Fe-based hardfacing layer

0IntroductionHot-rollers and scissors are the critical parts of thesteel rolling equipments.At present,the surface soften-ing,the early wearing and the tearing are the primary rea-sons for the lowservice life of the hot-rollers and scissors.Although hardfacing has been applied to repaire the partseasily being worn and torn,such as the hot-rollers and thescissors,and has been obtained economic benefits[1-3],this technology has common problem:if the hardfacing lay-er contains more excessive allo…     

纳米晶Fe72.8Cu1Nb1.7V1.5Mn0.5Si13.5B9软磁合金的磁性能

本文报道了高导磁纳米晶Fe72．8Cu1Nb1．7V1．5Mn0．5Si13．5B9合金的直流和交流磁性能水平，磁导率频散行为以及高频铁损行为，给出了描述高频区频散行为和铁损行为的近似表达式。     

铁基矿物质对西部煤热解特性的影响

以神东、新疆煤为研究对象,采用微量热重、常量固定床实验装置分别对原煤、脱矿煤、载铁煤在热解过程中的质量变化和气相产物进行了对比分析,研究了铁基矿物质对煤热解特性的影响.结果表明:煤热解出现最大失重速率和气相产物最大释放量的温区均与煤的变质程度有关,较低变质程度的神东煤在450℃左右出现最大失重,而新疆煤则为600℃;神东煤热解生成CH4,CO和CO2的最大释放温度小于新疆煤.载Fe煤热解过程中生成的气相产物总量大于原煤和脱矿物煤,显示了Fe的催化作用.该催化作用主要表现在热解达到最大失重速率的温度之后的缩聚阶段,这引起了H2的生成量增大.Fe的催化作用受煤变质程度的影响,对变质程度较低的神东煤的作用明显大于新疆煤.     

激光熔覆用高硬度铁基合金的研究与应用

研究了激光熔覆Fe-Ni-Cr—B—Si合金粉末时粉末中的碳含量对于熔覆层组织、开裂敏感性、硬度和硬度均匀性的影响。结果表明，粉末含碳量的微小变化能显著改变熔覆层的组织和性能；在相同工艺条件下，粉末含碳量在一定范围内可显著提高熔覆层的硬度、降低熔覆层开裂敏感性，从而获得高硬度无裂纹的熔覆层；碳含量的增加可提高熔覆层的硬度均匀性。本文还报道了用自制Fe基合金粉末成功修复大型轧辊的实例。     

Preparation, thermal stability, and magnetic properties of Fe---Co---Zr---Mo---W---B bulk metallic glass

A bulk metallic glass (BMG) cylinder of Fe₆₀Co₈Zr₁₀Mo₅W₂B₁₅ with a diameter of 1.5 mm was prepared by copper mould casting of industrial raw materials. The amorphous state and the crystallization behavior were investigated by X-ray diffraction (XRD). The thermal stability parameters, such as glass transition temperature (T_g), crystallization temperature (T_x), supercooled liquid region (ΔT_x) between T_g and T_x, and reduced glass transition temperature T_rg (T_g/T_m) were measured by differential scanning calorimetry (DSC) to be 891, 950, 59 K, and 0.62, respectively. The crystallization process took place through a single stage, and involved crystallization of the phases -Fe, ZrFe₂, Fe₃B, MoB₂, Mo₂FeB₂, and an unknown phase, as determined by X-ray analysis of the sample annealed for 1.5 ks at 1023 K, 50 K above the DSC peak temperature of crystallization. Mössbauer spectroscopy was studied for this alloy. The spectra exhibit a broadened and asymmetric doublet-like structure that indicated paramagnetic behavior and a fully amorphous structure. -Fe was found in the amorphous matrix for a cylinder with a diameter of 2.5 mm. The success of synthesis of the Fe-based bulk metallic glass from industrial materials is important for the future progress in research and practical application of new bulk metallic glasses.