陆东凹陷油气藏烃类组成非均质性及其意义

陆东凹陷原油和油砂抽提物中烃类的宏观组成存在着明显的非均质性。在高孔隙度(>15%)储层单元中,饱和烃的含量高,占总组成的含量均大于40%,而极性化合物则相对较低,一般不足40%;相反,在低孔隙度(<15%)储层单元中,饱和烃的含量明显降低,而极性化合物则显著增加。此外,陆东凹陷原油和油砂抽提物中烃类成熟度亦存在着非均质性:在高孔隙度储层中,原油和油砂烃类的成熟度参数高,而在低孔隙度储层中原油和油砂烃类的成熟度参数低。根据原油和油砂抽提物中烃类的宏观组成特征和成熟度参数的变化规律,提出了陆东凹陷油气聚集模式。     

天然气井井筒及井口安全技术研究

天然气勘探开发具有高温、高压、高风险,安全技术及管理难度大等特点,通过实例分析天然气井存在的主要问题,提出应采取的关键安全技术及需要解决的问题。     

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鄂尔多斯盆地油气资源丰富 ,目前已累计探明天然气地质储量 1 18× 10 12 m3 ,成为了中国第一个天然气探明储量超过万亿立方米的大气区。长庆油田作为盆地勘探的主体 ,在 30余年的天然气勘探历程中 ,经历曲折和挫折 ,终于取得了令人瞩目的突破。靖边下古生界气田 (长庆气田 )的发现 ,即是解放思想 ,重新认识 ,改变构造成藏的认识 ,提出风化壳古地貌成藏认识的结果 ;榆林气田和苏里格气田的探明 ,则是解放思想 ,提出上古生界大面积含气背景下 ,存在高渗储层而坚持勘探的成果。天然气勘探取得突破是勘探者解放思想 ,对盆地特征重新认识 ,应用勘探新理论 ,改变勘探思路的结果。     

Hydrocarbon exploration risk evaluation through uncertainty and sensitivity analyses techniques

The evaluation of the exploration risk in the oil industry is a fundamental component of the decision process related to the exploratory phase. In this paper the two basic components of the exploratory risk: trap geometry and trapped hydrocarbon quantities (fluid), are compounded in a single coherent uncertainty and sensitivity approach. The results clarify that the model geometry influences each Petroleum System Modeling step and that the geometric uncertainty is correlated with the fluid uncertainty. The geometric uncertainty evaluation makes use of geostatistical techniques that produce a number of possible realizations of the trap geometry, all compatible with available data. The evaluation of the fluid uncertainty, through a Monte Carlo methodology, allows us to compute the possible quantities of oil and gas, generated in a basin and migrated from the hydrocarbon source location to each single trap. The final result is the probability distribution of oil and gas for each trap in the basin, together with other useful indicators like: the hydrocarbon filling probability map, the closure probability map, the drainage area probability map, the spilling paths probabilities, the trap-filling scenarios.     

Ru-catalyzed anode materials for direct hydrocarbon SOFCs

A solid oxide fuel cell using a thin ceria-based electrolyte film with a Ru-catalyzed anode was directly operated on hydrocarbons, including methane, ethane, and propane, at 600 °C. The role of the Ru catalyst in the anode reaction was to promote the reforming reaction of the unreacted hydrocarbons by the produced steam and CO₂, which avoided interference from steam and CO₂ in the gas-phase diffusion of the fuels. The resulting peak power density reached 750 mW cm⁻² with dry methane, which was comparable to the peak power density of 769 mW cm⁻² with wet (2.9 vol.% H₂O) hydrogen. More important was the fact that the cell performance was maintained at a high level regardless of the change in the methane utilization from 12 to 46% but was significantly reduced by increasing the hydrogen utilization from 13 to 42%. While the anodic reaction of hydrogen was controlled by the slow gas diffusion, the anodic reaction of methane was not subject to the onset of such a gas-diffusion process.     

油田勘探数据中心及辅助支持系统研究

文章简要介绍胜利油田近年来致力于勘探数据中心建设及辅助支持系统研究的背景、主要研究内容及进展情况,探讨了石油勘探行业在信息化时代利用先进的数据管理理念和技术对勘探工作提供数据支持和应用支持的尝试,对于其它油田勘探行业具有一定的借鉴意义。     

应用烃类直接检测技术预测天然气藏

柴达木盆地位于青藏高原北部，是中国大型含油气盆地之一，历经４０年的勘探，发现了丰富的油气资源。柴达木盆地东部地区是第四纪沉降与沉积中心，区内第二系生储气岩厚度大、分布广、第四纪新构造运动形成的同生沉积构造发育、保存完整、具有形成大中型天然气田的地质条件。此外，由于该地区含气地层时代新、埋藏浅、成岩与胶结作用差、含气层厚度大、孔渗性好，加之构造条件简单，人文干扰小、是应用烃直接检测技术寻找天然气的有     

The initial behaviour of freshly etched copper in moderately acid, aerated chloride solutions

When freshly etched samples of various types of copper were exposed in moderately acid, aerated chloride solutions, two phenomena were observed. First the corrosion potential and the pH of the solution decreased over a shorter time, then the potential increased over a long period (600-1500 min), following an s-shaped pattern. Increase in pH during the second stage was avoided using a pH-stat. The corrosion rate increased little or not at all over the entire period. A tentative interpretation of the short-term behaviour is presented with some reservation. The long-term development of the potential suggests phase formation or transformation following the Avrami pattern. By suitable derivations it was possible to fit the development of potentials to the Avrami equation. Subsequent examinations by Auger spectroscopy proved the presence of thin layers of Cu₂O on the copper surfaces, increasing in thickness with exposure time. The dissolution kinetics can be described in terms of two parallel electrochemical reactions and a simultaneous non-electrochemical dissolution reaction.     

跨世纪的测井找油找气高技术

人类社会即将跨入21世纪,各行各业都在预测未来技术的发展,测井行业也不例外。预测成象测井技术将是跨世纪的测井找油找气高技术。     

Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel

Biodiesel fuel is a very attractive alternative to conventional fuel and its effects in the engine performance and regulated emissions have been widely studied. However, the impact on unregulated individual compounds or chemical characteristics of exhaust emissions is not fully characterized. In this paper, the semivolatile fractions of the exhaust emissions of biodiesel blends and conventional fuel have been speciated. The results show great differences between the compounds emitted, especially regarding oxygenated and aromatic species. Likewise, there is a clear relationship between speciated hydrocarbons and other important emissions such as total hydrocarbons (HC), particulate matter (PM), volatile organic fraction (VOF) and mean particle diameter (Dm) of PM.