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2.
M. Aigner M. Zeilinger H. Hofbauer 《Chemical Engineering and Processing: Process Intensification》1995,34(6):515-520
The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas. 相似文献
3.
4.
Gregory S. Ho Chen Huang Emily A. Carter 《Current Opinion in Solid State & Materials Science》2007,11(5-6):57-61
Orbital-free density functional theory (OF-DFT) can be made to scale linearly with sample size, allowing thousands of atoms to be treated explicitly with quantum mechanics. State-of-the-art kinetic energy density functionals and ion–electron pseudopotentials are used to obtain accurate structural property predictions for nanoparticles, nanowires, extended surfaces, and nanoindentation of simple metals. 相似文献
5.
It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.
An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi2 and TiB2 and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure. 相似文献
6.
Jeong-Woo Choi Jun Hyo Park Shin Chul Lee Dong-Il Kim Won Hong Lee 《Korean Journal of Chemical Engineering》1995,12(5):528-534
The on-line sensing of viable cell weight in plant cell culture process is applied to analysis and control of process. The
fiber-optic fluorescence sensor was constructed to measure the NADH-dependent fluorescence inNicotiana tabacum plant cell culture and the analysis of fluorescence signal was done to be correlated with the viable cell weight. The structured
kinetic model for cell growth was proposed to estimate the theoretical viable cell weight. The dimensional analysis was proposed
for the interpretation of fluorescence signal, in which the path length, the inner filter effect and the hydrodynamic conditions
were considered as the key factors on fluorescence signal. The dimensional analysis and empirical correlation of fluorescence
signal to viable cell weight was applied to the interpretation of the detected fluorescence signal during cultivation. The
proposed interpretation of fluorescence signal using dimensional analysis was well correlated with the viable cell weight
estimated by the structured kinetic model as well as by empirical correlation. 相似文献
7.
The methodology of response reactions (RERs) introduced earlier from thermodynamic and kinetic considerations is used in this work to develop a new algorithm for the classification and enumeration of unique/direct reaction routes (RRs) and overall reactions (ORs). According to the RERs approach, a unique set of both RRs and ORs may be generated starting from any conceivable set of linearly independent RRs and ORs. In particular, the direct ORs may be most conveniently enumerated starting from the formula matrix of the terminal species (reactants and products), i.e., without any relation to the elementary reactions comprising the detailed mechanism. Depending on the type of ORs produced by the RRs one can distinguish between two distinct types of direct RRs. Namely, one option is to define a direct RR by specifying the intermediate species that need to be eliminated. This type of RR is referred to as Milner RRs. The other option is to require the direct RRs to produce RERs, thus resulting in RRs referred to as Happel-Sellers RRs. 相似文献
8.
Summary We introduce a very simple model for thermally activated atomic migration on a lattice, and several techniques to handle it. For thermodynamical systems, the model can be used for simulating decomposition paths taking into account relevant metallurgical features. Close to equilibrium, the simplest mean-field approximation of the model can be linearized with respect to the departure from equilibrium; one then gets a microscopic interpretation of classical phenomenological coefficients, such as mobility, interfacial transfer coefficient, rate constants for the coupled relaxation of concentration and order fields. Further away from the equilibrium, the nonlinearities can be taken into account in a consistent way. For driven alloys, i.e. alloys submitted to external forcing, forced atomic migration is added to the model and new features emerge: the model is supported by several experimental results some of which confirmed its predictions a posteriori. 相似文献
9.
饮用水氯化中氯仿形成的动力学模式 总被引:12,自引:0,他引:12
以黄腐酸(FA)为卤仿前驱物质,分别测定不同投氯量、TOC水平、温度以及pH值对CHCl3形成速率的影响,确定出CHCl3形成的动力学模式。该模式可用于预测投氯后的管网水中CHCl3的形成量,以便采取必要措施保证饮用水符合国家规定CHCl3〈60μg/L的标准。 相似文献
10.
油脂氢化理论研究进展 总被引:2,自引:0,他引:2
本文从下列几个方面阐明油脂氢化理论的研究状况:(1)氢化机理的研究;(2)氢化反应动力学处理;(3)氢化反应活化能的确定;(4)氢化选择性的研究。 相似文献