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1.
The effect of the acidic hairy layer length on the interdiffusion of polymer between particles and as a consequence on the mechanical properties of the films produced from waterborne coatings has been studied. In order to isolate this effect, latexes with the same particle diameter and molecular weight but stabilized with poly(acrylic acid)-block-poly(butyl acrylate) (PAA-b-PBA) block copolymers of controlled and different lengths were prepared. Tensile strength measurements showed at the macroscopic level that the presence of AA chains in the particle surface reduced the mechanical properties of the films dried at room temperature, being its effect worse the longer the AA chain length. Higher annealing temperatures erased the negative effect of the acidic hairy layer on mechanical properties. The neutralization with NaOH instead of with NH4OH also led to worse mechanical properties. These macroscopic results were supported by Fluorescence Resonance Energy Transfer (FRET) experiments that showed that at the microscopic level, the extent of interdiffusion occurred slower when the AA chains in the particles surface increased, the annealing temperature was lower and when NaOH was used as neutralizing agent instead of NH4OH. 相似文献
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Statistical studies of branched ester latex and paint properties 总被引:3,自引:0,他引:3
R. A. Prior W. R. Hinson O. W. Smith D. R. Bassett 《Progress in Organic Coatings》1996,29(1-4):209-224
Vinyl versatate, butyl acrylate and 2-ethylhexyl acrylate were compared as comonomer, for colloid-stabilized vinyl acetate latex polymers to assess their impact on latex coating properties. Vinyl versatate afforded advantages in scrub resistance, gloss, hydrophobicity and higher glass transition temperatures. Butyl acrylate developed better wet adhesion efficiency, gel content and hiding efficiency. 2-Ethylhexyl acrylate offered performance comparable to butyl acrylate in hiding efficiency, lowering copolymer glass transition temperatures, and gloss development. Combinations of these monomers, in many instances, afforded a better balance of performance properties than individual monomers alone. In the subject study, a simplex-centroid design was utilized to statistically map polymer compositions for determining the effect of comonomer composition on latex and paint film properties. In addition to developing contour maps of polymer and paint properties as a function of composition, a technique for studying structure-property relationships is presented. 相似文献
3.
Properties of latex blends and its modified cement mortars 总被引:1,自引:0,他引:1
In this paper, the mechanical properties of three latex blends and the mechanical properties and chloride diffusivity of the latex-modified mortars are studied. The relationships between the properties of polymer films formed from latex blends and the properties of the latex blend-modified mortars are illustrated. The test results showed that the modified mortar with the blend of styrene-acrylic ester (SAE) and styrene-butadiene rubber (SBR) showed synergistic effect; especially the flexural strength of the SAE/SBR blend-modified mortars was about 20-40% higher than that of monolatex-modified mortars. However, the vinyl chloride-vinylidene chloride copolymer (PVDC)/SBR and PVDC/SAE blends-modified mortars showed antisynergistic effect. The compressive strength of the modified mortars increased with the increasing of the tensile strength of the latex films, while the flexural strength of the modified mortars did not depend on the tensile strength of the latex films. When PVDC with the mass fraction of 0.2 or SAE copolymer emulsion with mass fraction of 0.4 was blended into SBR latex, the latex blend-modified mortars showed lower chloride diffusivity. The chloride diffusivity of the modified mortars increased approximately linear with the tensile strength of the latex blend films, and decreased with increase of the elongation at rupture of the latex blend films. When the elongation at rupture of the latex blend films increased from 200-300% to more than 800%, the chloride diffusivity of the modified mortars decreased from 10-15×10−12 to 3-4×10−12 m2/s. 相似文献
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M.L. Jackson 《Polymer》2004,45(21):7229-7238
We examined drying in solventborne and waterborne latex impregnating resins using gravimetric methods, focusing on the precipitation of dicyandiamide (DICY) curing agent during coalescence, in neat resin films and glass-reinforced composites. A two-stage drying model was applied to the drying data yielding a threshold concentration for DICY surface segregation in latex epoxy to be between 3 and 4.5 wt%. Faster drying kinetics correlated with reduced surface DICY segregation. Drying model results show the rapid coalescence of both a ‘skin’ layer in the drying latex and trapped DICY within the lattice before its conveyance to the surface by percolating water. The presence of dispersed obstructions led to deviations from the latex drying model, particularly at higher DICY concentrations as more DICY crystallized. 相似文献
7.
从金银线专用烘漆的工艺和性能要求出发,探讨了聚酯真空镀铝膜(VMPET)烘漆的配方设计的要素,实验优选出氨基烘漆体系,研究表明氨基树脂和成膜树脂是获得高性能烘漆的重要因素,通过优选氨基烘漆配方各组分,可获得具有较高应用性能的金银线专用烘漆。 相似文献
8.
Polymer coatings with periodic topographic patterns, repeating over millimetre length scales, can be created from lateral flows in an aqueous dispersion of colloidal particles. The flow is driven by differences in evaporation rate across the wet film surface created by IR radiative heating through a shadow mask. This new process, which we call IR radiation-assisted evaporative lithography (IRAEL), combines IR particle sintering with the concept of evaporative lithography. Here, a series of experiments has been conducted in which the mass of the latex is measured as a function of the exposure time under infrared radiation through a mask. The water evaporation rates and the minimum exposure time required for a dry film are estimated as a function of the power density of the IR emitter. The temperature of the wet film is monitored to avoid overheating and boiling of the water, which will otherwise cause defects. It is demonstrated that textured films can be created on a variety of substrates (plastics, metals, paper and glass), and processing times can be as short as 5 min. We use IRAEL to decorate household goods with an aesthetic coating with the desired texture. 相似文献
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