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排序方式: 共有547条查询结果,搜索用时 46 毫秒
1.
尼龙1010的流变性能研究 总被引:2,自引:2,他引:0
用XLY-Ⅱ重型毛细管流变仪研究了尼龙1010的流变特性。实验结果表明,尼龙1010为假塑性流体;在210~250℃范围内,其非牛顿指数π为0.63~0.71;恒γw'下的粘流活化能随γw'的增大而减小。 相似文献
2.
Structural changes in the Brill transitions of Nylon 10/10 and its model compounds have been investigated by carrying out the temperature-dependent measurements of X-ray diffraction and infrared spectra along with the DSC measurement. The crystal structure at room temperature was found to be the so-called α form with the all-trans zigzag methylene segments. When the samples were heated, the infrared progression bands of the methylene segments, which are sensitive to the length of all-trans segmental parts, were found to change their spectral patterns in the transition temperature region: the progression bands decreased in intensity and disappeared above the transition region. At the same time several new bands were observed to appear, which were found to correspond to the progression bands of (CH2)7-(CH2)5trans-zigzag segments. These spectral changes indicate that the methylene segments were conformationally disordered by an invasion of some gauche bonds and as a result the effective length of trans-zigzag segments became shorter. This conformational disordering was found to occur more remarkably in the methylene segment of NH-(CH2)10-NH part than the CO-(CH2)8-CO part. At the same time the infrared bands of amide groups, in particular the bands sensitive to the twisting angles about the CH2-amide bonds were found to show the remarkable change, indicating the local conformational change from planar-zigzag to twisted form in the CH2-amide moiety. The frequency shift of amide A band (NH stretching mode) indicated a weakening of intermolecular hydrogen bonds, which however, did not disappear up to the melting region. From these data combined with the X-ray diffraction data, the structural disordering in the Brill transition phenomena was deduced concretely. 相似文献
3.
Y. D. Zhu G. C. Allen J. M. Adams D. Gittins M. Herrero P. Benito P. J. Heard 《应用聚合物科学杂志》2008,108(6):4108-4113
Layered double hydroxides (LDHs), a newly emerging 2D host material, consist of cationic brucite-like layers and exchangeable interlayer anions. In this work, the morphology and dispersion of LDH particles in LDH/Nylon 66 (salt) nanocomposites has been investigated using focused ion beam (FIB) techniques, transmission electron microscopy (TEM) and X-ray diffraction (XRD). The FIB images show that LDHs are present in the polymer phase dispersed to different degrees, with partial intercalation, exfoliation, and aggregation all being observed. The most even dispersion was achieved in nanocomposites with the lowest loading (0.5 wt % LDH). Residual tactoids and agglomerates were most common in the samples made with the highest concentration of LDHs studied here (5 wt %). The dispersion observed using FIB was consistent with TEM and XRD analysis, yet this technique had significant benefits in terms of time and simplicity over these “conventional” technologies. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
4.
用化学还原法制得了尼龙6表面金属(Ni)化膜材料。研究了还原条件,金属盐浓度对膜材料电性能的影响,以及膜材料的电发热性能,用光电子能谱和扫描电子显微镜对其表面及形貌进行了表征。 相似文献
5.
玻纤增强石油发酵尼龙的热稳定性研究 总被引:1,自引:0,他引:1
利用热重动力学方法研究了玻纤增强PF尼龙(即石油发酵尼龙)的热稳定性能。玻纤和偶联剂均对PF尼龙具有热稳定化作用,且硅烷A1100对PF尼龙的热稳定化作用最为显著。 相似文献
6.
锦纶66浸胶帘子布生产中的张力与控制 总被引:2,自引:0,他引:2
分析了帘子布生产中张力的作用及各区段的张力情况。张力应根据生产品种及浸胶帘子布的内在质量要求来选择,一般张力设定依据为拉伸区张力是干燥区张力的1倍,定型区张力是拉伸区张力的0.65倍。同时应控制好各区段的温度,降低拉伸应力使锦纶66帘子布拉伸均匀,提高帘子布的物理性能。 相似文献
7.
氧化钕填充尼龙6的结晶行为 总被引:6,自引:1,他引:6
利用示差扫描量热仪(DSC)研究了氧化钕(Nd2O3)对尼龙6(PA6)等温结晶行为的影响。结果表明,Nd2O3在PA6体系中起到了异相成核作用,提高了PA6的晶体增长速率。 相似文献
8.
PC/PA1010共混物的热行为 总被引:2,自引:0,他引:2
利用热失重、微分热失重和显示扫描量热法研究了聚碳酸酯/尼龙1010共混物的热行为和解降解过程。结果表明:共混物在600℃以下分两步降解,降解温度随尼龙1010用量增加有下降趋势;共混物的熔点随尼龙1010用量增加而升高。 相似文献
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