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1.
We demonstrate that alkali-halide salts, particularly potassium bromide, can reduce the photothermal emission (PTE) from single walled carbon nanotubes (SWNT). PTE is a prominent spectral feature in Raman spectroscopy when a near infrared laser is used to analyze a dark colored sample. We subsequently show that trapping salts inside SWNT and coating SWNT with the salt has a more pronounced impact on not only reducing PTE, but also enhancing the intensity of the Raman spectral features. The effect, which we have called nanotube enhanced Raman spectroscopy (NERS), has differences and similarities to the widely studied surface enhanced Raman spectroscopy (SERS).  相似文献   
2.
High magnetic fields are one of the most powerful tools available to scientists for the study, modification and control of matter. This includes the knowledge on correlations effects, interaction mechanisms, structural information and understanding of mesoscopic effects. In this context, a review of recent scientific achievements at the Grenoble High Magnetic Laboratory is given to illustrate, on specific examples, the power of the Magnetic Field probe.  相似文献   
3.
Absorption spectra of several types of diesel fuel are studied experimentally. Index of refraction of these fuels is calculated using subtractive Kramers-Krönig analysis. The ageing process of fuels is simulated by prolonged boiling. Radiative properties of diesel fuel droplets are calculated using the Mie theory and a simplified approach, based on approximations of absorption and scattering efficiency factors. It is pointed out that the accuracy of the simplified approach is sufficient for practical applications in the visible and infrared ranges, for various types of diesel fuel, and for droplet radii in the range from 5 to 50 μm. The monodisperse approximation is shown to be applicable for the analysis of infrared radiative properties of realistic polydisperse diesel fuel sprays.  相似文献   
4.
弹性波衍射CT   总被引:1,自引:0,他引:1  
刁顺  杨慧珠  许云 《石油物探》1994,33(3):47-53
本文直接从等价于弹性动力学Navier方程的耦合齐次与非齐次矢量波动方程组出发,围绕弹性波衍射CT展开了理论研究,尤其是其非齐次方程含有震源项,同时适合P波和S波,考虑爆炸震源,引进塑性半径,运用张量运算,推导了Born近似下散射波谱与目标函关系,得到二种数据采集方式下的层析成像FBP公式,可同时适用于P波和S波,尽管与以往不涉及震源项的结果相似,但本结果更符合地震勘探情况。  相似文献   
5.
提出一种求解正常声光相互作用拉曼 内斯 (Raman Nath)方程的矩阵级数解法 ,该解法直观方便且具有普遍性。计算结果表明 ,对Q =4 1π ,Bragg衍射的效率只有 97 5 % ;对非对称入射 ,以往的Raman Nath近似解误差较大 ;指出提高Bragg衍射效率的有效途径在于提高声光频率比并给出计算声光器件最优长度的计算公式。  相似文献   
6.
The structural properties and hydrogen bonding of undoped and phosphorous doped polycrystalline silicon produced by step-by-step laser dehydrogenation and crystallization technique were investigated using Raman spectroscopy and hydrogen effusion measurements. At low laser fluences, EL, a two-layer system is created. This is accompanied by the change in hydrogen bonding. The intensity of the Si–H vibration mode at 2000 decreases faster than the one at 2100 cm−1. This is even more pronounced in phosphorous-doped specimens. The laser crystallization results in an increase of the hydrogen binding energy by approximately 0.2–0.3 eV compared to the amorphous starting materials.  相似文献   
7.
Distributed Optical Fiber Sensor for Multi-point Temperature Measurement   总被引:1,自引:0,他引:1  
The distributed optical fiber sensing technology is overviewed, which is based on Raman scattering light theory. Basic operation principle, structure, system characteristics and signal processing are discussed. This structure and method of the signal processing possess of certain spatial resolution, hence will ensure the practicability of system.  相似文献   
8.
中子辐照金刚石生成卡宾碳   总被引:3,自引:3,他引:0  
金刚石在中子辐照下发生相转变,得到了线性结构的卡宾碳。所得产物为覆盖金刚石表面的黑色薄膜状物质,其拉曼光谱在2191cm-1处有强峰,归属于C≡C伸缩振动;同时,其俄歇电子谱的峰位与金刚石相比有5eV的位移,证实了卡宾碳的存在。在中子辐照条件下,金刚石向卡宾碳的转化可能是通过碳原子堆垛形式发生变化而实现的。  相似文献   
9.
In this paper, we present the theory for calculating Raman line shapes as functions of the Fermi energy and finite temperatures in zinc blende, n-type GaAs for donor densities between 1016 cm−3 and 1019 cm−3. Compared to other theories, this theory is unique in two respects: 1) the many-body effects are treated self-consistently and 2) the theory is valid at room temperature for arbitrary values of the ratio R = (Q2/α), where Q is the magnitude of the normalized wave vector and α is the normalized frequency used in the Raman measurements. These calculations solve the charge neutrality equation self-consistently for a two-band model of GaAs at 300 K that includes the effects of high carrier concentrations and dopant densities on the perturbed densities of states used to calculate the Fermi energy as a function of temperature. The results are then applied to obtain the carrier concentrations from Fermi energies in the context of line shapes in Raman spectra due to the coupling between longitudinal optical phonons and plasmons. Raman measurements have been proposed as a non-destructive method for wafer acceptance tests of carrier density in semiconductor epilayers. The interpretation of Raman spectra to determine the majority electron density in n-type semiconductors requires an interdisciplinary effort involving experiments, theory, and computer-based simulations and visualizations of the theoretical calculations.  相似文献   
10.
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