Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

暖通空调工程设计常见问题

通过对施工图审查工作进行总结，指出了暖通空调和防火防排烟设计中存在的问题及防火规范本身的一些不足。     

预应力混凝土箱梁主要裂缝成因和防治措施的探讨

预应力混凝土连续箱梁的裂缝问题一直以来倍受桥梁界专家及技术人员的关注。本文通过对预应力混凝土连续箱梁主要裂缝产生的原因进行了浅析，并提出了相应的防治的措施。     

马鞍山煤矿瓦斯地质理论在防突工作中的应用

总结了实际工作中防突管理的经验和问题 ,探讨了科学理论与具体实际的有机结合与统一 ,采取针对性强的有效措施 ,确保突出矿井的安全生产     

油基钻井液的推广及循环利用

针对普通水基钻井液在钻进中强、强水敏性油藏时会造成储层污染、产量降低的问题,指出了油基钻井液在钻进该类油藏时的优势和其成本高、对生态环境有污染的缺点。为了大面积推广应用油基钻井液,重点介绍了油基钻井液的特性和稳定性影响因素,并通过室内评价证明了油基钻井液在油层保护中的良好效果,着重阐述了油基钻井液在王庄油田的现场应用情况,并探讨了油基钻井液的循环利用技术。研究结果表明,油基钻井液不仅具有良好的油层保护效果,而且具有较好的社会经济效益。     

Red Wine Polyphenols for Cancer Prevention

Conventional cancer therapies, the second leading cause of death worldwide, result in serious side effects and, at best, merely extend the patient''s lifespan by a few years. Searching for effective prevention is of high priority in both basic and clinical sciences. In recent decades natural products have been considered to be an important source of cancer chemopreventive agents. Red wine polyphenols, which consisted of various powerful antioxidants such as flavonoids and stilbenes, have been implicated in cancer prevention and that promote human health without recognizable side effects. Since resveratrol, a major component of red wine polyphenols, has been studied and reviewed extensively for its chemopreventive activity to interfere with the multi-stage carcinogenesis, this review focuses on recent progress in studies on cancer chemopreventive activities of red wine polyphenol extracts and fractions as well as other red wine polyphenols, like procyanidin B5 analogues and myricetin.     

计算机网络安全问题及防范对策

文章简单阐述了当前计算机网络所面临的主要安全威胁,并在此基础上提出了分层控制的方案,建立了不同层次间网络安全的防范措施,希望以此来提高网络安全性。     

KYN44-12型中置柜联锁装置的改进设计

介绍了12kV中置柜联锁装置的设计原则,分析了现有中置柜联锁装置在实际运行中存在的问题和不足,提出了改进和完善中置柜联锁装置的设计方法。实际应用表明,改进后的中置柜联锁装置的功能更加完善,安全性更加可靠,完全达到了五防闭锁要求。     

网络蠕虫的检测防治技术研究

随着网络系统应用的普及和其复杂多变性,网络蠕虫已对网络安全造成极其严重的威胁。本文介绍了网络蠕虫的定义和检测策略,对几种常用的网络蠕虫检测防御技术进行了比较,分析了它们的优点和不足,同时对未来网络蠕虫检测防治技术研究提出了几点建议。