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1.
Ken Kato Yasuhiro Kasuga Masanori Fujiwara Kazuo Onda 《Electrical Engineering in Japan》1996,116(4):94-108
Laboratory-scale and parametric experiments of SO2 and NOx removal from the simulated combustion gas by pulsed corona discharge have been performed by changing the combustion gas composition and temperature, the electrode configuration of plasma reactor, and the polarity of high-voltage electrode. The following results are obtained: 1) the higher the concentration of H2O and O2, the higher the efficiency of desulfurization and denitrification at the same specific input; 2) the pulsed corona discharge with a voltage pulsewidth as short as 200 ns of negative polarity shows the possibility to attain almost 90 percent deSOx and deNOx efficiency at the specific discharge input of 20 J/g, which is almost the same as the specific input in the electron-beam process; 3) the deNOx characteristics show a little temperature dependence in the range of 70 to 130°C, but the deSOx efficiency increases rapidly in the temperature region below 100°C suggesting the thermochemical dependence of deSOx reaction; 4) when desulfurization and denitrification proceed, the white dendritic powder deposits on the plasma reactor whose composition is identified to be 49 mol% (NH4)2SO4 and 47 mol% of 2NH4NO3 · (NH4)2SO4, and the ratio of SO2, NO and NH3 of the deposit is almost equal to that of supplied gas. 相似文献
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A combinatorial process has been developed for the high throughput production and evaluation of surface coatings. The workflow designed for the production of arrays of liquid coatings involves the robotic transfer of aliquots of solutions of raw materials to an array of glass vials and mixing of the coatings using an unconventional magnetic stirring process. An investigation of the capability of the workflow to accurately and repeatedly prepare coating arrays was conducted as a function of solution viscosity and aliquot size. In addition, mixing capability was evaluated as a function of solution viscosity, total solution volume, and mechanism of stirring. Overall, the results of the study indicated that adequate accuracy and repeatability of the coating preparation process can be achieved as long as raw material solutions are designed such that viscosity is below about 250 cP and aliquot sizes are above about 75 μl. With regard to mixing capability, total solution volume was found to have a profound affect as did the stirring mechanism. 相似文献
4.
《无机及分析化学》在多媒体教学的应用及思考 总被引:1,自引:0,他引:1
对多媒体技术在无机及分析化学教学的应用进行了,阐述和分析,指出使用多媒体教学应注意的问题。 相似文献
5.
George M. Campbell 《Chemical Engineering Communications》1990,98(1):223-230
The room temperature adsorption of PuF6(g) on a solid substrate was compared to the adsorption of UF6(g) on the same surface. Significantly more PuF6(g) was adsorbed at pressures in the range of 1.2 to 0.2torr, accompanied by the evolution of molecular fluorine. The adsorbed UF6 was easily desorbed by reducing the pressure. Most of the adsorbed PuF6 remained on the surface when subjected to the same treatment. 相似文献
6.
A correlation between the reactivity and electrical resistivity of a series of cokes was determined using cokes prepared from blends of medium- and high-volatile coals. After correcting for the ash yield of the coke and the density of the resistivity specimen, a statistically significant relation between reactivity and resistivity was established. As the resistivity test requires much less time to perform than the reactivity test, it can be considered as an alternative approach to reactivity testing currently performed for quality control purposes. 相似文献
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离子液体以其独特的性质广受关注,被称为"绿色设计者溶剂",人们对其潜在的应用价值做了大量的研究.实验采用HyperChem软件构建了1-乙基-3-甲基咪唑四氟硼酸盐([EMIM][BF4])离子液体分子结构的3D模型,并用PM3法进行预优化,然后应用Gaussian 03w程序分别在RHF/6.31G(d)和BLYP/6-31G(d)计算水平上进行量子化学计算,并经振动频率和强度分析得到理论红外谱图.结果表明,[EMIM][BF4]离子液体的阴阳离子存在着氢键等弱相互作用. 相似文献
9.
It is shown by ESR spectroscopy that Mn2+ ions in MnAPO-5 are oxidized to Mn3+ during calcination atT475 K. Mn2+ occupies variously distorted tetrahedral positions within the framework and in extra-lattice sites. Octahedrally coordinated Mn2+ presumably located in the channels becomes detectable after adsorption of water. The ESR spectra of reduced MnAPO-5 show line-narrowing due to spin exchange interactions. The material behaves reversible in redox cycles at temperatures near 500 K. 相似文献
10.
《计算机与应用化学》2000,17(1)
Δ3-1,2,4—噻二唑类化合物具有抑制黄瓜霜霉病毒的杀菌活性。本文用半经验PM3方法对25个该类化合物进行了量子化学计算,并依据原子的净电荷、前沿轨道能级、轨道主要成分及原子在前沿轨道中所占比重等计算结果和多重回归分析讨论了该类化合物的活性部位,为该类化合物结构与活性的研究奠定了理论基础。 相似文献