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1.
Enas Taha Sayed Hussain Alawadhi A.G. Olabi Aisha Jamal Menna Salah Almahdi Juiaria Khalid Mohammad Ali Abdelkareem 《International Journal of Hydrogen Energy》2021,46(8):5975-5983
Microbial fuel cell (MFC) is a promising technology for simultaneous wastewater treatment and energy harvesting. The properties of the anode material play a critical role in the performance of the MFC. In this study, graphene oxide was prepared by a modified hummer's method. A thin layer of graphene oxide was incorporated on the carbon brush using an electrophoretic technique. The deoxygenated graphene oxide formed on the surface of the carbon brush (RGO-CB) was investigated as a bio-anode in MFC operated with real wastewater. The performance of the MFC using the RGO-CB was compared with that using plain carbon brush anode (PCB). Results showed that electrophoretic deposition of graphene oxide on the surface of carbon brush significantly enhanced the performance of the MFC, where the power density increased more than 10 times (from 33 mWm?2 to 381 mWm?2). Although the COD removal was nearly similar for the two MFCs, i.e., with PCB and RGO-CB; the columbic efficiency significantly increased in the case of RGO-CB anode. The improved performance in the case of the modified electrode was related to the role of the graphene in improving the electron transfer from the microorganism to the anode surface, as confirmed from the electrochemical impedance spectroscopy measurements. 相似文献
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Tian Xie Haixia Zhao Zunhang Lv Guangwen Xie Yan He 《International Journal of Hydrogen Energy》2021,46(1):581-588
This work demonstrates a facile Nb2O5-decorated electrocatalyst to prepare cost-effective Ni–Fe–P–Nb2O5/NF and compared HER & OER performance in alkaline media. The prepared electrocatalyst presented an outstanding electrocatalytic performance towards hydrogen evolution reaction, which required a quite low overpotential of 39.05 mV at the current density of ?10 mA cm?2 in 1 M KOH electrolyte. Moreover, the Ni–Fe–P–Nb2O5/NF catalyst also has excellent oxygen evolution efficiency, which needs only 322 mV to reach the current density of 50 mA cm?2. Furthermore, its electrocatalytic performance towards overall water splitting worked as both cathode and anode achieved a quite low potential of 1.56 V (10 mA cm?2). 相似文献
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Based on the voltage and current fluctuating phenomenon in the arc plasma load under the negative-pulse-bias, usingthe plasma physics theory and analysis of computer simulation expatiates that the nature of plasma load in vacuumarc plasma is a capacitance 相似文献
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Effect of Rare Earth Element Cerium on Mechanical Properties and Morphology of TiN Coating Prepared by Arc Ion Plating 总被引:7,自引:0,他引:7
TiN coatings were deposited on polished substrates of W18Cr4V high speed steel by means of vacuum arc ion plating. The effect of cerium on adhesion between TiN coating and substrate was studied. The microstructures and composition of TiN coatings were also investigated by means of scanning electron microscope (SEM), Auger electron spectroscopy (AES), and X-ray diffraction (XRD) technique. It was found that cerium is an effective modifying agent and the addition of suitable amount of cerium to TiN coatings can produce relatively excellent properties such as micro-hardness, wear resistance, oxidation resistance and porosity. The experimental results show that the added cerium in TiN coatings makesa contribution to form the preferred direction along with a (111 ) or (222) close packed face, which may be one of the reasons that improves some properties mentioned above. 相似文献
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采用X射线衍射分析技术,研究了脉冲化学镀非晶态Ni-P合金的原子分布和函数,得出其短程有序原子集团的尺度为0.754nm,约为熔体激冷法获得的非晶态Ni-P合金短程有序畴的1/2。并利用脉冲化学沉积非晶态合金的微机制择这一结果进行了解释。 相似文献
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制备了导电聚苯胺锂基润滑脂(简称PANI脂)和铜基银镀层材料(简称银层材料)。采用摩擦磨损试验机考察在无载流、载流及边界润滑条件下,铜基体材料(简称铜基材料)和银层材料的摩擦磨损性能。采用X射线衍射(XRD)、扫描电子显微镜(SEM)和电子能谱(EDS)对银层材料晶相及其表面磨斑形貌进行表征。结果表明,载流条件下,PANI脂润滑试验时的银层材料不仅具有良好的减摩抗磨性能,而且导电能力更强,其优异的减摩和抗磨性能归功于摩擦表面的保护膜和电流热效应引起的表面软化双重作用。 相似文献
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