Biotransformation of l‐menthol by twelve isolates of soil‐borne plant pathogenic fungi (Rhizoctonia solani) and classification of fungi

The microbial transformation of l‐menthol ( 1 ) was investigated by using 12 isolates of soil‐borne plant pathogenic fungi, Rhizoctonia solani (AG‐1‐IA Rs24, Joichi‐2, RRG97‐1; AG‐1‐IB TR22, R147, 110.4; AG‐1‐IC F‐1, F‐4, P‐1; AG‐1‐ID RCP‐1, RCP‐3, and RCP‐7) as a biocatalyst. Rhizoctonia solani F‐1, F‐4 and P‐1 showed 89.7–99.9% yields of converted product from 1 , RCP‐1, RCP‐3, and RCP‐7 26.0–26.9% and the other isolates 0.1–12.0%. In the cases of F‐1, F‐4 and P‐1, substrate 1 was converted to (?)‐(1S,3R,4S,6S)‐6‐hydroxymenthol ( 2 ), (?)‐(1S,3R,4S)‐1‐hydroxymenthol ( 3 ) and (+)‐(1S,3R,4R,6S)‐6,8‐dihydroxymenthol ( 4 ), which was a new compound. Substrate 1 was converted to 2 and/or 3 by RRG97‐1, 110.4, RCP‐1, RCP‐3 and RCP‐7. The structures of the metabolic products were elucidated on the basis of their spectral data. In addition, metabolic pathways of the biotransformation of 1 by Rhizoctonia solani are discussed. Finally, from the main component analysis and the differences in the yields of converted product from 1 , the 12 isolates of Rhizoctonia solani were divided into three groups based on an analysis of the metabolites. Copyright © 2003 Society of Chemical Industry     

基于LotusNotes的文档ID应用剖析

介绍了文档数据库Lotus Domino／Notes的特点．对其文档处理的核心，即Notes文档的ID构成机制作了系统剖析．并在此基础上分析了如何在文档复制中运用ID的不同组件以及如何运用API程序访问文档ID等。     

Platinum Binuclear Complexes as Phosphorescent Dopants for Monochromatic and White Organic Light‐Emitting Diodes

Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula C^∧NPt(μ‐pz)₂PtC^∧N (where C^∧N = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C^2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m^–2, a brightness of 3900 Cd m^–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (～ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (～ 5 %) and brightness (～ 600 Cd m^–2 at 10 V).     

光电设备电子机柜布线工艺研究

作为信号和电能载体的导线，同时也是噪声的载体和外来噪声侵入设备的媒体。描述了噪声通过导线侵入设备内部的方式，通过降低噪声的途径确定了机柜布线的原则，介绍了布线的要求和方法，最后提出了用布线槽布线的建议。     

用PB和ORACLE方法实现身份证号升位

在对人员的管理工作中 ,需经常使用姓名和身份证号来进行人员检索。身份证号所具有的唯一性 ,决定了它成为表征一个人信息的准确特征。原有的 15位身份证号存在着“2 0 0 0年”问题 ,需升至 18位。本文分别用PB和ORACLE两种语言方式 ,讲述了实现身份证号升位的方法。     

身份管理渐行其道

目前人们面临的网络安全问题越来越严峻，不仅包括计算机病毒、垃圾电子邮件等的挑战，对信息资源的有效存取保护要求也在提高。身份管理技术能对用户身份标识进行集中与简化管理，实现安全、简便登录等功能，不但削减了投入和维护成本，还提高了效率，因此近来得到迅速发展。2003年的调查显示，身份管理在安全产品市场增幅达45％；在各企业应用普及率已达到17.9％。但身份管理还需要解决提高单点登录安全性，实施多方可靠数字身份以及本身复杂性等问题。     

SDH光网络中的ID与IP地址

随着IP技术的迅速发展和应用以及SDH光传输设备在现代通信网络中的广泛应用。大空对ID与IP的认识也不断深入。本文首先比较深入地讨论了ID与IP地址的基本概念，与此同时，阐述了二者的关系和区分；接着，讨论了子网掩码的相关内容；最后，介绍了在实际工作中非常有用的两条命令及其用法。     

电子商务中的PKI、SSL与SET的技术分析

PKI是目前在电子商务中安全传输方案，SSL和SET两种安全的电子交易协议，在网上交易中有着广泛地应用，是大多数在线支付所采用的支付协议。这里在探讨PKI、SSL、SET技术原理的基础上，对它们各自的作用、技术实现、工作漉程等进行了描述；对它们之间的联系、区别、应用范围进行了深入的分析。     

微波非接触式智能卡中射频系统和电路的设计实现

采用了Agilent公司ADS2002软件、Ansoft公司的Ensemble软件对微波非接触智能卡中射频系统和电路进行了仿真和设计。主要进行收发信道性能的仿真、天馈系统设计以及各单元电路之间匹配电路的设计。