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排序方式: 共有221条查询结果,搜索用时 15 毫秒
1.
不饱和烃硅氢加成催化剂固载化研究进展 总被引:3,自引:2,他引:1
综述了各类负载过渡金属的催化剂体系及其在不饱和烃硅氢加成反应中的应用。负载过渡金属的催化剂具有良好的可回收性和选择性,研究主要集中在开发价廉、使用安全、环境友好和高催化性能的活性炭、氧化物或有机聚合物等负载过渡金属催化剂,并取得很好的结果。 相似文献
2.
Methylmethacrylate (MMA) and octadecyl acrylate (OA) were grafted to poly(methylhydrosiloxane) (PMHS) by hydrosilylation, respectively, with hexachloroplatinic acid as catalyst, and the former was further hydrolyzed to prepare methacrylic acid (MAA)‐graft‐PMHS under the alkaline condition. Through orthogonal experiment, main factors affecting the graft reaction between OA and PMHS were discussed and arranged in a decreasing order according to their abilities of the effect on the hydrosilylation of OA with PMHS: catalyst dosage, reaction temperature, reaction time, material ratio, and solvent dosage. It was found that the hydrosilylation of OA with PMHS was easier to that of MMA with PMHS. Under optimal conditions, the grafting ratios of MMA with PMHS and OA with PMHS reached about 90 and 95%, respectively. FTIR and 1H NMR spectra indicated that the hydrosilylation reactions followed the Markovnikov's rule and played a strong preference toward β‐1,2‐addition. The test of contact angle indicated that surface energy of a system was mainly dependent on the polar groups. The surface energy of OA‐graft‐PMHS (35.07 mN/m) was similar to those of PMHS (35.62 mN/m) and polyoctadecyl acrylate (36.57 mN/m), and lower than that of MAA‐graft‐PMHS (43.50 mN/m). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
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Theresa E. Gentle Alan R. Bassindale 《Journal of Inorganic and Organometallic Polymers》1995,5(3):281-294
We have recently reported the synthesis of octopus molecules of defined shape and size with molecular weights well into the thousands. These octopus molecules were made by placing eight pendant groups symmetrically about a central silsesquioxane core via the H2PtCl6 catalyzed hydrosilylation of 1-alkenes as well as vinyl- and allyl-siloxanes by T8 hydrogen silsesquioxane, (HSiO32)8. The chemistry of addition was studied and it was found that while the addition of the 1-alkenes to T8 was regioprecise with only -addition being observed, both - and -addition occurred with vinyl-siloxane. In addition, H-vinyl exchange on silicon was observed to occur with addition of vinyl-siloxane to T8. In the current studies, the effect of the hydrosilylation catalyst. homogeneous and heterogeneous, on the regioselectivity of addition and on the extent of exchange on silicon was evaluated. It was found that the heterogeneous catalysts Pt–C, sulfided Pt–C, and Rh–C required higher temperature and longer times to get complete reaction than the homogeneous catalysts. H2PtCl6 and the tetramethyldivinyldisiloxane complex of Pt. Pd supported catalysts were not effective catalysts for this hydrosilylation. The extent of exchange on silicon and the degree of the second mode of addition occurring were higher with the heterogenous catalysts and may be a result of the higher reaction temperatures. 相似文献
5.
以甲基二氯硅烷和甲醇为原料,采用气-液相反应法合成出甲基二甲氧基硅烷;然后,将甲基二甲氧基硅烷与3,3,3-三氟丙烯在铂催化剂作用下进行硅氢加成反应,得到3,3,3-三氟丙基甲基二甲氧基硅烷。考察了原料配比、填料种类等因素对醇解反应的影响以及铂催化剂的种类、用量、反应温度等对加成反应的影响。结果表明,最优合成条件为:在醇解反应中,甲基二氯硅烷与甲醇的量之比为1∶1·8、醇解温度50℃、甲醇滴加速度2mL/min、N2流量80mL/min,在此条件下,甲基二甲氧基硅烷的收率为86%;在加成反应中,采用自制的铂催化剂,当铂催化剂与甲基二甲氧基硅烷的量之比为3·0×10-4∶1、反应温度为120℃时,3,3,3-三氟丙基甲基二甲氧基硅烷的收率达90%。此法可有效提高3,3,3-三氟丙基甲基二甲氧基硅烷的收率。 相似文献
6.
十二烷基三甲氧基硅烷的合成 总被引:1,自引:2,他引:1
以三氯氢硅、1-十二碳烯为原料,在铂催化剂存在下合成出十二烷基三氯硅烷;并以溶剂法醇解得到十二烷基三甲氧基硅烷。考察了催化剂用量、原料配比、反应时间对加成反应的影响,溶剂、原料配比、温度等因素对醇解反应的影响。最佳反应条件为:在加成反应中,当铂催化剂与三氯氢硅的量之比为3.6×10-4∶1、三氯氢硅与1-十二碳烯的量之比为1.15∶1时,十二烷基三氯硅烷的收率达81%,反应在室温下无诱导期即可发生、且无需改变加料方式、反应时间短、副反应少、收率高;醇解反应采用溶剂法,将十二烷基三氯硅烷滴加到甲醇中,十二烷基三氯硅烷与甲醇的量之比为1∶3.2,底温控制在70℃,N2流量为80 mL/min,十二烷基三氯硅烷的滴加速度为1 mL/min,十二烷基三甲氧基硅烷的收率为85%。 相似文献
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加成型硅橡胶硫化过程中催化剂的活性抑制和防失效研究 总被引:4,自引:0,他引:4
针对某电子模块用加成型系列有机硅灌封材料体系.选用新型活性抑制剂,有效控制硅橡胶的硫化速度,并分析了导热型硅橡胶硫化过程中催化剂失效的原因,采取有效的防失效方法,成功解决了该灌封材料实际应用时硫化发粘的问题。 相似文献
9.
Zhang Ming CHEN Haiyan Chen Xiaosong Dai Shaojun Inoue Shinich OKAMOTO Hiroshi 《中国稀土学报(英文版)》2004,22(Z3)
Acrylic acid rare earth complex was prepared. Its chemical composition was determined by chemical and elemental analysis, and its structure as well as properties was characterized using IR, Fluorescence and UV spectrum, and its solubility was also investigated. Meanwhile a kind of elastic functional polymer with rare earth units in the side chains was produced. It is confirmed by IR spectrum that the Si-H bonds really react with acrylic acid rare earth. 相似文献
10.
硅氢加成反应是合成有机硅材料最重要的途径之一,铂催化剂作为其应用最广的催化剂,具有重要的意义。本文首先介绍了硅氢加成反应机理的研究现状;分析了聚合物长链段铂配合物、含多个铂原子铂簇化合物及N-杂环卡宾铂配合物均相铂催化剂的研究进展,致力于改善均相催化剂催化选择性差、催化活性难以控制等缺点;分别阐述了不同铂催化剂载体如无机二氧化硅、炭载体、金属氧化物、有机高分子、固载液等作为铂催化剂载体的优点,负载铂催化剂具有可回收、产物选择性好的优点,有效解决了工业上铂损失的问题;最后对铂催化硅氢加成反应的发展趋势进行了展望分析,铂负载能力的提高、铂负载催化剂的分离、硅氢加成反应的原理、催化范围的扩大等均是今后研究的重要方向。 相似文献