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1.
《International Journal of Hydrogen Energy》2022,47(100):41994-42000
Hydrogen technology is widely considered a novel clean energy source, and electrolysis is an effective method for hydrogen evolution. Therefore, efficient hydrogen evolution reaction (HER) catalysts are urgently needed to replace precious metal catalysts and meet ecological and environmental protection standards. Herein, Ni–Mn–P electrocatalysts are synthesized using facile electrodeposition technology. The influence of the Mn addition on the catalytic behavior is studied by the comprehensive analysis of catalytic performance and morphology of the catalysts. Among them, the Ni–Mn–P0.01 catalyst exhibits small coral-like structures, greatly improving the adsorption and desorption of hydrogen ions and reducing the overpotential hydrogen evolution. Consequently, overpotential at 10 mA cm?2 electric current density is 113 mV, and the value of the Tafel slope achieves 74 mV/dec. Furthermore, the Ni–Mn–P catalyst shows long-time (20 h) stability at current densities of 10 and 60 mA/cm2. The results confirm that the synergistic effect of Ni, Mn, and P accelerates the electrochemical reaction. Meanwhile, the addition of manganese element can change the micromorphology of the catalyst, thereby exposing more active sites to participate in the reaction, enhancing water ionization, improving the catalytic performance. This study opens a new way toward improving the activity of the catalyst by adjusting Mn concentration during the electrodeposition process. 相似文献
2.
Use of the Retarded Solution-Reprecipitation Process to Attain a Higher Initial Permeability in MnZn Ferrites 总被引:1,自引:0,他引:1
Miha Drofenik rej nidari Darko Makovec 《Journal of the American Ceramic Society》2003,86(9):1601-1604
We investigated the effect of various amounts of liquid phase on microstructure development during sintering and the resulting magnetic permeability of MnZn ferrite (MZF) samples. Our results revealed that the microstructure and the final magnetic permeability depend on the thickness of the liquid-phase film during sintering. The solution-reprecipitation (S-R) process, which is associated with an intensive microstructure development in MZF, starts when a continuous liquid-phase film of critical thickness δo , which wets the MZF grains, is formed. The solid-state sintering that takes place before the formation of the continuous liquid-phase film is essential for the final microstructure of MZF. 相似文献
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添加剂对尖晶石型锰酸锂性质表征的影响 总被引:1,自引:0,他引:1
以LiOH·H_20和MnO_2为原料,分别掺入H_2BO_3、Al_2O_3、SiO_2和P_2O_5等添加剂,用固相分段法制备尖晶石型锰酸锂。结果表明,SiO_2和P_2O_5可以有效地改善LiMn_2O_4的电化学性能,H_3BO_3对锰酸锂的电化学性能影响不大,而Al_2O_3破坏了LiMn_2O_4的电化学性能。面扫描结果显示,Si或P元素各自都均匀地分散于LiMn_2O_4的物相中。从元素电负性和原子半径的角度分析了B、Si、P和Al元素对尖晶石型LiMn_2O_4结构和性能的影响。 相似文献
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最近国外报道把EMD粉末等制成湿度敏感器的技术,但对其作用机理的解释尚有欠妥之处,本文除简介此类湿度敏感器的工艺之外,还利用我们研究水蒸气对EMDoA附的理论予以阐释,并确认其合理与否 相似文献
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The resistance to pitting corrosion of austenitic stainless steel Cr18Mn12N has been studied in model solutions of sulphuric
acid (0.5 m) containing chloride ions (0.5 m). The cyclic potentiodynamic method has been employed to investigate the effects of chloride ions and agitation rate on the
pitting and repassivation potentials. Electron and optical microscopy, electron diffraction spectroscopy and atomic absorption
spectrometry have been used to detect the surface sites for pit formation and the growth of pit nuclei. The results obtained
with chromium–manganese–nitrogen steel have been compared with those of austenitic Cr18Ni9 stainless steel. A similarity in
pit initiation is established, while steel composition exhibits no significant effect. Cr18Mn12N steel is less prone to repassivation
as compared with Cr18Ni9 steel. 相似文献
10.
从废旧锌锰电池中回收锌和锰的工艺研究 总被引:1,自引:0,他引:1
高玉华 《有色金属再生与利用》2006,(7):19-20
废旧锌锰干电池经过剖开、焙烧处理,去除汞和碳粉,再用硫酸浸取,滤液采用沉淀法分离锌和锰。锌和锰的回收率分别为94.5%和93.6%。 相似文献