Catalytic behavior in CH4 decomposition of catalysts derived from red mud: Impact of residual Na2O

Catalyst samples for CH₄ decomposition were prepared from red mud (RM) by an acid-leaching neutralization precipitation approach. Water-washing the resultant precipitates multiple times, followed by drying at 105 °C and calcination at 500 °C, resulted in a threshold of residual Na₂O, equivalent to 96% Na₂O removal. Drying the precipitate at a higher temperature of 200 °C, followed by repeated water washing, provided a deeper Na₂O removal of 99% and made the resultant samples more active for the targeted reaction. Subsequently, four catalyst samples with a simulated red mud composition and NaOH contents from 0 to 0.3 wt% were prepared and the catalytic test results revealed that the Na₂O remaining in the RM-derived catalysts did not only inhibit their activation in CH₄ but also lower their maximal activities for CH₄ decomposition. Finally, two catalysts with the same simulated red mud composition and their Na impregnated respectively on Fe₂O₃ and a mixture support of Al₂O₃-SiO₂-TiO₂ were prepared and tested to explore the effect of Na distribution on the activation behavior of RM-derived catalysts for CH₄ decomposition. The activity testing results showed that it was the Na residual dispersed on iron oxides in the RM-derived samples to significantly inhibit the activation of CH₄ decomposition.     

减水剂类型对赤泥—矿渣基地聚物注浆材料性能的影响及机理研究

针对赤泥等固体废弃物对环境危害性大且利用率低等问题,以碱激发赤泥-矿渣基地聚物注浆材料为 研究对象,研究了不同掺量的聚羧酸(PA)减水剂、醛酮缩合物(AKC)减水剂和萘系(N)减水剂对材料凝结时间、流动 性及强度等的影响,并通过 XRD、傅里叶红外光谱及 SEM 等设备对减水剂的作用机理进行研究。 结果表明:减水剂增 强了材料的流动性但降低了材料的剪切应力;N 和 PA 减水剂能缩短材料的凝结时间,但 AKC 减水剂会延长材料的凝 结时间;N 和 AKC 减水剂能提高材料的强度,但 PA 减水剂会降低材料的强度;N 减水剂对材料的综合性能提升效果 更加明显,其最优掺量为 0. 7%;减水剂对赤泥-矿渣基地聚物性能提升的作用机理主要是促进地聚合物凝胶的形成。 研究成果为拓展赤泥在工程上的使用途径和效率提供了理论指导。     

Behavior of 316L stainless steel containing corrosion pits under cyclic loading

The environmental performance of 316L grade stainless steel, in the form of tensile specimens containing a single corrosion pit with various aspect ratios, under cyclic loading in aerated chloride solutions is investigated in this study. Results from environmental tests were compared and contrasted with those obtained using finite element analysis (FEA). Fractography of the failed specimens obtained from experiments revealed that fatigue crack initiation took place at the base of the shallow pit. The crack initiation shifted towards the shoulder and the mouth of the pit for pits of increasing depth. This process is well predicted by FEA, as the strain contour maps show that strain is the highest around the centric strip of the pit. However, for shallow pits, local strain is uniformly distributed around that strip but begins to concentrate more towards the shoulder and the mouth region for increasingly deep pits.     

储层泥浆侵入深度预测方法研究

泥浆侵入半径的确定尚缺乏严格的验证标准.以油水两相渗流理论和离子扩散方程为基础,结合储集层特点,研究了不同储层参数下泥浆滤液对地层的侵入特性.数值模拟侵入时间选取10 d和20 d.数值模拟结果表明,侵入半径在渗透率不变的情况下随孔隙度的增大而减小,在孔隙度不变的情况下随渗透率的增大而增大;当渗透率和孔隙度都发生变化时,泥浆侵入半径一般随孔隙度的增加呈幂函数增加.依据这种关系对测井资料约束处理,得到的泥浆侵入半径较客观地反映了地层的真实情况.     

浅谈延迟焦化装置露天栈桥的设计

根据延迟焦化装置露天栈桥的工程设计实践,围绕一炉两塔(一个加热炉两个焦炭塔)的焦化装置,分析了露天栈桥设计中的要点及难点,对其在平面布置、基础安排和吊车梁选型等设计方面做一些介绍和论述。     

露天矿半连续工艺技术应用现状及发展前景

介绍了露天矿半连续工艺技术国内外应用现状、研究成果以及发展趋势。     

武山铜矿主井系统延深改造及效果浅析

武山铜矿主井延深时根据新的采、选工艺要求，在前期工程的基础上，对其箕斗提升系统进行改造，增设坑内破碎。针对该矿特粘的矿石性质和前期工程遗留问题，在具体设计和实施过程中采取特别措施保证系统通畅和安全并注意节省投资。同时对尚存在的问题也提出了新的思考。     

Sirius叠前深度偏移在莺歌海盆地“泥拱模糊带”处理中的应用

在对Sirius叠前深度偏移软件应用开发的基础上,分析讨论了Sirius 2D叠前深度偏移速度模型建立、层析成像及演、叠前深度偏移以及深度聚焦等技术环节的基本原理,并以莺歌海盆地某测线的处理为例,具体分析了Sirius 2D叠前深度偏移处理的流程、主要参数及时效.文中还分析讨论了莺歌海盆地中央“泥拱带”叠前深度偏移处理的地质效果.实践表明,莺歌海盆地广泛发育的与“泥拱模糊带”有关的构造各有其特殊性,只有通过3D叠前深度偏移处理才能从根本上解决“泥拱模糊带”的成像问题.     

地下连续墙在太钢老厂改造工程中的应用

结合某深基坑支护施工实例 ,介绍了采用多头潜水钻成槽机进行地下连续墙施工的基本原理、工艺流程及注意事项。指出该方案对于在老厂区改造工程狭窄场地条件下 ,解决深基坑施工保护附近建 (构 )筑物安全具有独特的优势     

时空效应规律在软土深基坑工程中的运用

阐述了时空效应规律在软土深基坑工程中的运用情况，实践证明，运用时空效应规律，能可靠而合理地利用土体自身在基坑开挖过程中控制土体位移的潜力而达到保护环境的目的。