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排序方式: 共有1523条查询结果,搜索用时 31 毫秒
1.
一种新颖的表面等离子谐振效应光波导水质传感技术 总被引:4,自引:0,他引:4
光学表面等离子谐振(SPR)效应是一种很有效的水质检测技术,经过详细的理论推导,同了SPR反射光强的普遍适用公式。在纯水与受污染水两种情况下,根据一些已知参数计算出结果。由计算结果数据一出的曲线比较表明,SPR效应在两种情况下有明显差别,这也正是SPR效应用于水质检测的理论根据。 相似文献
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Many-Body Terms in van der Waals Cohesion Energy of Nanotubes 总被引:2,自引:0,他引:2
We have developed a model for the calculation of van der Waals force for layered systems with axial symmetry. Our result can be applied to compute the cohesion of a carbon nanotube to a substrate, the cohesion between nanotubes, and between shells of multiwall nanotubes. We have obtained unusal power laws for the distance dependence of the many-body van der Waals potential. 相似文献
4.
Flavio S. Damos 《Electrochimica acta》2006,51(7):1304-1312
In the present work an investigation of the effects of the electropolymerization mode on the optical properties associated to the doping/dedoping processes of nanometric films of polypyrrole (PPy) is reported, monitoring in situ and in real time using simultaneously surface plasmon resonance and electrochemical techniques (ESPR). The electropolymerization of pyrrole was performed by potentiostatic, potentiodynamic and galvanostatic methods and the use of the ESPR technique showed that the electropolymerization mode is essential to the stability of polymer and the reversibility of its optical properties during the doping and dedoping processes. Thus, the optical properties of oxidized and reduced film were obtained by nonlinear least square fitting using Fresnel equations for a four-layer system. Then, the values of the real and imaginary parts of the complex dielectric constant for PPy fims were correlated with the polymer doping level. Finally, quartz crystal microbalance measurements were also applied to obtain correlation between doping/dedoping processes and the changes in the real and imaginary parts of the dielectric constant of the polypyrrole film, showing that the doping and dedoping processes in the polypyrrole film can act directly on its optical properties while the ESPR technique can give the same information indirectly. 相似文献
5.
A localized surface plasmon resonance based immunosensor for the detection of casein in milk 总被引:2,自引:0,他引:2
Ha Minh Hiep Kagan Kerman Do-Kyun Kim Yuzuru Takamura 《Science and Technology of Advanced Materials》2007,8(4):331-338
In this research, a localized surface plasmon resonance (LSPR) immunosensor based on gold-capped nanoparticle substrate for detecting casein, one of the most potent allergens in milk, was developed. The fabrication of the gold-capped nanoparticle substrate involved a surface-modified silica nanoparticle layer (core) on the slide glass substrate between bottom and top gold layers (shell). The absorbance peak of the gold-capped nanoparticle substrate was observed at ∼520 nm. In addition, the atomic force microscopy (AFM) images demonstrated that the nanoparticles formed a monolayer on the slide glass. After immobilizing anti-casein antibody on the surface, our device, casein immunosensor, could be applied easily for the detection of casein in the raw milk sample without a difficult pretreatment. Under the optimum conditions, the detection limit of the casein immunosensor was determined as 10 ng/mL. Our device brings several advantages to the existing LSPR-based biosensors with its easy fabrication, simple handling, low-cost, and high sensitivity. 相似文献
6.
A. N. Palagushkin S. A. Prokopenko A. P. Sergeev A. N. Arlamenkov 《Optical Memory & Neural Networks》2007,16(4):288-294
The results of experimental definition of optical parameters of silver nanolayers by the method of surface plasmon resonance
(SPR) are described. The goniometric installation for measurement of angular dependences of reflection of light by layered
nanosructures at the attenuated internal reflection (angular spectrum of reflection) is designed. Calculation of optical parameters
of nanolayers is executed taking into account the form of a curve of tin angular spectrum of reflection.
The text was submitted by the authors in English. 相似文献
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为了找到表面等离子体共振(SPR)检测物体的最佳方法,基于SPR,通过Matlab进行了一系列仿真。对检测物质的可行性进行了讨论,得出SPR能在一定范围内检测物质。对影响SPR现象的因素进行了仿真,得出达到最佳共振效果的参数值。分别对角度调制和波长调制方法进行仿真比较,分析了二者检测不同折射率样品的可行性和特点,选择出了较佳的检测方法。结果得出:达到最佳共振效果的参数值是金膜厚度为45 nm,入射光波长为632.8 nm,棱镜折射率根据实验条件和样品综合选定。角度和波长调制均能较好地检测不同折射率的样品,角度调制检测分辨率低于波长调制。 相似文献
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热处理条件对硅酸盐玻璃中原位形成银纳米颗粒的影响 总被引:3,自引:2,他引:3
用离子交换结合热处理法制备银(Ag)纳米颗粒-玻璃复合材料.用透射电镜、高分辨透射电子显微镜、Ruthefford背散射谱和紫外-可见光吸收光谱研究了热处理条件对玻璃中原位形成Ag纳米颗粒的影响.结果显示:随着热处理温度升高,玻璃表面的Ag原子逐渐向玻璃内部扩散,其表面摩尔浓度逐渐降低.提高热处理温度和延长热处理时间都有利于提高玻璃中Ag纳米颗粒的体积分数.空气中,高温热处理高掺Ag量的白玻璃样品时发生二次成核,因此,Ag纳米颗粒尺寸呈双峰分布.Ag纳米颗粒尺寸的双峰分布导致其等离子体共振吸收峰出现双峰.在氢气气氛中,在250℃热处理2min,即可在玻璃中形成大量Ag纳米颗粒,颗粒尺寸小于空气中高温热处理样品的尺寸,从而引起表面等离子体共振吸收峰发生蓝移. 相似文献