Molecular structure and granule morphology of native and heat‐moisture‐treated pinhão starch

Pinhão seed is an unconventional source of starch and the pines grow up in native forests of southern Latin America. In this study, pinhão starch was adjusted at 15, 20 and 25% moisture content and heated to 100, 110 and 120 °C for 1 h. A decrease in λ max (starch/iodine complex) was observed as a result of increase in temperature and moisture content of HMT. The ratio of crystalline to amorphous phase in pinhão starch was determined via Fourier transform infra red by taking 1045/1022 band ratio. A decrease in crystallinity occurred as a result of HMT. Polarised light microscopy indicated a loss of birefringence of starch granules under 120 °C at 25% moisture content. Granule size distribution was further confirmed via scanning electron microscopy which showed the HMT effects. These results increased the understanding on molecular and structural properties of HMT pinhão starch and broadened its food and nonfood industrial applications.     

Effect of complexation of oxidised corn starch with mineral elements on physicochemical properties

The objective of this study was to determine the effect of complexation of oxidised starch with mineral elements on its physicochemical properties. Corn starch was oxidised with sodium hypochlorite and, afterwards, modified with ions of potassium, magnesium and iron. Thus, native and modified starches were analysed for: contents of mineral elements, colour parameters (L*a*b*), water binding capacity and solubility in water at temperature of 60 and 80 °C. Thermodynamic characteristics of gelatinisation by DSC, molecular weight distribution by GPC, intrinsic viscosity and pasting properties by RVA were studied. The efficiency of incorporation of metal ions into oxidised corn starch was about 30%, 20% and 20% for potassium, magnesium and iron ions, respectively. The complexation with potassium ions caused the greatest changes in the molecular weight distribution and the intrinsic viscosity of starches and viscosity of starch pastes. Only modification of starch with iron ions affected the colour parameters of the starch. Incorporation of metal ions into starch resulted also in changes in its water binding capacity and solubility in water.     

Physical Stability of Octenyl Succinate–Modified Polysaccharides and Whey Proteins for Potential Use as Bioactive Carriers in Food Systems

The high cost and potential toxicity of biodegradable polymers like poly(lactic‐co‐glycolic)acid (PLGA) has increased the interest in natural and modified biopolymers as bioactive carriers. This study characterized the physical stability (water sorption and state transition behavior) of selected starch and proteins: octenyl succinate–modified depolymerized waxy corn starch (DWxCn), waxy rice starch (DWxRc), phytoglycogen, whey protein concentrate (80%, WPC), whey protein isolate (WPI), and α‐lactalbumin (α‐L) to determine their potential as carriers of bioactive compounds under different environmental conditions. After enzyme modification and particle size characterization, glass transition temperature and moisture isotherms were used to characterize the systems. DWxCn and DWxRc had increased water sorption compared to native starch. The level of octenyl succinate anhydrate (OSA) modification (3% and 7%) did not reduce the water sorption of the DWxCn and phytoglycogen samples. The Guggenheim–Andersen–de Boer model indicated that native waxy corn had significantly (P < 0.05) higher water monolayer capacity followed by 3%‐OSA‐modified DWxCn, WPI, 3%‐OSA‐modified DWxRc, α‐L, and native phytoglycogen. WPC had significantly lower water monolayer capacity. All Tg values matched with the solid‐like appearance of the biopolymers. Native polysaccharides and whey proteins had higher glass transition temperature (Tg) values. On the other hand, depolymerized waxy starches at 7%‐OSA modification had a “melted” appearance when exposed to environments with high relative humidity (above 70%) after 10 days at 23 °C. The use of depolymerized and OSA‐modified polysaccharides blended with proteins created more stable blends of biopolymers. Hence, this biopolymer would be suitable for materials exposed to high humidity environments in food applications.     

Starch: a potential substrate for biohydrogen production

Hydrogen is a clean energy carrier with great potential to be an alternative fuel. Anaerobic hydrogen fermentation seems to be more favorable, since hydrogen is yielded at high rates and various organic waste and wastewater enriched with carbohydrates as substrate result in low cost for hydrogen production. Abundant biomass from various industries could be a source for biohydrogen production where combination of waste treatment and energy production would be an advantage. Carbohydrate‐rich nitrogen‐deficient solid wastes such as starch residues can be used for hydrogen production by using suitable bioprocess technologies. Alternatively, converting biomass into gaseous fuels, such as biohydrogen, is possibly the most efficient way to use these agroindustrial residues. This review summarizes the potential of starch agroindustrial residues as a substrate for biohydrogen production. Types of potential starch agroindustrial residues, recent developments and bio‐processing conditions for biohydrogen production will be discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

浅谈门式刚架轻型钢结构厂房中抗风柱的设置

通过对抗风柱上下端的节点几种形式进行分析比较,提出建议性的节点连续方式。     

籼米淀粉超微粉体的制备及其性质

研究了籼米淀粉超微粉体的一种新的制备方法 ,通过正交实验确定了酶处理淀粉的最佳条件 ,考察了淀粉的溶解度和膨润力。结果表明 ,酶处理淀粉的最佳工艺参数为 :水解温度４５℃ ,时间为２５ｈ ,酶用量为水解淀粉的４５%。随着粒径的减小 ,淀粉的溶解度增大 ,膨润力下降。     

Mixed anaclitic-introjective psychopathology in treatment-resistant inpatients undergoing psychoanalytic psychotherapy.

Utilizing data from the Riggs-Yale Project, 45 male and 45 female 18-29-year-old treatment-resistant inpatients undergoing intensive psychoanalytically oriented treatment were studied. Twenty-seven mixed-type anaclitic-introjective inpatients were compared with 29 "pure" anaclitic and 34 "pure" introjective inpatients. At intake, mixed-type inpatients were more clinically impaired (i.e., were more symptomatic, cognitively impaired, and thought disordered) and more vulnerable (i.e., less accurate object representations and more frequently used maladaptive defense mechanisms) in comparison with clearly defined anaclitic and introjective patients. Mixed-type patients, however, improved significantly more in the course of psychoanalytically oriented treatment, in terms of clinical functioning (i.e., symptoms, cognitive functioning) and psychological vulnerability (i.e., utilization of more adaptive defense mechanisms). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Dynamics of Solidification in 2% Corn Starch-Water Mixtures: Effect of Variations in Freezing Rate on Product Homogeneity

Directional solidification studies of gelatinized corn starch-water mixtures were undertaken in order to examine, in situ, the freezing behavior of this food model. The solidification rate was controlled by varying sample cell velocity as it moved from a 25°C hot stage to a -25°C cold stage. While freezing at cell velocities ≤7.5 μm/sec, starch granules were alternately pushed or entrapped by the advancing solid-liquid interface producing a segregated structure consisting of alternating high-starch and low-starch bands. At a cell velocity of 10 μm/sec, the frozen product was homogeneous. The relationship between the solid-liquid interface velocity and segregation behavior was quantified and compared to an existing model of particle-interface interactions.     

磷酸酯淀粉在纯棉细特高密织物浆纱中的应用

就磷酸酯淀粉在纯棉细号高密织物中的上浆情况进行了试验，提出了具体浆纱工艺和减少织造断头率，提高织物效率及布面质量对策，实验表明，磷酸酯淀粉完全适应于纯绵细特高密织物的上浆要求。     

Effect of structural period and ground motion parameters on the earthquake response of asymmetric buildings

The results of a parametric study of torsional coupling effects in the response of asymmetric buildings to a grouped selection of 45 strong motion earthquakes from Europe, North America, the Middle East and Southern Pacific are presented. The period dependency of the key response parameters is studied in relation to the site dependent criteria employed by certain earthquake-resistant design codes for specifying the lateral shear forces to be resisted by the structural frames and/or walls. Unlike lateral forces, the torsional response is relatively insensitive to the ration of peak ground accelaration to velocity, which has been used in previous studies as a measure of the effect on earthquake ground motions of site soil conditions and epicentral distance. The results show that the effect of torsional coupling on edge displacement response is more pronounced in stiff, short period structures. However, the dynamic shear and torque responses are relatively insensitive to variations in structural period. Codified design provisions for torsional effects specified in the United States, Canadian and European seismic building regulations are assessed, along with alternative proposals, in relation to the analytical results. It is concluded that in some cases special provisions are needed for short period asymmetric systems, a feature which has been neglected by the codes and inadequately accounted for in previous proposals.