渤海SZ36-1油田注聚井堵塞原因分析

聚合物驱已成为渤海SZ36-1油田高效开采主要的稳产、增产技术。在聚合物驱开发过程中,随着聚合物累计注入量的增加,总体注入状况变差,有相当一部分井的注入压力已经接近或达到油层的破裂压力,达不到配注、间歇注入等,严重影响聚驱效果。从地质、聚合物吸附滞留、垢样分析和高价离子配伍性等方面探讨分析了聚合物驱时注聚井堵塞的原因,提出了相应的治理建议,对今后注入困难井措施改造有指导意义。     

High-performance hierarchical homologous scale-like CuCl/Cu foam anode for lithium ion battery

In situ growth of hierarchical scale-like CuCl on homologous Cu foam substrate for lithium ion battery (LIB) was achieved via facile anodization of Cu and the following rapid deposition of insoluble CuCl. The obtained hierarchical scale-like CuCl/Cu foam electrode were investigated in terms of scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), galvanostatic charge/discharge, rate performance, cycle stability and AC impedance. When used as the anode in LIB, the as-synthesized electrode with multi-scaled pores delivered satisfactory electrochemical performances. Particularly, the reversible discharge capacity was still maintained at about 197.2 mA h/g even after 1000 cycles at high rate of 10 C, indicating excellent endurance and structural stability during the fast cyclic charge/discharge. It can be concluded that the developed hierarchical scale-like CuCl/Cu foam electrode can not only improve the electronic conductivity, but also buffer the structure strain during long term cyclic lithiation/delithiation and maintain the structural stability. Seemingly, hierarchical CuCl with high Li-storage activity and highly conductive three dimensional (3D) porous homologous Cu foam substrate jointly contributed to high electrochemical performances.     

鳞片状硫化锡合成机理及生产工艺研究

金粉漆存在易氧化,耐候性、耐酸碱性和耐热性差的缺点,采用鳞片状硫化锡为原料可克服上述缺点。对鳞片状硫化锡的合成及机理进行了研究,得出其适宜的生产条件,并对产品进行了物性表征