硫化钠在黑白钨加温精选中的应用研究

介绍了柿竹园黑白钨混合粗精矿加温精选中 ,添加硫化钠与水玻璃混合剂比单一添加水玻璃能更有效地使白钨矿与萤石等含钙矿物及脉石矿物分离。论述了硫化钠在加温精选中的作用效果并探讨了其作用机理     

细磨活化对白钨矿浸取行为的影响SCIEI

本文研究了细磨活化对白钨矿浸取行为的影响.实验结果表明,细磨活化后白钨矿在HCl-Na_3PO_4介质中的浸出速率显著加快,钨的浸出率由原来的约8％提高到99％以上.红外光谱和X射线分析结果表明,细磨除了使白钨矿比表面积显著增大外,还在固体的表面和内部产生缺陷结构,增加了矿物表面的反应活性,改善了白钨矿的分解,使得白钨矿的浸出能在较低的温度顺利进行。     

EFFECT OF FINE GRINDING ACTIVATION ON LEACHING BEHAVIOUR OF SCHEELITE CONCENTRATE

The influence of mechanical activation on the leaching behaviour of scheelite was studied bymeans of fine grinding in an attritor and subsequently HCl leaching in presence of PO_4~(3-).Results showed that after fine grinding in the attritor,the reaction rate of scheelitewith HCl-Na_3PO_4 solution was remarkably increased,the extraction of W increased fromabout 8 to 99%.The IR spectra and X-ray diffraction analysis indicated that in addition toan enlargement of surface area the fine grinding action had made also changes of fine struc-ture and reactivity of solid surface,hence the leaching process of scheelite can be carried outunder mild leaching conditions.     

A decomposing technique for scheelite concentrate and low-grade scheelite concentrate

The effect of different decomposition conditions on tungsten recovery for scheelite concentrate has been examined. The results show that tungsten recovery can be more than 98% under decomposing conditions as follows: the amount of caustic soda is 2.2 and 3.2 times of theoretical respectively, ratio of water and ore is 0.7-0.8, temperature is 160℃, and preservation time is 2.0 h for scheelite concentrate (63.21% WO3) and low grade scheelite concentrate (55.17% WO3).     

Production of high purity APT from scheelite and complex tungsten raw material with high Mo content

More than 73% of the tungsten resources in China are scheelite and 41% are high molybdenum content ores, and their dressing becomes increasingly difficult. Such situation calls for new and advanced processes that can treat complex ores and still attain high overall recovery of tungsten. The novel NaOH digestion process and selective precipitation process was developed. The former is universal for leaching tungsten from various tungsten materials,including scheelite concentrate and keeps most of the impurity elements P, As and Si in residue; while the latter is effective for removing impurities such as Mo and Sn. Combined with the traditional ion exchange process, the new process can be used to produce APT that confirms with the Chinese National Standard GB10116-88APT-0 with crystallization ratio of 95%. When treating high molybdenum scheelite concentrate from Shizhuyuan Deposit with WO3 content of 50%-55%, recovery of the new process may reach up to about 95% which is grossly the same as that from the traditional way for treating standard wolframite concentrates.     

ROOM TEMPERATURE CLEANER FLOTATION TECHNIQUE FOR SCHEELITE ROUGH CONCENTRATE

ＲＯＯＭＴＥＭＰＥＲＡＴＵＲＥＣＬＥＡＮＥＲＦＬＯＴＡＴＩＯＮＴＥＣＨＮＩＱＵＥＦＯＲＳＣＨＥＥＬＩＴＥＲＯＵＧＨＣＯＮＣＥＮＴＲＡＴＥ①ＴｉａｎＸｕｅｄａＣｈｅｍｉｓｔｒｙ＆ＣｈｅｍｉｃａｌＥｎｇｉｎｅｒｉｎｇＣｏｌｅｇｅ，ＸｉａｎｇｔａｎＵｎｉｖ...     

工艺参数对白钨矿直接炼钢的影响

通过实验研究了工艺参数对白钨矿收得率的影响规律。完全用白钨矿冶炼含钨高的合金钢(9%W)是可行的。硅铁还原白钨矿时,炉渣碱度应控制在1.5以下。碳粉还原白钨矿时,渣中最好不要添加CaF2。硅铁和碳混合还原剂还原白钨矿时,碳还原白钨矿比例控制在30%以下能取得较好的还原效果。     

从浮选尾矿中回收白钨矿试验研究

为充分利用矿产资源,提高企业效益,经过近2年的技术攻关,直接从硫化矿浮选尾矿中浮选回收白钨矿试验获得成功。通过粗选工业试验和粗精矿加温小型试验,在白钨入选品位0.25%的条件下,取得了白钨精矿65.046%、回收率50.47%的较好指标。对项目进行可行性研究论证,预计投产后能大幅提高企业效益。     

青海察汗森地区白钨矿成矿特征及找矿潜力

察汗森矿区位于青海省欧龙布鲁克陆块边缘,出露地层为古元古界达肯大板岩群地层,成矿地质构造条件优越。通过对该地区成矿地质特征、成矿构造环境、地球化学特征、矿石特征及矿化分布规律进行研究与分析,认为混合岩化热液与碳酸岩接触交代是成矿的主要原因,矿化与矽卡岩化关系密切。初步总结了该区成矿模式,认为该区具有形成与混合岩化有关的矽卡岩型白钨矿的有利条件,为该区下一步矿产勘查工作指明了方向。     

湖南瑶岗仙两类钨矿成矿流体对比研究

湖南瑶岗仙钨矿田由夕卡岩型白钨矿矿床和石英脉型黑钨矿矿床组成,分别位于瑶岗仙花岗岩体的东南侧和北西侧。文章从成矿流体的演化特点、流体成分以及流体来源方面,探讨了两类钨矿化的区别,并讨论成矿地质条件及流体成分对矿化的控制。研究认为,脉型黑钨矿形成于封闭系统,成矿流体呈临界状态,为一种介于岩浆与热液之间的过渡性流体,该流体的形成与岩浆的熔离及分异作用有关,成矿流体主要为来自岩浆的中高温、中低盐度,富含CO₂、CH₄以及H₂S的卤水。而白钨矿化形成于开放环境,流体演化过程中混合作用明显,其来源早期以岩浆水为主,后期有大量天水的加入。除了围岩性质不同,两类钨矿化对应的流体性质也是形成不同类型钨矿化的另一重要因素。