肥料防结块缓释概况及性能快速表征方法探讨

介绍了颗粒肥料结块的原因机理、影响因素和传统的处理方法。简述了缓释肥料的特点、类型、加工方法以及国内外的研究发展状况。模拟肥料贮存、运输和施用环境以及设计装置，对颗粒肥料防结块、缓释性能快速表征方法进行了有益的探讨。对不同包膜尿素的测试结果表明，所设计的肥料养分释放模拟装置具有较好的应用前景。     

Anionic Clays as Potential Slow-Release Fertilizers: Nitrate Ion Exchange

Several nitrate containing anionic clays were synthesized at different temperatures and the kinetics of NO₃ ^– release were determined to test their suitability as slow-release N fertilizers. A sample (Mg:Al = 2:1) synthesized at 60°C with smaller particle size released 75, 86 and 100% of its NO₃ ^– in 1, 3 and 7 days, respectively when equilibrated with a simulated soil solution. On the other hand, the 175°C/2 hrs sample with larger particle size released 65, 77 and 84% of its nitrate in 1, 3 and 7 days, respectively. Another anionic clay (synthesized at 175°C/24 hrs) of higher charge density (Mg:Al = 2:1) containing NO₃ ^– was equilibrated with a 0.012 N NaCl or Na₂CO₃ to test the role of different anions in releasing the NO₃ ^– anion from the interlayers. The results showed that Cl^– released more NO₃ ^– than did CO₃ ^2– from this anionic clay after all the treatment times probably as a result of the CO₃ ^2– anion blocking the release of NO₃ ^– from the interior of the crystals. When a lower charge density (Mg:Al = 3:1) sample (synthesized at 175°C/48 hrs) was equilibrated with 0.02N solution of anions the release of nitrate was as follows: Cl^– < F^– < SO₄ ⁼ CO₃ ^2–. These results suggest that the divalent SO₄ ⁼ and CO₃ ^2– anions are more effective in the release of NO₃ ^– from this lower charge density anionic clay. Time-resolved structural analysis of NO₃ ^– exchange with CO₃ ^2– in the above anionic clay using synchrotron x-ray diffraction showed that ion exchange is rapid because of small crystal size and lower charge density. Thus the release of NO₃ ^– from anionic clays is an interplay among the type of anions present in soil solution, their concentration, pH of soil solution, the charge density and crystal size of anionic clay etc.     

缓释玻璃肥料的应用进展

玻璃肥料是一种缓释长效肥料，也是一种含微量元素的复合肥料。作者概述了缓释玻璃肥料的特点与应用，介绍了缓释磷酸盐玻璃的结构特点，并对缓释玻璃肥料的发展前景进行了探讨。     

复合缓释药物肥料研制和生产

介绍了复合缓释药物肥料的研发思路、原料、生产工艺、技术创新。该肥料集有机养分、无机养分,以及杀虫、杀螨、杀菌、缓释功能于一体,并可活化土壤,提高作物产量7.5%以上,具有较好的市场前景。     

不同因素对HAP-尿素缓释肥中养分释放性能的影响

以羟基磷灰石(HAP)作为载体材料制备羟基磷灰石-尿素缓释复合肥,利用DMAB显色法检测尿素的含量,考察温度、肥水比、pH值对HAP-尿素复合物养分在水中释放率的影响,复合物在水中溶出养分释放率最佳条件是:肥水比为1∶20,温度为30℃,pH值为7。     

缓释尿素中尿素含量的测定

介绍用对二甲氨基苯甲醛分光光度法测定缓释尿素中尿素含量的分析方法。该法具有操作简便、省时、准确度高、精密度好等优点,适合于测定缓释尿素中的尿素含量。     

木质素季铵盐-海藻酸钠聚合物负载阿维菌素粉体的制备及抗紫外光性能分析

以三甲基木质素季铵盐-海藻酸钠(QL-SA)为载体,用物理混合法制备了阿维菌素缓释聚合物(AVM-QL-SA),利用FT-IR对其结构进行了表征,探讨了交联剂用量、药物加入量、体系pH值等因素对载药量和包封率的影响,并对其缓释性能和抗紫外光降解进行了研究。结果表明:阿维菌素(AVM)均匀的混合在QL-SA载体中,主要以物理混合为主;最佳制备条件为:戊二醛为5%(以单体质量分数计)、药物加入量为1%(以单体质量分数计)、体系pH值为8.5,载药量和包封率分别达到1.36%和73.36%;阿维菌素缓释聚合物粒径符合正态分布,平均粒径为83.90 μm;阿维菌素缓释聚合物具有很好的缓释性能,在乙醇/水(体积比1:1)中释放30 h,累计释放率为88.97%;经8 h紫外光照射,阿维菌素原药中AVM残留量为6.24%,阿维菌素缓释聚合物中AVM残留量为37.75%,具有良好的抗紫外分解性能。     

Evaluation of two unusual high analysis compounds as fertilizers,including possible slow release features

The fertilizer potential of two unusual N-P compounds with cage structures was evaluated in pot experiments where plants were repetitively cut over 400 days. One of the compounds, hexamethyl-hexaaza-tetraphosphaadamantane (APA), having 41.6% P and 28.2% N, showed high fertilizer capability. After more than 400 days, dry matter yield of Rhodes grass given APA was 83–102% of that given conventional N-P sources, and yield of Townsville stylo 60–70%. Curves for N and P uptakes over time were of sigmoidal form, with the steepest parts between days 40 and 120, suggesting a slow-release feature. However growth was depressed up to day 40, presumably by some toxic factor associated with the decomposition of the APA. This toxicity was avoided if some conventional fertilizer was applied with the APA.The other compound, the tetrasulphide of APA (APAS) had only limited fertilizer potential. Plants did absorb P and S at least from this compound, but Townsville stylo yield was only 32–38% of that with conventional fertilizers, and Rhodes grass yield not much greater than from control pots. The possible slow-release feature, and the toxic effect, did not occur with APAS.     

熔体造粒腐植酸功能性专用肥的工艺开发与农业应用试验

熔体造粒腐植酸功能性专用肥是采用预处理过的风化煤和普通无机复合肥为生产原料,经高温熔融、特制喷头造粒、筛分、计量、包装制成。在大田条件下,研究了熔体造粒腐植酸功能性专用肥对玉米产量及氮肥利用率的影响,试验结果表明,熔体造粒腐植酸功能性专用肥能显著提高玉米产量,在相同施肥量(N、P、K相同)的情况下,与普通肥处理相比,熔体造粒腐植酸功能性专用肥处理增产11.74%,其氮肥利用率显著高于普通肥处理。     

用缓释指数评价化学缓释肥的缓释特性及其生物效应

在实验室条件下,采用简化的工艺制备了对氮、磷、钾三元素均有部分缓释作用的复混肥(化学缓释肥),用特定淋洗装置测定肥料各养分随时间的溶出率,通过双曲线方程Xt=b-a/t对其养分累计溶出率与时间的关系进行拟合,以方程常数b和a计算出的缓释指数(SR I)来定量评价肥料缓释特性,同时进行盆栽试验,探讨了缓释指数与复混肥中相应缓释添加剂百分含量(X)之间、各复混肥处理的油菜产量与复混肥中缓释添加剂总含量(X'')之间的关系。结果表明:各养分的缓释指数(SR I)与相应缓释添加剂含量(X)均有很好的线性正相关;各化学缓释肥处理的油菜产量随缓释添加剂总含量(X'')增加而增加;化学缓释肥以较少的荚数获得更高的产量。这预示着通过肥料的室内淋洗试验得到的缓释指数SR I不仅可以用来评价肥料的缓释性能,且在一定程度上可预测肥料的增产效应。