Electrochemical synthesis and characterization of chloride doped polyaniline

Chloride doped polyaniline conducting polymer films have been prepared in a protic acid medium (HCl) by potentiodynamic method in an electrochemical cell and studied by cyclic voltammetry and FTIR techniques. The FTIR spectra confirmed Cl^- ion doping in the polymers. The polymerization rate was found to increase with increasing concentration of aniline monomer. But the films obtained at high monomer concentration were rough having a nonuniform flaky polyaniline distribution. Results showed that the polymerization rate did not increase beyond a critical HCl concentration. Cyclic voltammetry suggested that, the oxidation-reduction current increased with an increase in scan rate and that the undoped polyaniline films were not hygroscopic whereas chloride doped polyaniline films were found to be highly hygroscopic.     

LMG200型可调高滚筒式露天采煤机

介绍了可调高滚筒式露天采煤机的结构特点及在露天煤矿应用所产生的效益和其广 阔的发展前景。     

离心萃取装置中硝酸羟胺还原反萃钚的研究

用十六级分离式混合—离心澄清萃取装置,在20-24℃,30-34℃,45-50℃等不同温度下进行了3B槽硝酸羟胺还原反萃钚的实验。结果表明,钚的收率均可达99.9%以上。在20-24℃时,有机相出口级附近几级的钚浓度较高,实验条件一旦波动,有可能造成钚的流失,且钚在萃取设备中有明显的积累。温度升高,14级反萃(停留时间约18min)时,钚的收率基本得到保证。     

Optical switching properties of RCo2-type alloy thin films by electrochemical hydrogenation

The switchable optical properties of Pd-protected RCo₂-type Ho_0.6Mm_0.4Co₂ alloy thin films have been investigated in a KOH electrolyte. The reversible optical switching has been carried out simultaneously by measuring transmitted light through the thin film during electrochemical charging–discharging of hydrogen. The dependence of switching speed and cyclic durability of the film on the charging and discharging current density as well as concentration of KOH electrolyte has been studied. In addition, cyclic voltammetric measurements have been performed to examine the hydride formation and decomposition reactions.     

井巷掘进控制斜形炮孔钻孔精度的试验研究

井巷掘进爆破工程中，工作面按设计要求，布置各种斜形炮孔，利用量角器和垂直尺控制钎杆与工作面夹角，使炮孔钻孔精度与设计炮孔角度基本上符合，在生产中取得了良好的爆破效果．     

A comparison of backpropagation and general regression neural networks in quantative trace metal analysis using anodic stripping voltammetry and cybernetic instrumentation

A comparison is made between backpropagation and general regression neural networks for the prediction of parts per billion lead concentration when used to process data obtained from digested curry powder by the electrochemical analysis method of differential pulse, anodic stripping at a thin film mercury electrode (TFME). Two data sets are used, one requiring the net to classify an unknown analytical data vector into one of a number of previously learnt concentrations, and one requiring the net to predict the probable concentration of an unknown sample by interpolation of the already learnt concentrations. For both of these data sets the general regression neural network is shown to train faster and to provide results superior to those obtained by backpropagation.     

用发展的Sachs法研究模拟轧辊中的残余应力

对不同辊型，尺寸，材料与加工处理方法的模拟冷轧辊进行了内剥层试验研究，求出了原辊和打中心孔或扩孔后辊内残余应力分布曲线，提出了虚拟打孔法和虚拟剥层法，解决了实心辊中心和空心辊内表层的残余应力的精确测量问题，丰富了Ｓａｃｈｓ内剥层法的内容，机械法打中心孔，热处理前打中心孔，空心辊表淬前改变温度场的方法可降低残余应力值，后者降低残余应力的效果尤为显著。     

含氨废水处理方法的探讨

对催化剂厂含氨废水的处理，提出了多种方法，着重分析了A/O生物法、膜分离法和汽提法，比较后确定采用汽提法处理该废水，建成投产达到预期效果。     

Electrochemistry of polyaniline: Study of the pH effect and electrochromism

Polyaniline was electrochemically synthesized from an aqueous medium with various acid electrolytes via potentiodynamic and potentiostatic techniques. The electrochemical synthesis of polyaniline was studied over various substrates, including Pt, Ti, Ni, and SnO₂ coated glass, and in various acid electrolytes. Cyclic voltammograms of electrochemically synthesized polyaniline were studied in HCl in a pH range of 1–4. Probable electrochemistry and chemical changes were deduced that occurred when polyaniline film was electrochemically oxidized and reduced between ?0.2 and 1.0 V versus a Ag/AgCl reference electrode in an acidic electrolyte at pH 1, and three corresponding oxidation and reduction peaks were described instead of two redox peaks (as observed by W. S. Huang, B. D. Humphrey, and A. G. MacDiarmid, J Chem Soc Faraday Trans 1 1986, 82, 2385). The electrochromic property was studied with changes in the chemical states of polyaniline during electrochemical oxidation and reduction. A new viscous electrolyte, aqueous AlCl₃ (pH 2), saturated with AgCl was used for the construction of an electrochromic display device. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 378–385, 2002