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1.
The study presents the preparation of the new magnetic nanocomposite based on PLGA and magnetite. The PLGA used to obtain the magnetic nanocomposites was synthesized by the copolymerization of lactic acid with glycolic acid, in the presence of tin octanoate [Sn(Oct)2] as catalyst, by polycondensation procedure. Magnetite was obtained by co-precipitation from aqueous salt solutions FeCl2/FeCl3. The particles size of magnetite was 420 nm, and the saturation magnetization 62.78 emu/g, while the PLGA/magnetite nanocomposite size was 864 nm and the saturation magnetization 39.44 emu/g. The magnetic nanocomposites were characterized by FT-IR, DLS technique, SEM, VSM and simultaneous thermal analyses (TG–FTIR–MS). The polymer matrix PLGA acts as a shell and carrier for the active component, while magnetite is the component which makes targeting possible by external magnetic field manipulation. Based on the gases resulted by thermal degradation of PLGA copolymer, using the simultaneous analysis TG–FTIR–MS, a possible degradation mechanism was proposed. 相似文献
2.
Tatsuya Hanaoka Hisashi Ishitani Ryuji Matsuhashi Yoshikuni Yoshida 《Applied Energy》2002,72(3-4):705-721
The objective of this study is to evaluate the potential for recovering fluorocarbons as measures for the abatement of global warming. In this study, we focused on the three different kinds of fluorocarbons: CFCs, HCFCs and HFCs, and targeted refrigerant use because of the availability of relevant data. We first estimated future fluorocarbon emissions from the targeted appliances; we next compared those emissions in the units of CO2 equivalent to the level of CO2 emissions in 1990 from a quantitative point of view. As the result of this study, it was found that fluorocarbon emissions in 1999 and 2010 would be equal to approximately 7 and 3% of the level of CO2 emissions in 1990 respectively. Moreover, if we implement a 100% recovery rate in every recovery route, we can reduce a large amount of emissions which correspond to approximately 2–5% of the level of CO2 emissions in 1990, even if we take into account the energy-related CO2 emissions by the transportation and decomposition of fluorocarbons. 相似文献
3.
介绍了我国车用汽油的发展轨迹 ,通过与国外先进标准的对比分析了我国车用汽油存在的不足 .指出我国在加入WTO后 ,更应不断升级车用汽油质量标准 ,需要从标准制定、炼油技术等多方面追赶世界先进水平 ,积极研制生产清洁型无污染汽油 ,从根本上消除汽车尾气对环境的污染 . 相似文献
4.
The behavior of an ultrasonic shot peening process is observed and analyzed by using a model of inelastic hard spheres in a gravitational field that are fluidized by a vibrating bottom wall (sonotrode) in a cylindrical chamber. A marked heterogeneous distribution of impacts appears when the collision between the shot and the side wall becomes inelastic with constant dissipation. This effect is one order of magnitude larger than the simple heterogeneity arising from boundary collision on the cylinder. Variable restitution coefficients bring the simulation closer to the general observation and allow the investigation of peening regimes with changing shot density. We compute within this model other physical quantities (impact velocities, impact angle, temperature and density profile) that are influenced by the number N of spheres. 相似文献
5.
本文综述我们对电脑气体选择性激发产生变色发光的理论研究和实验研究,并探讨这种类型变色发光的实际应用。 相似文献
6.
本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。 相似文献
7.
The results of the measurements of the concentrations of freons (F-11 and F-113), chloroform (CHCl3), trichloroethane (CH3CCl3) and carbon tetrachloride (CCl4) in air are presented. The data concern concentration measurements that have been conducted in Krakow since half way through 1997 to the end of 1999. The mean monthly values of these concentrations have been compared with the data from Mace Head, the station situated at a similar longitude as Krakow. It has been concluded that, in the observed period of time, the concentrations of the pollutants in Krakow are higher than in Mace Head. The mean monthly concentrations of F-11 and CCl4 decrease in Krakow faster than in Mace Head (2.5 and 3.3 times, respectively). The concentrations of CHCl3 and CH3CCl3 decrease at both locations, but the change is greater in Krakow. In Krakow, the observed increase of F-113 is 0.13 ppt/month and has an opposite trend than in the same period at Mace Head. 相似文献
8.
Modeling mercury speciation is an important requirement for estimating harmful emissions from coal-fired power plants and developing strategies to reduce them. First-principle models based on chemical, kinetic, and thermodynamic aspects exist, but these are complex and difficult to develop. The use of modern data-based machine learning techniques has been recently introduced, including neural networks. Here we propose an alternative approach using abductive networks based on the group method of data handling (GMDH) algorithm, with the advantages of simplified and more automated model synthesis, automatic selection of significant inputs, and more transparent input–output model relationships. Models were developed for predicting three types of mercury speciation (elemental, oxidized, and particulate) using a small dataset containing six inputs parameters on the composition of the coal used and boiler operating conditions. Prediction performance compares favourably with neural network models developed using the same dataset, with correlation coefficients as high as 0.97 for training data. Network committees (ensembles) are proposed as a means of improving prediction accuracy, and suggestions are made for future work to further improve performance. 相似文献
9.
利用自生气的油气田开发开采工艺技术概况 总被引:1,自引:0,他引:1
油气田开发工艺技术中使用的自生气有N2、O2、CO2、ClO2和混合气五大类型,来源于化学反应和微生物的代谢产物。自生N2主要来自亚硝酸盐和铵盐的氧化还原反应。自生O2则来自过硫酸盐和过氧化物的高温分解。白生CO2来自碳酸盐与酸的反应及含氮类有机物的高温分解。自生混合气包括高能气体和生物气,高能气体是火药或炸药爆燃产生的混合气,生物气是微生物代谢产生的混合气。自生气工作液在油气田现场已应用于固井、射孔、解堵、压裂、调剖和三次采油等广阔的领域。本文概述油气田开发开采中利用五大类自生气的19项工艺技术。参43. 相似文献
10.
Mikhail Yu. Sinev Yurii P. Tulenin Olga V. Kalashnikova Viktor Yu. Bychkov Vladimir N. Korchak 《Catalysis Today》1996,32(1-4):157-162
The analysis of methane oxidation in a wide range of pressures (0.05–10 atm) demonstrates that the efficiency of CH3 radicals recombination is of great importance for high selectivity of C2 hydrocarbons formation. The relative efficiency of different “colliders” assisting the stabilization of exited C2H*6 molecules increases in the series: solid surface> Ar> He. The increase of the overall reaction rate upon increasing pressure of the inert gases in the case of catalysts having a higher surface area and more developed pore structure is likely due to the contribution of the surface-induced chain reaction in the volume of pores. 相似文献