表面控制助剂在水性聚氨酯涂料中的应用

客户在现场喷涂水性涂料时经常会遇到一些涂膜外观不良的问题,其中很多问题是由于底材润湿不佳造成的流平不良所致。为了减少乃至消除这些问题,需要在配方设计时选择适合该体系的水性表面控制助剂。从表面控制助剂的消泡和抑泡性、扩散性,以及流平润湿性方面入手,筛选适合水性配方的最优助剂组合。     

聚氨酯分散剂在液体靛蓝制备中的应用

采用异佛尔酮二异氰酸酯(IPDI)、聚乙二醇200、400、600、800(PEG200、PEG400、PEG600、PEG800)、2,2-二羟甲基丙酸(DMPA)、1-苯基-1,2-乙二醇、中和剂三乙胺(TEA)、甲乙酮肟等为原料,制备了一种阴离子聚氨酯分散剂.通过FTIR、GPC、TG表征了分散剂的结构与性能.利用自制的分散剂采用研磨法制备了液体靛蓝分散液,以液体靛蓝分散液粒径、离心稳定性、储存稳定性为指标,探讨了分散剂链长、用量对分散液性能的影响.结果表明,研磨1 h后,以PEG400为软段合成的聚氨酯分散剂用量为染料质量的60％时制备的液体靛蓝粒径为277.1 nm,1000 r/min离心稳定性达到93.98％,3000 r/min离心稳定性为51.13％,常温放置7 d后粒径变化在20 nm以内,染色后织物的颜色深度(K/S)为10左右,约是粉状靛蓝染色K/S的2倍,染色织物的颜色性能并未改变,SEM显示分散体颗粒大小分布均匀,与分散剂甲基萘磺酸钠的甲醛缩合物(MF)和木质素85A相比,其分散体系稳定性差别不大.     

渣油催化临氢热转化钼铁双金属催化剂的研究

Replacement of precious single metal catalysts with cost-effective, highly-dispersed composite catalysts for catalytic hydrothermal conversion of residue holds tremendous promise for the residue upgrading technologies. Organic metals were added to the feed as the oil-soluble precursors, and transformed into the catalytic active phases in this work. Physical properties and structures of the composite catalysts had been investigated by X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscope and transmission electron microscopy. The composite catalysts were found to be highly efficient in the catalytic hydrothermal conversion of both model compound and residue. Increased metal dispersion and synergistic effects of two metals played indispensable roles in such catalytic system. Results showed that under the test conditions in the article, the catalyst had the best catalytic performance when the mass ratio of molybdenum to iron was 1.5.     

新型重油催化装置CO余热锅炉设计

设计某炼油厂重油催化装置新型CO余热锅炉,采用先进的工艺技术,选择合理的设计结构,控制排烟温度,避免露点腐蚀,使余热锅炉的烟气污染物排放量满足国家及地方环保要求。     

探析合成氨催化技术与工艺发展趋势

合成氨作为工业生产重要原料之一,需应用先进技术手段提高其质量,以满足生产加工切实需求,其中催化技术作为常用技术手段之一,亦随着经验积累及创新实践不断优化。本文通过探析合成氨催化技术与工艺发展趋势,以期助推新时代与合成氨有关工业生产活动的良性发展。