丝绸的氧化还原低温染色法

1.引言 丝绸作为纺织纤维具有无可比拟的光泽、手感和悬垂性。但由于它是由氨基酸组成的多肽,就象其它动物性纤维那样,不耐高温,这些性能在染色过程中要被破坏,因此,丝绸的低温染色在染色工业上具有重要的意义,许多染色学家研究了数十年了。 最近,Luo发表了过氧化氢/葡萄糖氧化还原体系存在下酸性染料对丝绸的低温染色法改善竭染率和染色牢度的文章。他认为,氧化还原体系能通过游离基的作用增加染座的数量,通过这些游离基有可能形成染料的游离基,除了普通的离子结合,氢键和范德华力外,在     

我国染料工业发展的新特点和面临的新形势

世界染料工业经过150年的发展正面临着环境制约、生态要求、纺织转移、布局调整、资源配置、技术更新、用途拓宽和营销变化等多种因素的挑战，这使得染料行业组织结构发生了历史上规模最大和最广的一次变革，染料的生产和供应中心也从欧美国家向亚洲转移，其结果是有力地促进了亚洲特别是我国染料工业的发展。     

NPCDP／PET复合仿毛纤维纺丝工艺研究

应用复合纺丝方法并通过加弹、空气变形等措施使ＮＰＣＤＰ／ＰＥＴ异染异收缩纤维获得优良的毛性感。简要介绍了复合纺丝的工艺路线，讨论了纺丝温度、压力、干燥工艺、拉伸条件对可纺性的影响，并明确了变形工艺对复合纤维的影响作用。制得的ＮＰＣＤＰ／ＰＥＴ复合纤维物理力学性能符合后加工要求，织物的缓弹回复角达３０５度。     

取代保险粉的新还原剂

取代保险粉的新还原剂是剥色剂CY-730与催化剂CY-770在溶液中发生化学反应．生成还原能力极强的还原剂，可剥除活性染料、酸性染料、中性染料。文章对剥色剂CY-730的应用条件进行探索。摸索出一整套适宜于各种染料结构的剥色方法及涤纶染色后的还原清洗方法，可以取代保险粉用于剥色、还原清洗，消除了保险粉应用时的所有缺点。     

酸性染料与分散染料同浴浸染单板工艺实践

厚单板染色加工难以获得良好的透染性、均染性和较高的色牢度。采用高温高压工艺和分散性、渗透性较好的染料浸染厚单板，可以获得良好的染色效果。     

十六烷基三甲基季铵阳离子改良二氧化硅对酸性染料的吸着

The sorption behavior of acid dyes onto cetyltrimethylammonium bromide (CTAB)-modified silica as a function of pH in the aqueous medium was studied. Single-and multi-solute sorption equilibria of orange Ⅱ（OR), phenol red (PR) and Eriochrome Black T (EBT) were studied at pH 3, unbuffered water pH and pH 11. Sorption behavior of EBT could not be conducted at pH3 due to its aggregation in acidic medium. All the reaction conditions, experimental protocols and techniques remained the same throughout the sorption process. Sorption isotherms for single-solute system were fitted by the Langmuir model, while Langmuir competitive model (LCM) and the ideal adsorbed solution theory (IAST) coupled with Langmuir model (IAST/Langmuir) were used for the prediction of multisolute competitive sorption. Sorption affinities influenced by the factors like physical interactive forces between the molecules of CTA on silica and sorbate, structural limitations of the dyes based on their geometrical arrangement were investigated. Sorption affinity of OR was found to be higher than that of EBT and PR at all the pH values investigated. Magnitude of the sorption capacities was observed to be higher in acidic medium but lower in alkaline medium. Trends of the sorption affinities in multisolute system were simlar to those in single-solute system but magnitude of the sorption capacities was significantly reduced due to the prevailing competition among the sorbates.