全文获取类型
收费全文 | 2532篇 |
免费 | 192篇 |
国内免费 | 155篇 |
专业分类
电工技术 | 36篇 |
综合类 | 105篇 |
化学工业 | 764篇 |
金属工艺 | 526篇 |
机械仪表 | 101篇 |
建筑科学 | 180篇 |
矿业工程 | 43篇 |
能源动力 | 55篇 |
轻工业 | 193篇 |
水利工程 | 13篇 |
石油天然气 | 170篇 |
武器工业 | 19篇 |
无线电 | 57篇 |
一般工业技术 | 241篇 |
冶金工业 | 196篇 |
原子能技术 | 86篇 |
自动化技术 | 94篇 |
出版年
2024年 | 3篇 |
2023年 | 34篇 |
2022年 | 78篇 |
2021年 | 87篇 |
2020年 | 79篇 |
2019年 | 65篇 |
2018年 | 45篇 |
2017年 | 81篇 |
2016年 | 116篇 |
2015年 | 87篇 |
2014年 | 127篇 |
2013年 | 149篇 |
2012年 | 146篇 |
2011年 | 187篇 |
2010年 | 144篇 |
2009年 | 164篇 |
2008年 | 119篇 |
2007年 | 168篇 |
2006年 | 155篇 |
2005年 | 94篇 |
2004年 | 86篇 |
2003年 | 78篇 |
2002年 | 77篇 |
2001年 | 52篇 |
2000年 | 57篇 |
1999年 | 53篇 |
1998年 | 46篇 |
1997年 | 36篇 |
1996年 | 31篇 |
1995年 | 26篇 |
1994年 | 32篇 |
1993年 | 38篇 |
1992年 | 33篇 |
1991年 | 22篇 |
1990年 | 15篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 8篇 |
1985年 | 13篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1963年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有2879条查询结果,搜索用时 15 毫秒
1.
Prof. Dr. Hans-René Bjørsvik Prof. Dr. Bjørn Tore Gjertsen Dr. Vijayaragavan Elumalai 《ChemMedChem》2020,15(10):862-870
A previously designed and developed 12-step total synthesis that includes [1,1′-biphenyl]-2-amine and carbazole intermediates and that ultimately produces the carbazole alkaloid carbazomycin G was exploited as a screening compound library with the goal of identifying potential lead compound(s) with cytotoxic effect. These compounds were investigated by using in-vitro tests involving the two human cell lines HL-60 and MOLM-13, which both model acute myeloid leukaemia (AML). The in-vitro biological test results were used together with the molecular structures of the various intermediates in a concise SAR analysis. Several of the intermediates revealed cytotoxicity (IC50<10−4 M), although the final natural product carbazomycin G did not reveal cytotoxicity versus the two said human cell lines. 相似文献
2.
许禄 《计算机与应用化学》1994,11(2):107-111
进行碳-13NMR波谱模拟的一种常用方法为线性回归,其数学模型则由已知结构所测得的化学位来建立。显然,每一数学模型仅可用于某种相似的化学环境。因此,为了进行化学环境的分类,本文提出权重层次位图法和分子连接性指数法两种方法以进行一些参数的计算,同时采用多元分析手段,如主成分分析和聚类分析,以进行多维空间数据点的显示,所得结果比较满意,从而可为碳-13波谱模拟中回归方程的选择提供理论依据。 相似文献
3.
风扇磨煤机ZGMn13冲击板的失效分析 总被引:1,自引:1,他引:0
ZGMn13冲击板的失效方式为不同角度的粒子撞击和冲刷,其表面可以分为三个典型的磨损区域:低角度撞击区、高角度撞击区和冲刷区。详细分析了该三个磨损区域的磨损机理。次表面分析的结果表明,在低负度撞击和冲刷条件下,高锰钢未能充分加工硬化,耐磨性提高有限。 相似文献
4.
Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers. 相似文献
5.
Aboubakar Sako Kenneth G. MacLeod Catherine M. O’Reilly 《Journal of Great Lakes research》2007,33(4):806-815
In this study, we measured growth trends in oxygen and carbon isotopic ratios in whole sagittal otoliths from three adult centropomid fish (Lates stappersii) from each of three sub-basins of Lake Tanganyika, East Africa. Sampling density was 20 to 50 samples per otolith. Both δ18O and δ13C values increase with age. The δ18O data suggest that otoliths were precipitated near the expected equilibrium with the ambient environment (ca. +3.5‰) and support a migration pattern from surface waters during larval stages to deeper waters (40 to 80 m) for mature fish. Relatively high δ18O values in the southern sub-basin are consistent with cooler temperatures in the region during seasonal upwelling. The δ13C increase from otolith core to edge is large (up to 4‰) and is interpreted as due to ontogenetic changes in diet and contributions from a decrease in the proportion of respired CO2 incorporated into otolith carbonate as metabolic rates of the fish dropped with maturity. The data seem to successfully reveal life strategy and migration patterns of L. stappersii, document regional differences in lake conditions, and provide a record of temperature within the water column during which the fish lived. Higher resolution studies and analyses of historical samples could be used to constrain modern and past growth patterns, and to reconstruct past temperature gradients and productivity patterns in the lake. 相似文献
6.
采用二甲苯为溶剂,将不同乙烯含量(5% ̄15%质量)的抗冲聚丙烯用特定程序进行分级,将各样品分为室温下可溶于甲苯和不可溶于甲苯的两部分。使用^13C-NMR方法和FT-IR方法对各组分进行表征,明确了乙烯链段在聚丙烯链上的分布,并在此基础上提出了产生这种链结构的聚合工艺的特点。 相似文献
7.
TORGILS FOSSEN ØYVIND M. ANDERSEN DAG OLAV ØVSTEDAL ATLE T. PEDERSEN ÅSE RAKNES 《Journal of food science》1996,61(4):703-706
Three red onion (Allium cepa) cultivars, top onion (A. cepa var. vivi-parum), A. altaicum and chive (A. schoenoprasum) contained several or all of the following anthocyanins: 3-(6′-malonyl-3′-glucosylglucoside), 3-(3′,6′-dimalonylglucoside), 3-(6′-malonylglucoside), 3-(3′-malonyl-glucoside), 3-(3′-glucosylglucoside) and 3-glucoside of cyanidin. Trace amounts of two pelargonidin derivatives and the 3,5-diglucosides of cyanidin and peonidin were for the first time reported in red onion. Carbon NMR data showed that the sugars of the 3-(6′-malonyl-3′-glu-cosylglucoside), 3-(6′-malonylglucoside) and 3-glucoside of cyanidin were pyranoses. Substitution either by sugar or acid in the sugar 3-position of an anthocyanin has never been reported outside the genus Allium. 相似文献
8.
热采水平井整体开发草13块砂砾岩薄层特稠油 总被引:11,自引:5,他引:6
热采水平井技术是科学有效开发稠油油藏的重要手段。以胜利油田草13块为例,系统论述了利用热采水平井整体开发具有边底水的砂砾岩薄层特稠油油藏的开发程序和研究方法。在油蒇精细描述的基础上,通过热采筛选、产能评价、直井和水平井数值模拟、开发方式优化及指标预测等油藏工程研究技术方法,综合论证了利用热采水平井整体开发草13块的必要性和可行性,总结了砂砾岩薄层特稠油油藏水平井油藏工程设计中应遵循的原则,并在生产实践中见到明显效果,为胜利油田其它区块和类似油田的开发提供了借鉴和指导。 相似文献
9.
10.
Coatings derived from organofunctional silanes have been investigated as possible replacements for the chromate-based systems used in the aerospace industry. In this study, organofunctional silanes [bis-(triethoxysilylpropyl)ethane and bis(triethoxysilylpropyl) tetrasulfide] were reacted with commercially available acrylate (ECO-CRYL™ 9790) and epoxy (EPI-REZ™ WD-510) resins, resulting in a one-step, low-VOC, chromate-free primer. Liquid-state 29Si and 13C NMR were used to determine structural characteristics of various optimized formulations. 相似文献