Amtshaftung bei Bauführung im Hochwassergebiet; fehlerhafter Flächenwidmungsplan; Nachforschungspflichten der Gemeinde

Bestehen ausreichende Anhaltspunkte für die Hochwassergef?hrdung, ist die Gemeinde verpflichtet, sich durch Nachforschungen Gewissheit über das Vorliegen oder Nichtvorliegen eines Hochwasserabflussgebietes gem § 38 Abs 3 WRG zu verschaffen. Liegt ein solches vor, hat sie gem § 12 Abs 1 Z 2 krnt GplG dieses im Fl?chenwidmungsplan ersichtlich zu machen. Erteilt die Gemeinde eine Baubewilligung ohne diese von der Erteilung einer wasserrechtlichen Bewilligung abh?ngig zu machen, haftet sie für die Kosten der Bauführung, die bei gesetzes-konformer Vorgangsweise unterlassen worden w?re.     

Photocatalytic degradation of methyl orange using heteropolytungstic acid-encapsulated TiSBA-15

Heteropolyphosphotungstic acid (H₃PW₁₂O₄₀) (HPA)-encapsulated titanium-supported SBA15 nanoporous materials (HPA-TiSBA-15) were synthesized as a new photocatalyst, and they were characterized by FT-IR and ³¹P NMR MAS spectroscopic methods. Their photocatalytic effects on degradation of methyl orange in water were investigated under natural conditions, and it was found that a 4-fold increase in the photodegradation rate is observed in the presence of HPA-TiSBA-15 as compared to the rate observed in the presence of titanium-supported SBA15 nanoporous materials (TiSBA-15) without HPA.     

水浴法加温液氧泵

1　故障现象一次 ,我们用KL -1 5型制氧制氮车开机制氮 ,给一只容积为 40升、最高工作压力为1 4 7MPa的气瓶灌充氮气 ,当气瓶充气压力升高到一定值时不再上升。反复开泵 ,压力基本不变。液氧泵停止时 ,出口压力无明显下降。经分析判断导致气瓶压力升高到一定值时不再上升的原因是由于液氧泵被冻结所致。2　排除方法首先关闭液氧泵。拧开制冷机氢气放气阀 ,使压力下降到 1 0MPa。开大放气阀 ,使二级压力保持在 0 3 5MPa左右。调整正流空气调节阀 ,调节好中部温度。关闭液氮进液氧泵阀和气氮出液氧泵阀。戴棉布手套 ,拆开液氮进口接头、…     

A Hermitian Box-scheme for One-dimensional Elliptic Equations – Application to Problems with High Contrasts in the Ellipticity

We introduce a new box-scheme, called ``hermitian box-scheme' on the model of the one-dimensional Poisson problem. The scheme combines features of the box-scheme of Keller, [20], [13], with the hermitian approximation of the gradient on a compact stencil, which is characteristic of compact schemes, [9], [21]. The resulting scheme is proved to be 4th order accurate for the primitive unknown u and its gradient p. The proved convergence rate is 1.5 for (u,p) in the discrete L ² norm. The connection with a non standard mixed finite element method is given. Finally, numerical results are displayed on pertinent 1-D elliptic problems with high contrasts in the ellipticity, showing in practice convergence rates ranging from 1 to 2.5 in the discrete H ¹ norm. This work has been performed with the support of the GDR MOMAS, (ANDRA, CEA, EDF, BRGM and CNRS): Modélisation pour le stockage des déchets radioactifs. The author thanks especially A. Bourgeat for his encouragements and his interest in this work.     

南钢15CrMoG管坯圆钢中裂纹的成因分析

采用金相分析、力学性能测试、扫描电镜能谱分析等方法，对开裂试样进行分析。结果表明，条状MnS夹杂是导致钢材开裂的根本原因，不合理的轧钢加热制度和冷却速度加快了裂纹的扩展。     

固载于SBA-15分子筛中的同双核金属配合物催化剂

合成了3种同双核金属配合物[M2LCl3]Cl(L代表配体三亚乙基四胺,M代表Co,Cu,Cr),采用微波加热法合成了SBA-15分子筛,采用浸渍法将3种同双核金属配合物分别固载在表面官能化的SBA-15分子筛(SBA-15-NH2分子筛)中制得负载型催化剂。傅里叶变换红外光谱、X射线衍射、紫外可见光谱和热分析表征结果表明,同双核金属配合物被固载后,其结构仍保持完整。以环己烷氧化反应为探针反应,考察了[Co2LCl3]Cl/SBA-15-NH2,[Cu2LCl3]Cl/SBA-15-NH2,[Cr2LCl3]Cl/SBA-15-NH2催化剂的活性,环己烷转化率分别为11.0%,49.5%,57.9%;对于[Cr2LCl3]Cl/SBA-15-NH2催化剂,当分别以乙睛、丙酮和冰醋酸为溶剂时,环己烷转化率分别为57.9%,52.1%,34.2%,3次重复实验的环己烷转化率分别为57.9%,47.8%,46.5%,表明该催化剂具有较好的活性和重复使用性。     

复合射孔枪枪身材料动态本构关系的试验研究

为确定复合射孔枪枪身材料32CrMo4钢在井下高温、高加载率工作环境下的动态性能,利用MTS试验机和分离式Hopkinson冲击压杆装置做了应变率为0.001、1000和3000/s,温度为294、373、473和573K的单轴动态压缩试验,得到32CrMo4钢各组温度及应变率下的流动应力-应变曲线。拟合得到该钢Johnson-Cook本构关系模型所需的5个参数,模型拟合曲线与试验曲线吻合。     

The Berlekamp-Massey Algorithm revisited

We propose a slight modification of the Berlekamp-Massey Algorithm for obtaining the minimal polynomial of a given linearly recurrent sequence. Such a modification enables to explain it in a simpler way and to adapt it to lazy evaluation. partially supported by the Galois Theory and Explicit Methods in Arithmetic Project HPRN-CT-2000-00114 partially supported by the European Union funded project RAAG CT-2001-00271     

Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios

Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, ²⁷Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH₃. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH₃ adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities.