Pb(Zr0.52Ti0.48)O3 nanotubes synthesis and infrared absorption properties

Herein a useful methodology to synthesize the lead zirconate titanate (PZT) nanotubes via a dip-coating deposition process with anodic aluminum oxide (AAO) template is proposed. The nano-porous AAO templates were produced using a controlled two-step electrochemical anodization technique. The PZT/AAO composite was formed using the dip-coating wetting technique. The prepared PZT precursor solution was driven into the nanopore channels of AAO template under the driving force of capillary action, subsequently the sintering process of the as-filled templates was carefully tuned to obtain Pb(Zr_0.52Ti_0.48)O₃ nanotubes of crystalline tetragonal phase with uniform pore size and ordered arrange. Fourier transform infrared spectroscopy (FTIR) results show that in the 1200–1900 cm⁻¹ band, the composite structure of PZT/AAO has obvious absorption peaks at 1471.56 cm⁻¹ and 1556.09 cm⁻¹, the absorption intensity of the composite structure is about six times of pure AAO template. The unusual optical properties found in PZT/AAO composite will stimulate further theoretical and experimental interests in ferroelectric nanostructures.     

Characteristics of ACPDP test panels with aluminum fence electrode formed via anodic bonding with soda‐lime glass

Abstract— In an attempt to reduce materials and processing costs of ACPDPs, aluminum fence electrodes were prepared on soda‐lime glass substrates by chemically etching aluminum foil bonded directly onto the substrate via an anodic‐bonding process. Several different fence‐electrode patterns were designed and coated either with a glass dielectric layer or with an anodic aluminum oxide layer. Firing voltages, operation margin, luminance, and luminous efficiency of such test panels were evaluated. The results indicated that the performance of test panels with aluminum fence electrodes is comparable with conventional test panels with ITO/Ag electrodes, demonstrating the possibility of a dramatic reduction in the costs of ACPDPs.     

直流电沉积CdS纳米线的研究

在磷酸溶液中，采用二次铝阳极氧化法得到了多孔铝阳极氧化膜(AAO)．以AAO为模板，选用直流电沉积方法在孔内组装CdS半导体纳米线，溶去模板后，获得粗细均一、直径约为100nm、长度约为1．5μm的纳米线，与AAO模板的孔径一致．该方法在制备过程中，无需对AAO模板进行去除阻挡层、喷金或预镀金属等处理过程，而是直接在纳米孔内电沉积CdS，形成CdS半导体纳米线阵列．该方法工艺简单，操作方便，容易获得半导体CdS的一维纳米材料．TEM和XRD测试结果表明，CdS纳米线为六方晶型结构．对CdS纳米线的生长机理还进行了初步的分析和探讨．     

Fabrication of alumina films with laminated structures by ac anodization

Anodization techniques by alternating current (ac) are introduced in this review. By using ac anodization, laminated alumina films are fabricated. Different types of alumina films consisting of 50–200 nm layers were obtained by varying both the ac power supply and the electrolyte. The total film thickness increased with an increase in the total charge transferred. The thickness of the individual layers increased with the ac voltage; however, the anodization time had little effect on the film thickness. The laminated alumina films resembled the nacre structure of shells, and the different morphologies exhibited by bivalves and spiral shells could be replicated by controlling the rate of increase of the applied potentials.     

Cu/AAO复合材料的制备及表征

通过阶梯降压法,成功制备出带有铝基底的有序多孔阳极氧化铝,铝基底与有序多孔氧化铝之间的阻挡层极薄。以该模板为阴极,采用循环伏安法电化学沉积技术制备出Cu/AAO纳米复合材料。分别用场发射扫描电子显微镜(FESEM)、透射电子显微镜(TEM)、X射线衍射(XRD)等测试方法对该纳米复合材料的形貌、组成和结构进行了表征和分析。结果表明,Cu纳米线在模板中填充率高,直径约为70nm,长度可达30μm,具有面心立方单晶结构。     

城市污水处理厂增加脱氮除磷功能的改造实践

为了满足国家对城市污水厂出水氮磷的排放要求,采用倒置AAO工艺对常州市某污水处理厂的三期工程原有普通活性污泥法工艺进行了改造.在没有新建生化反应池和增加回流系统的前提下,通过提高活性污泥浓度,在原生化反应池内进行了缺氧/厌氧/好氧功能区的分配,取得了良好的脱氮除磷效果.新工艺对NH3-N和TP的去除率均达到90%以上,对TN的去除率为45.4%.通过对生化反应池内污染物浓度沿程变化情况的监测,初步分析了工艺运行机理,为今后其它城市污水厂的改造积累了经验.     

A newly-developed wide range molecular flow meter based on AAO leak element

An innovate constant volume flow meter (ICVFM) using AAO leak element was developed, and then applied to measure the pumping speed of dry vacuum pumps. The AAO leak element was calibrated with dynamic differential pressure decay method. The results imply that the conductance of AAO leak is inversely proportional to the square root of the molecular mass, and remains unchanged with pressure varying from vacuum to atmosphere. Then the pumping speed was measured by a simple test system. In the end, the uncertainties of calibrating AAO leak element and measuring pumping speed were considered to confirm the measurement capability. The newly developed flow meter enables flow measurements at pressures ranging from vacuum through atmospheric pressure, which has potential application in the semiconductor industry.     

阳极氧化铝模板应用研究新进展

论述了AAO模板以其独特的六角有序纳米结构,组装1-D材料取得的成功,指出目前关注重点为AAO的应用研究.指出由于AAO模板易脆、存在绝缘阻挡层等缺点,其应用研究进展不大.阐述了为克服上述困难,将AAO模板转移到Si衬底或玻璃衬底上的可行性.分析表明,目前AAO模板的应用研究主要集中在发光器件和存储器件上,其他研究报导还很少.对近年来人们利用AAO模板开展应用研究方面的进展做了回顾和评述以其进一步加快AAO模板的应用.     

Anodic Aluminum Oxide Membrane-Assisted Fabrication of β-In2S3 Nanowires

In this study, β-In₂S₃ nanowires were first synthesized by sulfurizing the pure Indium (In) nanowires in an AAO membrane. As FE-SEM results, β-In₂S₃ nanowires are highly ordered, arranged tightly corresponding to the high porosity of the AAO membrane used. The diameter of the β-In₂S₃ nanowires is about 60 nm with the length of about 6–8 μm. Moreover, the aspect ratio of β-In₂S₃ nanowires is up to 117. An EDS analysis revealed the β-In₂S₃ nanowires with an atomic ratio of nearly S/In = 1.5. X-ray diffraction and corresponding selected area electron diffraction patterns demonstrated that the β-In₂S₃ nanowire is tetragonal polycrystalline. The direct band gap energy (E_g) is 2.40 eV from the optical measurement, and it is reasonable with literature.     

高度有序多孔氧化铝模板影响因素的研究

在酸性电解液中,用阳极氧化法制备得到了多孔阳极氧化铝(anodic aluminum oxide,AAO)模板。用金相显微镜观察了铝箔退火后表面上的晶界,并结合扫描电镜对多孔氧化铝薄膜进行了观察和表征。研究了影响多孔氧化铝模板孔洞有序性的关键性因素。实验结果表明,多孔阳极氧化铝膜的有序度依赖于铝箔预处理、氧化电压和电解液等的选择。