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排序方式: 共有329条查询结果,搜索用时 31 毫秒
1.
2.
Marta Fernndez-García Pedro Francisco Caamero Jos Luis de la Fuente 《Reactive and Functional Polymers》2008,68(9):1384-1391
Epoxy-functional spontaneous gradient copolymers of glycidyl methacrylate (G) and n-butyl acrylate (B) were synthesized via atom transfer radical polymerization (ATRP). The copolymerization reactions were carried out in toluene solution at 70 °C, using methyl 2-bromopropionate (MBrP) as initiator and copper chloride with N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The kinetic behaviour of the statistical copolymerizations was studied in a wide composition interval with molar fractions of G ranging from 0.10 to 0.75. The synthesized copolymers were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. 1H NMR was employed to determine the copolymer composition, demonstrating the gradient character of the copolymers along the main chain in the whole monomer conversion interval. Apart from this, the sequence distribution and stereoregularity were analyzed. These microstructural experimental data agreed well with those calculated from Mayo-Lewis terminal model (MLTM) and a Bernoullian statistic with an isotacticity parameter of σG = 0.28 and a coisotacticity parameter of σ = 0.30. 相似文献
3.
In this work, the kinetics and mechanism of free-radical polymerisation of glycidyl methacrylate (GMA) using potassium peroxydisulphate
(PDS) as water soluble initiator in the presence of synthesized 1, 4-Bis (tributyl methyl ammonium) benzene dichloride (TBMABDC)
as multi-site phase transfer catalyst (MPTC) was studied. The polymerisation reactions were carried out under inert and unstirred
conditions at constant temperature of 60 ± 1°C in cyclohexane/water biphase media. The role of concentrations of monomer,
initiator, catalyst and volume fraction of aqueous phase, solvent polarity and temperature on the rate of polymerisation (Rp)
was ascertained. The order with respect to monomer and initiator was found to be unity. The order with respect to catalyst
was found to be 0.51. The rate of polymerisation is independent of ionic strength and pH of the medium. However, an increase
in the polarity of solvent has slightly increased the Rp value. Based on the results obtained, a suitable kinetic scheme has
been proposed to account for the experimental observations and its significance discussed. 相似文献
4.
采用种子乳液聚合法制备了含有PBA\PMMA\PS三种组分的丙烯酸酯类抗冲型改性剂ACR,在ACR的幔层结构中引入接枝剂甲基丙烯酸烯丙酯(ALMA)来完善幔层结构,从而实现核一壳之间良好的结合,用红外光谱(FTIR)和差示扫描量热法(DSC)对ACR的组成和结构进行表征。研究结果表明:由PBA\PMMA\PS三组分构成的ACR在抗冲击性能上要略优于由简单的PBA\PMMA构成的ACR,苯乙烯单体(St)最多可以取代大约1/3壳层的甲基丙烯酸甲酯(MMA),甲基丙烯酸烯丙酯(ALMA)的引入对幔层结构的完善起了显著的作用。 相似文献
5.
用4,4′-二苯氧基二苯砜(DPODPS)分别与对苯二甲酰氯(TPC)、间苯二甲酰氯(IPC)或2,5-二氯对苯二甲酰氯(DCC)在1,2-二氯乙烷(DCE)中,以无水 AlCl_3为催化剂,在 N-甲基吡咯烷酮(NMP)存在下,通过付-克亲电聚合反应,制得了五种不同结构的聚醚醚酮酮砜(简称PEEKKS)。用红外光谱(IR)、X-射线衍射(XRD)、扫描电镜(SEM)、差示扫描量热(DSC)、热重(TG)及耐溶剂试验,对聚合物进行了表征。结果表明,五种聚合物的对数比浓粘度(η_(inh))均达到0.85以上.具有较低的熔融温度、良好的溶解性能和耐高温性能,PEEKKS 属于非晶态聚合物。 相似文献
6.
Performance of the polymer- and oxide-supported triphase catalysts and effect of ultrasound on their stabilities 总被引:1,自引:0,他引:1
Hsieh-Ting Chung Hung-Shan Weng 《Journal of the Chinese Institute of Chemical Engineers》2008,39(5):449-455
In this study, several trialkylamines were immobilized on chloromethylated polystyrene (CMPS), silica gel, and alumina to prepare triphase catalysts for catalyzing the etherification reaction of allyl bromide (the organic reactant) and sodium phenolate (the aqueous reactant). The reactor was agitated mechanically or with the aid of ultrasonic vibration. Performances of the prepared catalysts were compared, and the effect of imposing ultrasound was investigated based on the activity, selectivity, and stability of the catalyst. Experimental results show that tri-n-propylamine is the best active species when CMPS is used as the support, while tri-n-butylamine is the best when SiO2 and Al2O3 are employed as the supports. The CMPS-supported catalyst is far better than the SiO2- and Al2O3-supported catalysts in activity and selectivity but not in stability. Imposing the ultrasound can effectively increase the reaction rate. Mechanical agitation at a low speed with the imposition of ultrasonic vibration not only results in a conversion slightly higher than the case with a high mechanical agitation speed without ultrasonic vibration, but also gives a constant stability for the CMPS-supported catalyst. 相似文献
7.
杨成军 《计算机光盘软件与应用》2011,(14)
在进入“三网融合”的今天,全国广电网络面临着从单向单一的数字电视传输网络改为双向多功能多业务网,本文就以湄潭县城区有线电视传输网为例,根据目前网络实际情况出发,简单介绍几种进行低成本、高效率的双向改造组网方式,为了给更多的用户提供更加多的双向业务,建立稳定可靠、可运营、可持续发展的广电双向网络,最终达到三网融合。 相似文献
8.
21世纪的"绿色燃料"--二甲醚 总被引:9,自引:0,他引:9
被称为 2 1世纪“绿色燃料”的二甲醚具有清洁、低毒性、低蒸气压和优良的燃烧性能 ,因而成为多种产品的替代品 ,如环境友好的民用燃料、柴油和制冷剂 ,而且具有较好的市场潜力。本文主要介绍了二甲醚的生产方法、用途和国内外的发展状况 相似文献
9.
南昌市昌北闸门控制系统负责南昌市整个昌北地区的防洪排涝任务,以其中的前湖电排站为例,详细介绍了基于工业以太网的闸门群组控制系统的组成结构、现场控制所用的PLC选型依据,结合程序流程图给出了现场控制程序的编制原则和部分程序实例,介绍了基于工业以太网的WinCC组态软件的设计方法,给出了部分控制界面。根据“数字昌北”的扩展性要求,系统在结构上具有良好的延展性,采取软硬件结合的方式保证其响应速度,投入运行以来工作稳定可靠,降低了人工操作的危险性和不准确性,减轻了人员的劳动强度,实现了预期的目标,得到了用户的高度肯定。 相似文献
10.
p-TsOH-mediated the direct α-substitution of cyclic Morita–Baylis–Hillman alcohols with aliphatic and aromatic thiols in refluxing THF. The reaction proceeded with complete α-regioselectivity and provided the corresponding allyl sulfides in moderate to good yields. 相似文献