全文获取类型
收费全文 | 62511篇 |
免费 | 3001篇 |
国内免费 | 1801篇 |
专业分类
电工技术 | 1910篇 |
技术理论 | 1篇 |
综合类 | 3689篇 |
化学工业 | 10398篇 |
金属工艺 | 5446篇 |
机械仪表 | 3183篇 |
建筑科学 | 2137篇 |
矿业工程 | 880篇 |
能源动力 | 2267篇 |
轻工业 | 2602篇 |
水利工程 | 235篇 |
石油天然气 | 1838篇 |
武器工业 | 344篇 |
无线电 | 6255篇 |
一般工业技术 | 11127篇 |
冶金工业 | 1396篇 |
原子能技术 | 787篇 |
自动化技术 | 12818篇 |
出版年
2024年 | 83篇 |
2023年 | 619篇 |
2022年 | 1000篇 |
2021年 | 1049篇 |
2020年 | 941篇 |
2019年 | 1101篇 |
2018年 | 943篇 |
2017年 | 1350篇 |
2016年 | 1645篇 |
2015年 | 1925篇 |
2014年 | 2672篇 |
2013年 | 2727篇 |
2012年 | 3181篇 |
2011年 | 4775篇 |
2010年 | 3604篇 |
2009年 | 4035篇 |
2008年 | 3586篇 |
2007年 | 3570篇 |
2006年 | 3155篇 |
2005年 | 2762篇 |
2004年 | 3159篇 |
2003年 | 2836篇 |
2002年 | 3208篇 |
2001年 | 2203篇 |
2000年 | 1913篇 |
1999年 | 1627篇 |
1998年 | 1091篇 |
1997年 | 1060篇 |
1996年 | 1819篇 |
1995年 | 1073篇 |
1994年 | 783篇 |
1993年 | 299篇 |
1992年 | 257篇 |
1991年 | 244篇 |
1990年 | 214篇 |
1989年 | 134篇 |
1988年 | 103篇 |
1987年 | 72篇 |
1986年 | 98篇 |
1985年 | 97篇 |
1984年 | 67篇 |
1983年 | 45篇 |
1982年 | 45篇 |
1981年 | 37篇 |
1980年 | 24篇 |
1979年 | 22篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1975年 | 6篇 |
1973年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
High-purity mullite ceramics, promising engineering ceramics for high-temperature applications, were fabricated using transient liquid phase sintering to improve their high-temperature mechanical properties. Small amounts of ultrafine alumina or silica powders were uniformly mixed with the mullite precursor depending on the silica-alumina ratio of the resulting ceramics to allow for the formation of a transient liquid phase during sintering, thus, enhancing densification at the early stage of sintering and mullite formation by the reaction between additional alumina and the residual glassy phase (mullitization) at the final stage of sintering. The addition of alumina powder to the silica-rich mullite precursor resulted in a reaction between the glassy silica and alumina phases during sintering, thereby forming a mullite phase without inhibiting densification. The addition of fine silica powder to the mullite single-phase precursor led to densification with an abnormal grain growth of mullite, whereas some of the added silica remained as a glassy phase after sintering. The resulting mullite ceramics prepared using different powder compositions showed different sintering behaviors, depending on the amount of alumina added. Upon selecting an optimum process and the amount of alumina to be added, the pure mullite ceramics obtained via transient liquid phase sintering exhibited high density (approximately 99%) and excellent high-temperature flexural strength (approximately 320 MPa) at 1500 °C in air. These results clearly demonstrate that pure mullite ceramics fabricated via transient liquid phase sintering with compositions close to those of stoichiometric mullite could be a promising process for the fabrication of high-temperature structural ceramics used in an ambient atmosphere. The transient liquid phase sintering process proposed in this study could be a powerful processing tool that allows for the preparation of superior high-temperature structural ceramics used in the ambient processing atmosphere. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(8):5609-5626
The demand for clean energy use has been increasing worldwide, and hydrogen has attracted attention as an alternative energy source. The efficient transport of hydrogen must be established such that hydrogen may be used as an energy source. In this study, we considered the influences of various parameters in the transportation of liquefied hydrogen using type C tanks in shipping vessels. The sloshing and thermal flows were considered in the transportation of liquefied hydrogen, which exists as a cryogenic liquid at ?253 °C. In this study, the sloshing flow was analyzed using a numerical approach. A multiphase sloshing simulation was performed using the volume of fluid method for the observation and analysis of the internal flow. First, a sloshing experiment according to the gas-liquid density ratio performed by other researchers was utilized to verify the simulation technique and investigate the characteristics of liquefied hydrogen. Based on the results of this experiment, a sloshing simulation was then performed for a type C cargo tank for liquefied hydrogen carriers under three different filling level conditions. The sloshing impact pressure inside of the tank was measured via simulation and subjected to statistical analysis. In addition, the influence of sloshing flow on the appendages installed inside of the type C tank (stiffened ring and swash bulkhead) was quantitatively evaluated. In particular, the influence of the sloshing flow inside of the type C tank on the appendages can be utilized as an important indicator at the design stage. Furthermore, if such sloshing impact forces are repeatedly experienced over an extended period of time under cryogenic conditions, the behavior of the tank and appendages must be analyzed in terms of fatigue and brittle failure to ensure the safety of the transportation operation. 相似文献
3.
《Ceramics International》2022,48(7):9330-9341
This study investigates the effects of densification on the deformation and fracture in fused silica under Vickers indentation by both the finite element analysis (FEA) and experimental tests. A refined elliptical constitutive model was used, which enables us to investigate the effects of the evolution of yield stress under pure shear and elastic properties with densification. The densification distribution was predicted and compared with experiments. The plastic deformation and indentation stress fields were used to analyze the initiation and morphology of various crack types. The formation mechanism of borderline cracks was revealed for the first time. This study reveals that the asymmetry of the densification distribution and elastic-plastic boundary significantly influences the cracking behavior. Under the Vickers indentation, conical cracks have the largest penetration depth. When these cracks emerge from a region far from the impression, they extend with constant radii to form circles on the sample surface. Otherwise, they tend to be initiated at the centers of the indenter-material contact edges before propagating towards the impression corners with increasing radii. Therefore, the borderline cracks consisting of successive partial conical cracks can form at a low load and makes them the first type of crack to appear. 相似文献
4.
5.
《Ceramics International》2021,47(23):33223-33231
The effects of pH of the reaction solution and the concentration of phosphoric acid on the crystal growth behavior of LaPO4 crystallites were investigated and the mechanical properties of rare-earth phosphates were compared. As a result, the concentration of phosphoric acid of 10% was beneficial to the crystal growth of LaPO4 nanocrystalline. When the pH value of the reaction solution was 2, the size of LaPO4 crystallites increased gradually with the increasing reaction temperature, and the smallest crystallite size of 43.27 nm was obtained after heat-treatment at 1000 °C. Simultaneously, the activation energy for crystal growth of LaPO4 nanocrystalline was relatively lower (26.82 kJ mol−1). With the decreasing radii of rare-earth ions, the hardness, Young's modulus and fracture toughness of the bulk rare-earth phosphates exhibited a reduced tendency, resulted from the increase of porosity under the same preparation process. 相似文献
6.
Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films are attracting famous applications in antistatic coating, energy storage and conversion, printed electronics, and biomedical fields due to their conductivity, optical transparency and flexibility. However, PEDOT:PSS has poor dispersion stability during long-term storage and transport. Moreover, the dried PEDOT:PSS films are insoluble in any solvent and cannot be redispersed again. In comparison to bake drying, here, a feasible strategy to achieve mechanically redispersed PEDOT:PSS with the help of freeze-drying process was reported. The redispersed PEDOT:PSS can recover not only the initial characters such as pH, chemical composition, viscosity, and particle size under similar solid contents, but also conductivity and surface morphology of treated films. In addition, the treated film exhibits self-healing properties similar to pristine film in terms of mechanical and electrical properties. This technology enables reuse and overcomes the technical problems of PEDOT:PSS dispersion, realizing real-time processing to meet variable applications. 相似文献
7.
《Ceramics International》2022,48(12):16923-16932
This paper offers a new way of testing the ablation property of material under an oxyacetylene torch using a thin-blade specimen, which costs much less time to reach the maximum temperature and provides a harsh turbulence fluid field that's closer to reality. The thin-blade specimen experiences a higher turbulent intensity than the traditional disk-like specimen, leading to more efficient heat exchange. The fluid field simulation agrees with the testing results. In addition, we manage to synthesize the C/Cx-SiCy composites with the co-deposition chemical vapor infiltration (CVI) method. The C/Cx-SiCy composites exhibit a similar anti-ablation property as C/C composites and consist of enough SiC phase simultaneously, combining the advantages of both C/C composites and C/SiC composites. The thin-blade C/Cx-SiCy composites show a lower linear ablation rate (1.6 μm/s) than C/C composites (4.1 μm/s) and C/SiC composites (19.6 μm/s) during the oxyacetylene test. The glass layer formed on the surface of C/Cx-SiCy could cling to the bulk material instead of peeling off due to the high PyC content in the matrix could protect the SiO2 from blowing away. 相似文献
8.
Aleksandar Miletić Peter Panjan Miha Čekada Lazar Kovačević Pal Terek Janez Kovač Goran Dražič Branko Škorić 《Ceramics International》2021,47(2):2022-2033
With the goal to produce a hard and tough coating intended for tribological applications, CrAlN/TiSiN nanolayer coating was prepared by alternative deposition of CrAlN and TiSiN layers. In the first part of the article, a detailed study of phase composition, microstructure, and layer structure of CrAlN/TiSiN coating is presented. In the second part, its mechanical properties, fracture and tribological behavior are compared to the nanocomposite TiSiN coating. An industrial magnetron sputtering unit was used for coating deposition. X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used for compositional and microstructural analysis. Mechanical properties and fracture behavior were studied by instrumented indentation and focused ion beam techniques. Tribological properties were evaluated by ball-on-disk test in a linear reciprocal mode. A complex layer structure was found in the nanolayer coating. The TiSiN layers were epitaxially stabilized inside the coating which led to formation of dislocations at interfaces, to introduction of disturbances in the coating growth, and as a result, to development of fine-grained columnar microstructure. Indentation load required for the onset of fracture was twice lower for the nanolayer CrAlN/TiSiN, compared to the nanocomposite TiSiN coating. This agrees very well with their mechanical properties, with H3/E2 being twice higher for the TiSiN coating. However, the nanolayer coating experienced less severe damage, which had a strong impact on tribological behavior. A magnitude of order lower wear rate and four times lower steady state friction coefficient were found for the nanolayer coating. 相似文献
9.
Solomon Hanson Duntu Francis Tetteh Iftikhar Ahmad Mohammad Islam Solomon Boakye-Yiadom 《Ceramics International》2021,47(1):367-380
The onset of hybrid alumina-based composites, which combines two or more nano-particles within the alumina matrix has already shown promising improvements in the matrix material. However, variations in mechanical properties including the optimum compositions that give improved properties faced with the development of alumina-based composites require further studies to understand the underlying mechanisms and synergistic effects of the nano-particle additions on the alumina matrix. In the current study, the structure and properties of Al?O?-graphene (0.5 wt%) and Al?O?–ZrO? (4 wt% and 10 wt%) composites fabricated via hot-pressing was studied as a baseline for multiple combinations. Even though the addition of 10 wt%ZrO? resulted in a 23% reduction in the grain size of the alumina matrix, the 4 wt%ZrO? addition resulted in a 14% increase in grain size as compared to the parent alumina matrix. X-ray diffraction analysis revealed that there was approximately 85% monoclinic (m-ZrO2) vs. 15% tetragonal (t-ZrO2) crystal structures in the A4ZrO? sample whilst the A10ZrO? had approximately 93% m-ZrO2 vs. 7% t-ZrO2. The high-volume fraction of the monoclinic crystal structures in the A10ZrO? accounts for the induced microcracks in the sample since the transition from the ductile-tetragonal to brittle-monoclinic is associated with the exertion of compressive stresses on the alumina matrix by the associated elastic volume expansion of m-ZrO2. Also, the addition of 0.5 wt%graphene resulted in about 37% reduction in the grain size of the alumina matrix, and approximately 10% increase in hardness as a result of the distribution of graphene along the grain boundaries of the parent alumina matrix, which restricts grain coalescence and growth during processing. Furthermore, an increase up to 115% and 164% were observed in the fracture toughness (KIC) with the inclusion of 0.5 wt%graphene and 10 wt%ZrO? respectively, which was primarily ascribed to the fine-grained microstructures and toughening mechanisms of the intergranular graphene and ZrO? particles. 相似文献
10.
《Ceramics International》2021,47(21):29949-29959
High carbon footprint of cement production is the major drawback of plain cement concrete resulting in environmental pollution. Geopolymer composites paste can be effectively used as an alternative to Portland cement in the construction industry for a sustainable environment. The demand for high-performance composites and sustainable construction is increasing day by day. Therefore, the present experimental program has endeavored to investigate the mechanical performance of basalt fiber-reinforced fly ash-based geopolymer pastes with various contents of nano CaCO3. The content of basalt fibers was fixed at 2% by weight for all specimens while the studied contents of nano CaCO3 were 0%, 1%, 2%, and 3%, respectively. The compressive strength, compressive stress-strain response, flexural strength, bending stress-strain response, elastic modulus, toughness modulus, toughness indices, fracture toughness, impact strength, hardness, and microstructural analysis of all four geopolymer composite pastes with varying contents of nano CaCO3 using scanning electron microscopy (SEM) were evaluated. The results revealed that the use of 3% nano CaCO3 in basalt fiber-reinforced geopolymer paste presented the highest values of compressive strength and hardness while the use of 2% nano CaCO3 showed the highest values of flexural strength, impact strength, and fracture toughness of composite paste. The SEM results indicated that the addition of nano CaCO3 improved the microstructure and provided a denser geopolymer paste by refining the interfacial zones and accelerating the geopolymerization reaction. 相似文献