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Synthesis of dimethyl acetal of ketones: design of solid acid catalysts for one-pot acetalization reaction 总被引:1,自引:0,他引:1
Bejoy Thomas Sreedharan Prathapan Sankaran Sugunan 《Microporous and mesoporous materials》2005,80(1-3):65-72
The synthesis of dimethyl acetals of carbonyl compounds such as cyclohexanone, acetophenone, and benzophenone has successfully been carried out by the reaction between ketones and methanol using different solid acid catalysts. The strong influence of the textural properties of the catalysts such as acid amount and adsorption properties (surface area and pore volume) determine the catalytic activity. The molecular size of the reactants and products determine the acetalization ability of a particular ketone. The hydrophobicity of the various rare earth exchanged Mg–Y zeolites, K-10 montmorillonite clay, and cerium exchanged montmorillonite (which shows maximum activity) is more determinant than the number of active sites present on the catalyst. The optimum number of acidic sites as well as dehydrating ability of Ce3+-montmorillonite and K-10 montmorillonite clays and various rare earth exchanged Mg–Y zeolites seem to work well in shifting the equilibrium to the product side. 相似文献
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Acetalization of ketones on K-10 clay and rare earth exchanged HFAU-Y zeolites: A mild and facile procedure for the synthesis of dimethylacetals 总被引:3,自引:0,他引:3
Dimethylacetals of ketones; cyclohexanone, acetophenone, and benzophenone have been prepared by reacting ketones with methanol
under mild reaction conditions. Large pore zeolites (H-Y and its rare earth metal, Ce3+, La3+, and RE3+ modified forms), and mesoporous clay (K-10 montmorillonite and its cerium exchanged counterpart) with regular pore structure,
silica and silica-alumina have been used as catalysts. Clay catalysts are found to be much more active than zeolites, thanks
to slightly bigger pore size. The nature of the pores of the solid acid catalysts determine acetalization efficiency of a
particular catalyst. As evidenced by the reaction time studies, the catalyst decay is greater over the zeolites than over
the clays. Carrying out the reaction with ketones of different molecular sizes it is shown that K-10 clays and rare earth
exchanged H-Y zeolites are promising environmentally friendly catalysts for their use in the production fine chemicals. 相似文献
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