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排序方式: 共有65条查询结果,搜索用时 15 毫秒
1.
《中国稀土学报(英文版)》2022,40(6):897-905
A family of Ce-doped LaCoO3 perovskites are presented as possible catalysts for Cl–VOCs elimination. These materials with different contents of Ce were obtained through the citrate and the reactive grinding methods. The insertion of Ce in the original perovskite structure favours the presence of Co2+/Co3+ and Ce3+/Ce4+ redox pairs and a higher content of oxygen vacancies that enhances the catalytic performance in chlorobenzene combustion based on differential kinetics studies. The family obtained by the grinding method presents a performance as high as that synthesized by citrate method. Thus, the reactive grinding is a feasible green chemistry alternative to obtain a catalyst with the same performance as that obtained from traditional methods. Finally, the stability of samples was evaluated under total combustion reaction conditions showing an excellent activity during 45 h time on stream. 相似文献
2.
3.
Removal of the persistent pollutant chlorobenzene by adsorption onto activated montmorillonite 总被引:1,自引:0,他引:1
The potential of activated bentonite was assessed for adsorption of chlorobenzene from aqueous solution. The bentonite used was treated by chemical and thermal activation over 100–500 °C. The thermal activation increased the adsorption capacity more strongly than chemical activation which consists to acid and hydrogen peroxide treatment. The removal is dominated by adsorption at low initial concentrations and low temperatures and favourable in acidic media. The dependence of the adsorption on pH appears to be related to the solubility of chlorobenzene. Thermodynamic parameters such as ΔH°, ΔS°, ΔG° and Ea have been calculated. The adsorption process is spontaneous and exothermic in nature. The Freundlich isotherm described the adsorption data over the concentration range (20–270 °C). 相似文献
4.
New dehalogenation catalysts Pd/SBA-1 mesoporous molecular sieves are synthesized and characterized by N2 adsorption/desorption, XRD, XPS, FT-IR, DR-UV–vis and AAS. In liquid-phase catalytic transfer hydrogenation of chlorobenzene
reaction, low Pd content catalyst Pd/SBA-1 is found to be an efficient catalyst in water/ethanol (2/3) solution of NaOH. The
catalyst can easily be recovered and efficiently reused at least three times. 相似文献
5.
采用顶空-气相色谱法同时测定生活饮用水及水源水中1,2-二氯苯、1,4-二氯苯、1,2,3-三氯苯、1,2,4-三氯苯、1,3,5-三氯苯、六氯苯6种氯苯类化合物。测定结果的相对标准偏差为1.6%~2.8%。回收率为95.9%~100.4%。通过实样分析验证了方法的适用性。 相似文献
6.
Hydrodechlorination of chlorobenzenes on platinum (Pt)-supported γ-alumina and alumina Lewis superacid (AmLSA) catalysts was carried out at room temperature and ambient pressure using a fixed bed flow reactor and a semi-batch reactor. Both the catalysts indicated good activity for the hydrodechlorination, but the former was superior to the latter. The hydrodechlorinations of reactants C6H6−xClx (x=1, 2, 3) proceeded step-wisely to benzene and then cyclohexane via C6H6−yCly (y=x−1). The reactions seem to be promoted by the contribution of spillover hydrogen formed on the Pt-supported catalysts. The catalysts deactivated with reaction time and the amount of chlorine that accumulated on the Pt-supported γ-alumina catalyst in the hydrodechlorination of 1,4-dichlorobenzene for 3 h was near to that estimated from the converted reactant molecules. When the deactivated catalysts were treated in a stream of hydrogen above 503 K, the original activity was completely restored, but the deactivation phenomenon with reaction time was observed again. 相似文献
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8.
对氯苯磺酰氯的合成进展及改进方向 总被引:1,自引:0,他引:1
本文介绍了精细化工中间体对氯苯磺酰氯的用途,及其重要的后续产品聚砜的优良特性和巨大的市场潜力,列举了国内外对氯苯磺酰氯的几种工业化生产工艺及其所造成的环境问题,综述了过量氯磺酸法制取对氯苯磺酰氯的研究进展,最后在不改变国内工业原料路线的前提下,根据氯磺化的反应机理.依据清洁生产的思想,从改变工艺操作、选用惰性溶剂及运用固相分离介质等几个方面提出改进传统过量氯磺酸法生产工艺的一些思路。 相似文献
9.
Rajesh Gopinath N. Seshu Babu J. Vinod Kumar N. Lingaiah P. S. Sai Prasad 《Catalysis Letters》2008,120(3-4):312-319
A series of alumina supported Pd catalysts were prepared by the novel deposition-precipitation method adopting the chloride
precursor (DP-Cl) of Pd and varying the metal content from 0.25 to 1.0 wt%. The catalytic properties of prepared catalysts
were studied by various characterization techniques such as N2 adsorption, CO chemisorption, TPR, XRD, XPS, and TEM techniques. The activity and stability of the catalysts were evaluated
for the gas phase hydrodechlorination (HDC) of chlorobenzene operating at atmospheric pressure. At 1 wt% of Pd the catalyst
showed higher chlorobenzene conversion with good stability when tested for a period of 25 h, whereas the other catalysts exhibited
a loss in activity with time. In order to elucidate the exceptional activity and stability of this catalyst, a few more catalysts
with 1 wt% Pd were prepared by impregnation technique and also using a non-chloride precursor, palladium nitrate. The 1 wt%
DP-Cl catalyst again was found to be the best among the others. The activity and stability of the DP-Cl catalyst was also
found to be superior to two low-dispersed catalysts, each with 10 wt% Pd, prepared by conventional impregnation method using
the chloride and nitrate as the precursors. The characterization results reveal that the high activity and stability of the
DP-Cl catalyst is related to the formation of electron deficient Pd species and its stabilization in the octahedral vacancies
of alumina. 相似文献
10.