新催化剂合成DOP

简要介绍了自制催化剂：Ｔｉ（ＯＭｅ）４／ＳｉＯ２－ＭｇＯ合成邻苯二甲酸酯（ＤＯＰ）增塑剂的概况，该增塑剂对提高ＰＶＣ电缆料的耐绝缘性有好处。     

Theoretical analysis of polarization properties for tilted fiber Bragg gratings

The polarization properties for tilted fiber Bragg gratings (TFBGs) are investigated theoretically based on coupled-mode theory and Mueller matrix method. The expression of wavelength-related polarizationdependent loss (PDL) for TFBGs with different tilt angles is derived and calculated. Simulation results are compared, and the results indicate that the polarization capability of TFBGs with 45° angle is stronger than other TFBGs with smaller angles. The degree of polarization for unpolarized light passing T...     

光副载波复用系统中偏振模色散对偏振度的影响

在光副载波复用系统中若使用偏振度作为偏振模色散的监测信号将会遇到灵敏度低的问题.本文首先讨论了色度色散和初始啁啾对偏振度的影响,然后找出了影响监测信号灵敏度的因素,并提出了相应的解决方法.使用一个窄带滤波器用来平衡光载波和边带的功率,偏振度对偏振模色散的灵敏度将会明显的增长.     

光纤型偏振OCT 系统中光偏振特性的研究

建立了偏振光在生物组织中传播的模型,并利用该模型模拟了偏振光在生物组织中传播的过程,重建了多种偏振态输入光的情况下光偏振态在生物组织中的分布及生物组织的偏振特性模型.分析了光偏振度与光被生物组织散射次数的关系,阐明了由于偏振光在组织中传播,其偏振态逐渐改变而造成的偏振OCT 干涉计两臂光束失去相干性及偏振OCT 图像质量下降现象.通过分析斯托克斯(Stokes)矢量和穆勒(Muller)矩阵在光纤型偏振OCT系统中的应用,说明Muller 矩阵不受输入光偏振态的影响,因此它比Stokes 矢量更适用于光纤型偏振OCT 系统研究.     

纳米SiO2抑制PVC中增塑剂DOP迁移的研究

实验通过添加纳米粒子SiO2,研究抑制软质聚氯乙烯(PVC)中增塑剂邻苯二甲酸二辛脂(DOP)迁移规律,评价PVC样品溶剂抽出率,对挥发损失率、拉伸性能和邵氏硬度的测定分析,得出以下结论:纳米粒子SiO2可以抑制软质PVC中DOP的迁移。用正己烷浸泡PVC样品,随浸泡时间的延长,溶剂抽出率增大;随着添加的纳米SiO2含量的增加,样品的溶剂抽出率降低。在浸泡24h后,添加5份纳米SiO2样品PVC的溶剂抽出率为18.9%,比对照(25.6%)降低了26.2%。添加少量的纳米SiO2并没有使样品的挥发损失率明显降低,添加1~5份不同量的纳米SiO2的样品的挥发损失率均比不添加纳米SiO2的对照样品低。随着无机纳米粒子含量的增加,样品的拉伸强度和断裂伸长率反而降低,硬度有所增加。      

Reducing the migration of additives from plasticised poly(vinyl chloride)

This paper reports work studying the partial substitution of the commonly used plasticiser di-octyl phtalate (DOP) by the permanent plasticisers ethylene-vinyl-acetate (EVA) and acrylonitrile-butadiene-styrene (ABS) in order to reduce migration of additives initially present in poly(vinyl chloride) (PVC) stabilised with epoxidised sunflower oil (ESO). Various formulations with and without the two different permanent plasticisers were prepared. Their tensile properties were compared. Migration tests with agitation at 40°C in two food simulants (olive oil and 15% aqueous ethanol) were carried out. The mass variation of the PVC samples with time was investigated. Migration phenomena were studied by using various analytical methods such as Fourier transform infrared spectroscopy (FTIR), atomic absorption spectrometry (AAS) and scanning electron microscopy (SEM). The results showed that additives migration can be considerably reduced by partial substitution of DOP with both permanent plasticisers used. The best results were obtained with the binary system of plasticisers based on DOP:ABS (30:10).     

伪卫星定位系统中组网布局研究

为达到伪卫星在任一时间、地点都能对目标进行精确可靠定位,对影响定位精度的关键技术—组网布局进行讨论。分析伪卫星及伪卫星定位系统的基本概念,探讨影响组网布局的3个因素：伪卫星定位系统的定位原理、伪卫星的＂视距＂范围和几何衰减因子。结果表明,几何精度因子GDOP与被观测伪卫星所构成的四面体体积成反比。     

PVC保鲜膜中增塑剂DOP在水中迁移规律研究

主要研究了不同几种MA条件下3种PVC保鲜膜中增塑剂DOP在蒸馏水中的迁移规律(模拟果蔬MA保鲜的环境),以PE保鲜膜对照。结果表明,3种PVC保鲜膜包装的蒸馏水中增塑剂DOP有不同程度的迁移,而在PE膜包装的水中没有检测到DOP的迁移。PVC保鲜膜DOP的迁移量与温度、时间、保鲜膜DOP的含量、保鲜膜的厚度有一定的相关性。     

Improving the transfer of near infrared prediction models by orthogonal methods

Eight calibration transfer methods based on the removal of orthogonal signal were compared for the standardization of whole soybean protein and oil models. Dynamic orthogonal projection (DOP), transfer by orthogonal projection (TOP), error removal by orthogonal subtraction (EROS), orthogonal signal correction (OSC), and orthogonal projections to latent structures (O-PLS) as well as the modification and extension of some of these methods were compared in the transfer of models in intra and inter-brand situations using two Foss Infratecs and two Bruins OmegAnalyzerGs. For each brand, a master was designated and its models transferred onto the second unit of its network and the two units of the second brand. Calibration models were transferable from brand to brand with similar or better precision than when each instrument was calibrated on its own calibration set (for Infratec 1229, the relative predictive determinant (RPD) increased in intra and inter-brand calibration transfer situations from 10.42 to 11.45 and 10.57, with DOP and EROS respectively). Performance of each method was different across parameters, instruments, and validation sets. DOP modifications on the determination of the difference matrix showed promising results while TOP and EROS extensions to include variability specifically present in certain crop years did not bring any beneficial effects.     

以杂多蓝为催化剂合成邻苯二甲酸二辛酯的研究

本文研究了在常压和较低的温度下的均相和固载型杂多蓝催化剂在合成ＤＯＰ中的催化作用。实验表明在合成ＤＯＰ的酯化反应中，杂多蓝具有较高的催化活性和选择性。