Cure reaction for modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide

The glass‐transition temperature as a function of curing conversion for a modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide (BMI) resin was investigated at different temperature regimes and modeled using a modified Di Benedetto equation. Although the relationship between the glass‐transition temperature and conversion of the BMI system conforms to the Di Benedetto equation for α < 0.6 and at lower cure temperatures, at higher cure temperatures the results deviated significantly from the equation; thus, it was an inadequate model for the system. Fourier transform IR analysis showed that the major crosslinking reactions did not occur during cure for the modified BMI at and below 150°C. However, as the cure temperature was increased, the crosslinking reactions responsible for 3‐dimensional network structures became more dominant. At 190°C the C? N? C_stretch vibration of the uncured maleimide ring converted into succinimide rings in the curing process. Simultaneously, a decrease was observed for the absorbance bands of ? C? H_bending (maleimide). The higher cure temperatures induced a significantly faster initial crosslinking rate and also resulted in a shorter period of time after which further crosslinking was retarded, because the increase in the crosslinks also physically slowed further crosslinking activity. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 227–235, 2002     

苯和二异丙苯烷基转移化反应的研究

研究了二异丙苯转移烷基化反应中，催化剂配制条件等因素对反应的影响，对均相条件下的二异丙苯转移烷基化反应动力学进行了研究，得到了反应动力学方程。     

固体超强酸催化剂在合成癸二酸二异辛酯反应中的研究

选用固体超强酸SO2 -4 ZrO2 -TiO2 催化合成癸二酸二异辛酯 ,制备该催化剂的最优条件为 :钛锆物质的量比为 7∶1,用浓度为 0 .5mol·L- 1 硫酸浸渍 ,5 5 0℃焙烧 3h ;使用该催化剂合成癸二酸二异辛酯的最佳反应条件为 :醇酸物质的量比为 3.0∶1,催化剂用量 3.5g moL ,反应时间 4h ,酯化率达 99.4 %。     

Di对Mg-10Al合金显微组织与力学性能的影响

研究了Di加入量为1％～3％（质量分数，下同）[Nd—Pr混合稀土金属，w（Nd）：w（Pr）=3：1]的Mg-10Al合金的显微组织和力学性能。通过显微组织分析发现Di加入Mg-10Al合金后，析出了块状的Al2（Nd，Pr）相及杆状的Al11（Nd，Pr）3相，合金组织得到细化。Di的加入使铸态的Mg-10Al合金的力学性能提高，在Di的加入量为2％时，块状的Al2（Nd，Pr）相占主导地位，合金的抗拉强度和伸长率都达到峰值。在Di的加入量达到3％时，杆状的Al11（Nd，Pr），相增加，抗拉强度、尤其是伸长率有所降低。     

移动Agent的安全性问题探讨

介绍了移动Agent的安全性问题：1）保护运行移动Agent的主机或称运行环境免遭恶意移动Agent的攻击和破坏;2）保护移动Agent免遭运行环境的攻击。并就这两个方面问题的一些解决方案的思想、各自的特点、实现方法以及存在的问题作了详细的分析、介绍与讨论。最后探讨了问题1）与2）的解决方案之间的矛盾与互斥性问题。     

基于消息的离散事件仿真方法

本文提出了一种基于沙息的离散事件仿真方法,它将面向对象的程序设计方法,分布式仿真和并行算法的概念结合在一起,与传统的离散事件仿真方法相比,是一种更加灵活而直观的模型仿真方法。     

Impact of Canolol‐Enriched Extract from Heat‐Treated Canola Meal to Enhance Oil Quality Parameters in Deep‐Frying: a Comparison with Rosemary Extract and TBHQ‐Fortified Oil Systems

Canolol‐enriched extracts obtained from the extraction of fluidized bed treated canola meal with supercritical carbon dioxide were added to high‐oleic canola oil in different concentrations (200, 500 and 750 mg/kg). After 30 h of deep‐fat frying, oils fortified with canolol‐enriched extracts showed a two to three times better frying performance in comparison to the commonly used antioxidants (TBHQ, 200 mg/kg; rosemary extract, 40 and 200 mg/kg) and a control without antioxidants with regards to the formation of di‐ and polymer triacylglycerols, total polar compounds, secondary degradation products (anisidine value) and the iodine value. The canolol‐enriched extracts were also able to slow down the degradation of α‐ and γ‐tocopherol during frying resulting in significant amounts of tocopherols after 30 h of frying in comparison to the other oils. The influence of the canolol‐enriched extracts indicated strongly concentration‐dependent performance. With increasing concentration of the extract, the thermal stability of the fortified oil was improved. The only disadvantage of the addition of the extracts was an increase in the initial acid value, but within the frying time, only oil fortified with 750 mg canolol‐enriched extract/kg reached the limit given in different countries.     

昌化鸡血石的宝石学研究

利用X射线粉末衍射仪、拉曼光谱仪、扫描电子显微镜、电子探针及岩石薄片对昌化鸡血石样品中"地"与"血"的矿物组成、形貌特征、化学成分等进行了研究.结果表明,昌化鸡血石"硬地""软地"与"冻地"的矿物组合不同;其中,"地"以地开石为主且呈鳞片状,随着石英的增加,特别是明矾石的加入,"地"的硬度变大."冻地"鸡血石中地开石的结晶粒度比"硬地"鸡血石中的大,但其空间定向性排列没有后者的好.昌化鸡血石中"血"由细小的半自形-他形辰砂微晶集合体组成,其"血"色与辰砂晶体的聚集状态及其杂质成分有关,而杂质成分又与Se元素的质量分数密切相关.     

Identifying model pollutants to investigate biodegradation of hazardous XOCs in WWTPs

Xenobiotic organic compounds (XOCs) in wastewater treatment plant (WWTP) effluents might cause toxic effects in ecosystems. Several investigations have emphasized biodegradation as an important removal mechanism to reduce pollution with XOCs from WWTP effluents. The aim of the study was to design a screening tool to identify and select hazardous model pollutants for the further investigation of biodegradation in WWTPs. The screening tool consists of three criteria: The XOC is present in WWTP effluents, the XOC constitutes an intolerable risk in drinking water or the environment, and the XOC is expected to be biodegradable in WWTPs. The screening tool was tested on bisphenol A (BPA), carbamazepine (CBZ), di(2ethylhexyl)-phthalate (DEHP), 17beta-estradiol (E2), estrone (E1), 17alpha-ethinyloetradiol (EE2), ibuprofen, naproxen, nonylphenol (NP), and octylphenol (OP). BPA, DEHP, E2, E1, EE2, and NP passed all criteria in the screening tool and were selected as model pollutants. OP did not pass the filter and was rejected as model pollutant. CBZ, ibuprofen, and naproxen were not finally evaluated due to insufficient data.     

工业苯胺废水的处理

研究了用萃取剂N ,N 二 (1 甲基庚基 )乙酰胺 (N50 3)处理工业苯胺废水的条件及苯胺的回收。试验表明 :高浓度苯胺废水经萃取剂N50 3 三级萃取后 ,苯胺脱除率达 99 76% ,排出的废水经少量氧化剂处理后 ,可以达到国家一级排放标准