Influence of Se and Te substitutions at Tl-site of Tl(Ba,Sr)CaCu2O7 superconductor on the AC susceptibility and electrical properties

The Sr and Ba bearing Tl-1212 phase, Tl(Ba,Sr)CaCu₂O₇ is an interesting superconductor. The Sr only bearing TlSr₂CaCu₂O₇ is not easily prepared in the superconducting form. The Ba only bearing TlBa₂CaCu₂O₇ on the other hand does not show improvement in the transition temperature with elemental substitution. In this work the influence of multivalent Se (non-metal) and Te (metalloid) substitutions at the Tl-site of Tl_1-xM_x(Ba,Sr)CaCu₂O₇ (M = Se or Te) superconductors for x = 0–0.6 was studied. The samples were prepared via the conventional solid-state reaction method. XRD patterns showed a single Tl-1212 phase for x = 0 and 0.1 Se substituted samples. The critical current density at the peak temperature, T_p of the imaginary (χ”) part of the AC susceptibility (χ = χ’ +χ”), J_c-inter(T_p) for all samples was between 15 and 21 A cm⁻². The highest superconducting transition temperature was shown by the x = 0.3 Se-substituted sample (T_c-onset = 104 K, T_c-zero = 89 K, T_cχ’ = 104 K and T_p = 80 K). Te suppressed the superconductivity of Tl-1212 phase. The order of highest transition temperatures are as follows: Tl_1-xTe_x(Ba,Sr)CaCu₂O₇<Tl(Ba,Sr)CaCu₂O₇<Tl_1-xSe_x(Ba,Sr)CaCu₂O₇. This work showed that Se was better than Te in improving the transition temperature and flux pinning of the Tl-1212 phase. The roles of ionic radius of Se and Te on the superconductivity of Tl(Ba,Sr)CaCu₂O₇ are discussed in this paper.     

储层泥浆侵入深度预测方法研究

泥浆侵入半径的确定尚缺乏严格的验证标准.以油水两相渗流理论和离子扩散方程为基础,结合储集层特点,研究了不同储层参数下泥浆滤液对地层的侵入特性.数值模拟侵入时间选取10 d和20 d.数值模拟结果表明,侵入半径在渗透率不变的情况下随孔隙度的增大而减小,在孔隙度不变的情况下随渗透率的增大而增大;当渗透率和孔隙度都发生变化时,泥浆侵入半径一般随孔隙度的增加呈幂函数增加.依据这种关系对测井资料约束处理,得到的泥浆侵入半径较客观地反映了地层的真实情况.     

对象族可镇定半径的计算

本文采用优化方法把计算对象族的可镇定半径问题转化成优化问题。2范数定义下的可镇定半径采用了Lagrange乘子法求解；无穷范数意义下的可镇定半径采用了最小范数解方法求解。本文方法对可镇定半径的定义形式和不确定参数结构没有要求，因此更具有一般性。     

普通稠油油藏启动压力梯度求解方法与应用

利用微观尺度管流模型,结合普通稠油流变特征,提出了在考虑稠油流变性条件下微观启动压力梯度计算方法.对渤海渤中18块不同渗透率岩心进行室内驱替实验,通过对实验数据的回归分析,得到不同粘度普通稠油油藏启动压力梯度与地层平均渗透率关系,并绘制了启动压力梯度的图版.将研究结果应用于普通稠油油藏,给出了利用启动压力梯度确定极限泄油半径及合理井距的理论计算方法.     

吐丝圈径对大规格高碳盘条组织性能的影响

计算与分析了斯太尔摩冷线上盘条的吐丝圈径、搭接密度及"佳灵"装置横向布风曲线之间的关系,研究了吐丝圈径的大小对大规格82B盘条组织和性能的影响,确定了大规格82B盘条最小吐丝圈径应为980mm.     

Boiling: Size Distribution of Bubbles as Demanded by the Principle of Maximum Information

The principle of maximum informational entropy is used to find the probability density function for the departure radius of a bubble in boiling on a solid surface. A general relation is derived, which leads to particular expressions.     

Drainage and imbibition relative permeabilities at near miscible conditions

The changes in gas and oil relative permeabilities as miscibility is approached are of particular importance in multi-contact miscible displacements. These changes are a function of the detailed phase behaviour of the fluids and their physical properties as well as the properties of the porous medium itself.In this work, we investigate the behaviour of two-phase drainage and imbibition relative permeability curves of four, different, equilibrated fluid pairs from a three component, two-phase system (cyclohexene, isopropyl alcohol and water) that exhibits a critical point at ambient conditions. The tie-lines of these fluid pairs are at varying distances from the system's critical point. Equilibrium phase compositions and interfacial tensions (IFT) were determined for each of the four fluid pairs. Dynamic displacements were then performed in a linear two dimensional, bead-pack. Unsteady state, drainage and imbibition relative permeabilities were determined for the various pre-equilibrated mixtures. The experimental results show a clear change in relative permeability as the fluid pairs approach the critical point. As the interfacial tension decreases the non-wetting phase relative permeability increases more rapidly than the wetting phase relative permeability and hysteresis becomes less important.Two correlations [Coats, K.H., 1980. An equation of state compositional model: SPE J, 20 (5): 363-376.; Whitson, C.H., and Fevang, Ø., 1997. Generalized pseudo pressure well treatment in reservoir simulation. In Proc., IBC Conference on Optimization of Gas Condensate Fields.], commonly used to model the changes in relative permeability with interfacial tension, and the development of miscibility, were compared with the experimental data. The Coats correlation, which uses a single adjustable parameter to model the changes in both relative permeabilities and residual oil saturation as a direct function of the IFT, yielded an unacceptable match to the experimentally determined fractional flow. However the Whitson–Fevang correlation, which relates the changes in relative permeability to the capillary number using two adjustable weighting functions, presents a satisfactory match.     

An analysis of the electrical conductivity in BaSO4-added Ag2SO4 solid electrolyte system

The compositions (1 −x)Ag₂SO₄−(x)BaSO₄, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba²⁺ in Ag₂SO₄ was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained using a detailed impedance analysis. The partial substitution of Ba²⁺ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model based on lattice distortion (expansion) due to partial substitution of Ag⁺ by the bigger Ba²⁺ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO₄-dispersed Ag₂SO₄ conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO₄ dispersed Ag₂SO₄ is due to percolation threshold.     

小井眼侧钻短半径水平井钻井技术

侧钻短半径水平井与常规中、长半径水平井相比较除具有提高油气采收率共性外,还具有成本低、周期短、见效快等特点。从侧钻短半径水平井施工特点、剖面设计、开窗工具及开窗方式的选择、轨迹控制、测量方式及测量工具的选择以及钻井液设计等方面对小井眼侧钻水平井技术进行了介绍,并结合实钻经验给出了各阶段相应的钻具结构和技术措施及注意事项等,采用小井眼侧钻短半径水平井钻井技术,对塔河油田奥陶系油藏进行了勘探开发并取得圆满成功,取得了较好的效果。对今后同类型井的钻井设计、施工有一定的指导和借鉴意义。     

脱硫灰渣的排放方式及利用

火电厂产生的脱硫灰渣的组成和性能与其排放方式有着密切关系。为使其得到较好的处置与利用 ,本文从排放方式方面进行探讨 ,并略述各种脱硫灰渣的性能与利用前景