全文获取类型
收费全文 | 8633篇 |
免费 | 365篇 |
国内免费 | 373篇 |
专业分类
电工技术 | 826篇 |
综合类 | 263篇 |
化学工业 | 2773篇 |
金属工艺 | 775篇 |
机械仪表 | 370篇 |
建筑科学 | 97篇 |
矿业工程 | 89篇 |
能源动力 | 1468篇 |
轻工业 | 90篇 |
水利工程 | 17篇 |
石油天然气 | 63篇 |
武器工业 | 25篇 |
无线电 | 807篇 |
一般工业技术 | 1158篇 |
冶金工业 | 104篇 |
原子能技术 | 45篇 |
自动化技术 | 401篇 |
出版年
2024年 | 14篇 |
2023年 | 143篇 |
2022年 | 198篇 |
2021年 | 260篇 |
2020年 | 244篇 |
2019年 | 229篇 |
2018年 | 216篇 |
2017年 | 240篇 |
2016年 | 187篇 |
2015年 | 204篇 |
2014年 | 417篇 |
2013年 | 441篇 |
2012年 | 456篇 |
2011年 | 946篇 |
2010年 | 700篇 |
2009年 | 757篇 |
2008年 | 675篇 |
2007年 | 657篇 |
2006年 | 514篇 |
2005年 | 347篇 |
2004年 | 308篇 |
2003年 | 244篇 |
2002年 | 251篇 |
2001年 | 113篇 |
2000年 | 110篇 |
1999年 | 100篇 |
1998年 | 78篇 |
1997年 | 62篇 |
1996年 | 60篇 |
1995年 | 39篇 |
1994年 | 41篇 |
1993年 | 21篇 |
1992年 | 18篇 |
1991年 | 12篇 |
1990年 | 16篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有9371条查询结果,搜索用时 15 毫秒
1.
Pengfei Liang Jie Zhu Di Wu Hui Peng Xiaolian Chao Zupei Yang 《Journal of the American Ceramic Society》2021,104(6):2702-2710
Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO2-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag+/Nb5+ co-doped (Ag1/4Nb3/4)xTi1−xO2 (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 103 and 1.6 × 104 at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics. 相似文献
2.
Fangjun Zhu You Shi Guorong Hu Zhongdong Peng Yanbing Cao Qian Sun Zhichen Xue Yinjia Zhang Ke Du 《Ceramics International》2021,47(3):3070-3078
Titanium and boron are simultaneously introduced into LiNi0.8Co0.1Mn0.1O2 to improve the structural stability and electrochemical performance of the material. X-ray diffraction studies reveal that Ti4+ ion replaces Li+ ion and reduces the cation mixing; B3+ ion enters the tetrahedron of the transition metal layers and enlarges the distance of the [LiO6] layers. The co-doped sample has spherical secondary particles with elongated and enlarged primary particles, in which Ti and B elements distribute uniformly. Electrochemical studies reveal the co-doped sample has improved rate performance (183.1 mAh·g-1 at 1 C and 155.5 mAh·g-1 at 10 C) and cycle stability (capacity retention of 94.7% after 100 cycles at 1 C). EIS and CV disclose that Ti and B co-doping reduces charge transfer impedance and suppresses phase change of LiNi0.8Co0.1Mn0.1O2. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(12):7915-7931
This paper carefully evaluates the electrocatalytic activity of Sr2FeMo0.5Mn0.5O6 (SFMM) double perovskite as a candidate to substitute the state-of-the-art Ni/YSZ fuel electrode. The electrochemical performance of a 40% SFMM/CGO composite electrode was studied in CO/CO2 and H2 with different oxygen partial pressure. Two different cell configurations are prepared at a relatively low temperature of 800 °C to increase the electrochemically active surface area. The cell was supported with a 150 μm 10Sc1CeSZ electrolyte in the first configuration. The cell in the second configuration was made by applying a 400 nm thin 8YSZ layer on 150 μm CGO electrolyte to improve the electrolyte ionic conductivity. Improving catalytic activity with increasing oxygen partial pressure is a key characteristic of the developed electrode. The polarization resistance of about 0.34 and 0.56 Ω cm2 at 750 °C in 3%H2O + H2 and 60% CO/CO2 makes this electrode a promising candidate for SOCs application. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(26):12829-12840
In the present work, nitrogen doped hierarchically activated porous carbon (APC) samples have been synthesized via single step scalable method using ethylene di-amine tetra acetic acid (EDTA) as precursor and KOH as activating agent. Activated porous carbons with different pore sizes have been developed by varying the activation temperature. SEM, TEM and SAXS analysis suggest that with variation of activation temperature, a hierarchical porous structure with interconnected meso-pore and micro pores has been achieved. The sufficiently high surface area of the synthesized materials provides active sites to enhance the diffusion of ions between the electrolyte and the carbon electrodes. The electrode prepared at 800 °C activated sample exhibited highest specific capacitance of 274 Fg-1 in two electrode setup, at a current density of 0.1 Ag-1 in 1 M aqueous H2SO4. Along with this, it showed maximum energy density of 9.5 Whkg?1 at a power density of 64.5 Wkg-1. The remarkable electrochemical performance reveals that the synthesized nitrogen doped activated carbon electrodes derived from EDTA can be tuned to have optimum pore structure and pore size distribution for better electrochemical performance, so it can be considered as a potential electrode material for applications in electrochemical energy storage. 相似文献
5.
In this work, ZnO nanostructures are electrodeposited on a transparent conducting glass from chloride baths. The influence of H2O2 concentration on the electrochemical characteristics has been studied using cyclic voltammetry (CV) and chronoamperometry (CA) techniques. From the analysis of the current transients on the basis of the Scharifker–Hills model, it is found that nucleation mechanism is progressive with a typical three-dimensional (3D) nucleation and growth process; independently with the concentration of H2O2. However, the nucleation rate of the ZnO changes with the increase of H2O2 concentration. The Mott–Schottky measurements demonstrate an n-type semiconductor character for all samples with a carrier density varying between 5.14×1018 cm−3 and 1.47×1018 cm−3. Scanning electron microscopy (SEM) observations show arrays of vertically aligned ZnO nanorods (NRs) with good homogeneity. The X-ray diffraction (XRD) patterns show that the ZnO deposited crystallises according to a hexagonal Würtzite-type structure and with the c-axis perpendicular to the electrode surface. The directional growth along (002) crystallographic plane is very important for deposits obtained at 5 and 7 mM of H2O2. The high optical properties of the ZnO NRs with a low density of deep defects was checked by UV–vis transmittance analyses, the band gap energy of films varies between 3.23 and 3.31 eV with transparency around 80–90%. 相似文献
6.
Numerical simulation, using SILVACO-TCAD, is carried out to explain experimentally observed effects of different types of deep levels on the capacitance–voltage characteristics of p-type Si-doped GaAs Schottky diodes grown on high index GaAs substrates. Two diodes were grown on (311)A and (211)A oriented GaAs substrates using Molecular Beam Epitaxy (MBE). Although, deep levels were observed in both structures, the measured capacitance–voltage characteristics show a negative differential capacitance (NDC) for the (311)A diodes, while the (211)A devices display a usual behaviour. The NDC is related to the nature and spatial distribution of the deep levels, which are characterized by the Deep Level Transient Spectroscopy (DLTS) technique. In the (311)A structure only majority deep levels (hole traps) were observed while both majority and minority deep levels were present in the (211)A diodes. The simulation, which calculates the capacitance–voltage characteristics in the absence and presence of different types of deep levels, agrees well with the experimentally observed behaviour. 相似文献
7.
《Ceramics International》2021,47(20):28338-28347
Transition metal oxides have been explored in supercapacitor applications owing to their safety, low cost, high specific capacitance and high electrochemical activity. Among all transition metal oxides, zinc oxide based materials show remarkable response for designing the supercapacitors with high electrochemical activity. Here in, Mn doped ZnO (Zn1-xMnxO3 with x = 0, 0.25, 0.50, 0.75 and 1) was synthesized by a facile hydrothermal method. Doping of Mn into the ZnO increased the surface area and decease the charge transfer resistance for the Zn0.5Mn0.5O3. All the synthesized materials were characterized by x-ray diffraction (XRD), scanning electron microscopy SEM), BET, electrochemical tests and other various analytical techniques to confirm the structural, morphological, textural and suprcapacitive properties. The synthesized material Zn0.5Mn0.5O3 having the porous nanoribons structure with BET surface area (2490 cm2/g). The electrochemical studies showed significantly enhanced response toward pseudocapacitive nature. The synthesized material exhibited the excellent specific capacitance (515F/g), specific energy (28.61 Wh/kg) and specific power (1000 W/kg) at current density of 2 mA/g. Such impressive and superior properties make the MnZnO3 material as promising candidate for new generation supercapacitor applications. 相似文献
8.
Chuangang Yao Jixing Yang Haixia Zhang Sigeng Chen Jian Meng Kedi Cai 《Ceramics International》2021,47(17):24589-24596
Bismuth doped La2-xBixNiO4+δ (x = 0, 0.02 and 0.04) oxides are investigated as SOFC cathodes. The effects of Bi doping on the phase structure, thermal expansion, electrical conduction behavior as well as electrochemical performance are studied. All the samples exist as a tetragonal Ruddlesden-Popper structure. Bi-doped LBNO-0.02 and LBNO-0.04 have good chemical and thermal compatibility with LSGM electrolyte. The average TEC over 20–900°С was 13.4 × 10?6 and 14.2 × 10?6 K?1 for LBNO-0.02 and LBNO-0.04, respectively. The electrical conductivity was decreasing with the rise of Bi doping content. EIS measurement indicates Bi doping can decrease the ASR values. At 750 °C, the obtained ASR for LBNO-0.04 is 0.18 Ωcm2, which is 56% lower than that of the sample without Bi doping, suggesting Bi doping is beneficial to the electrochemical catalytic activity of LBNO cathodes. 相似文献
9.
《Ceramics International》2021,47(19):27177-27187
BaZrO3-based materials doped with a trivalent cation have excellent chemical stability and relatively high proton conductivity which makes them potential proton conducting oxide materials for various electrochemical device applications such as hydrogen processing, high-temperature electrolysis, and solid electrolyte in fuel cells. However, BaZrO3 showed poor sinterability, requiring high sintering temperatures (1700–2100 °C) with longtime sintering (20–100 h) to achieve the desired microstructure and grain growth. This sintering problem can be solved by slightly doping BaZrO3 with a sintering aid element. Therefore, in this study, two different zirconate proton conductors: BaZr0·9Y0·1O3-α (BZY) and BaZr0·955Y0·03Co0·015O3-α (BZYC) were sintered in an air atmosphere and an oxygen atmosphere for 20 h in the temperature range of 1500–1640 °C. The sinterability was evaluated by analyzing the XRD diffraction patterns, lattice constant, lattice strain, crystallite size, relative density, open porosity, closed porosity, surface morphology, grain size, and grain boundary distribution, using the XRD, SEM, EDX, and Archimedes density measurement methods. It is concluded that in an oxygen atmosphere, sintering aid Co not only improves the relative density but also produces highly dense fine particles with clear grain boundaries which are promising for electrochemical hydrogen device applications. 相似文献
10.
《International Journal of Hydrogen Energy》2021,46(56):28397-28405
Water electrolysis powered by renewable electricity will likely be critical to a future hydrogen economy. However, the typical use of strongly acidic or alkaline electrolytes necessitates the use of expensive materials, while bubbles add to capital and operational costs, due to blocking of the electrode surface and the necessary use of pumps and gas-liquid separators. Here ‘bubble-free’ oxygen evolution at mild pH is carried out using an electrocatalyst that mimics photosystem II (PSII). The bubble-free electrode includes a gas-extracting Gore-Tex® membrane. Edge-functionalised graphene (EFG) is included to mimic the metal-binding local protein environment, and the tyrosine residue, in the oxygen evolving complex (OEC) of PSII, while MnOx and Ca2+ are incorporated to mimic the Mn4CaO5 cluster. Interaction between EFG, MnOx, and Ca2+ results in a significant, 130 mV fall in the overpotential required to drive electrocatalytic oxygen evolution at 10 mA cm−2, compared to the electrode without these biomimetic components. 相似文献