Evaluating Ozone as a Remedial Treatment for Removing RDX from Unsaturated Soils

Years of wastewater discharge at the Department of Energy’s Pantex Plant have contaminated the vadose zone and underlying perched aquifer with hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Because the vadose zone is acting as a continual source of groundwater contamination, removing RDX from the unsaturated zone is paramount to prevent further contamination. We determined the efficacy of ozone to degrade and mineralize RDX. Solution experiments showed that ozone (27?mg?L?1; 150?mL?min?1) was effective in mineralizing 80% of the RDX (30?mg?RDX?L?1) provided that some Pantex soil was present to buffer the solution pH. Soil columns treated with ozone produced 50% RDX mineralization within 1 day and >80% within 7 day. Experiments designed to evaluate aerobic biodegradation following partial ozonation of a RDX solution showed that ozone-generated RDX products were much more biodegradable than untreated controls in aerobic microcosms (35 versus <0.3% cumulative mineralization). These results support the use of ozone as a remedial treatment for the contaminated vadose zone at the Pantex facility.     

Risk Management and Design of Critical Bridges for Terrorist Attacks

In the aftermath of the September 11th tragedies, the vulnerability of the United States' transportation infrastructure to terrorist attack has gained national attention. In light of this vulnerability, various governmental agencies are looking into ways to improve the design of structures to better withstand extreme loadings. Until recently, little attention has been given to bridges which are critical to our economy and transportation network. This paper summarizes the results of ongoing research to investigate economical, unobtrusive, and effective methods to mitigate the risk of terrorist attacks against critical bridges. It outlines a recommended plan to reduce these threats through proven risk management techniques, lists possible cost-effective security measures, discusses blast effects on bridges, and provides structural design and retrofit guidelines. It also discusses ongoing research oriented towards the development of a performance-based design methodology. In using proper risk management techniques, transportation managers and bridge engineers can mitigate the risk of terrorist attacks against critical bridges to an acceptable level, while ensuring efficient use of limited resources.     

Adsorption of RDX and HMX in Rapid Small-Scale Column Tests: Implications for Full-Scale Adsorbers

The high explosive (HE) compounds royal demolition explosive or hexahydro-1,3,5-trinitro-1,3,5-triazocine (RDX) and high melting explosive or octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) have been detected as groundwater contaminants at many military facilities. This research evaluated adsorption of RDX and HMX with granular activated carbon (GAC) to provide guidance for the design and operation of GAC adsorbers for treatment of HE-contaminated groundwater. Five GACs were screened using rapid small-scale column tests (RSSCTs), after which additional tests were performed with the two GACs that most effectively treated mixtures of RDX and HMX (Calgon F400 and Northwestern LB-830). GAC service life as a function of empty-bed contact time (EBCT) was determined using RSSCTs for a range of simulated full scale EBCTs with influent concentrations of 2,200 μg RDX/L and 350 μg HMX/L. Increasing the influent concentration of either contaminant significantly reduced the predicted service life, as did preloading GAC with groundwater natural organic matter. In batch isotherm tests, RDX was less adsorbable than HMX under all conditions studied. Concurrent loading of natural organic matter reduced the Freundlich K for RDX, whereas adsorption of HMX was not affected. Of the GACs tested, Calgon F400 most effectively removed RDX and HMX.     

Explosive Testing of Polymer Retrofit Masonry Walls

The most widely used terrorist tactic is the improvised explosive device, which can range in size from hand-held to truck-size. Most casualties and injuries sustained in such an attack are not caused by the blast itself, but rather by the disintegration and fragmentation of walls, the shattering of windows, and by nonsecured objects propelled at high velocities by the blast. Since 1995, the Air Force Research Laboratory at Tyndall Air Force Base has investigated methods of retrofitting wall structures to better resist blast loads from external explosions. This paper summarizes results from recent tests that involve an innovative use of a sprayed-on polymer to increase blast resistance of unreinforced concrete masonry walls. Test methodology, retrofit materials considered, material properties, mechanisms of effectiveness, and research challenges are discussed.     

Poly(3-hexylthiophene) and hexafluoro-2-propanol-substituted polysiloxane based OFETs as a sensor for explosive vapor detection

The organic field effect transistors (OFETs) with regioregular poly 3-hexylthiophene (rr-P3HT) and hexafluoro-2-propanol-substituted polysiloxane (SXFA) as an organic layer, have been used for detection of explosive vapors with excellent sensitivity of less than 70 ppt for 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and less than 100 ppt for 2,4,6-trinitrotoluene (TNT). The sensor response (% change in saturation current) was found to be 125 ± 10% for TNT and 90 ± 10% for RDX. It was also observed that the incorporation of Cu^II tetraphenylporphyrin (CuTPP) into rr-P3HT/SXFA matrix resulted in an improved selectivity for the vapors of nitro based analytes (TNT, RDX and DNB) as compared to the vapors of non explosive oxidizing agents such as nitrobenzene (NB), benzoquinone (BQ) and benzophenone (BP). This is attributed to the increased binding of the vapors containing nitro compound to the thin films due to the presence of CuTTP. Spin coated thin films were further characterized by Atomic Force Microscopy (AFM) and Electrostatic Force Microscopy (EFM).     

Mechanical Behavior of Nanostructured and Microstructured Explosives

Nanostructured hexolites (40/60), (60/40), (80/20) and microstructured hexolite (60/40) powders are pressed by uniaxial compression to obtain explosive charges. This kind of composition is often used for the synthesis of detonation nanodiamonds. The morphology, density and cohesion of the resulting pellets are analyzed in the light of the different used compression parameters. This study allows optimizing the compression parameters to obtain well suited explosive charges from nanostructured explosive components. A good cohesion of the nanostructured explosive pellets could be obtained with increasing the temperature used for the compression. Another very important point is that the nanostructuring of the composites is maintained for every compression.     

Bishydrazinium and Diammonium Salts of 4,4′,5,5′‐Tetranitro‐2,2′‐biimidazolate (TNBI): Synthesis and Properties

The diammonium ( 1 ) and bishydrazinium ( 2 ) salts of 4,4′,5,5′‐tetranitro‐2,2′‐biimidazolate (TNBI) were synthesized and their physical properties as well as predicted explosive performance characteristics are described. These dianionic salts are easily formed in good yields by reaction of TNBI with aqueous solutions of the cationic species. TNBI is synthesized from 2,2′‐biimidazole, which is ultimately synthesized by the condensation of aqueous glyoxal with ammonium acetate. The compounds were characterized by NMR spectroscopy, vibrational (FT‐IR and Raman) spectroscopy, elemental analysis, thermal analysis (DSC, VTS and calorimetry), and small scale safety testing (impact, friction, ESD). The measured densities and heats of formation are reported. The materials show promise for use in IM explosive and propellant formulations due to the combination of their calculated performances, thermal stability and insensitivity to stimuli.     

神经网络理论在火炸药企业控制系统中系统安全评价的分析

阐述了人工神经网络基本原理,研究分析了BP神经网络模型的缺陷并提出了优化策略。在此基础上,将神经网络理论应用于火炸药企业的控制系统安全评价之中,提出了基于此理论的系统安全评价、实现方法和优点。     

水下爆炸对水下目标的毁伤试验研究

为研究水下爆炸对蛙人的毁伤效果,进行了GUHL-1的水下爆炸试验,得到不同爆距处冲击波峰值压力。通过计算获得GUHL-1炸药水中爆炸自由场冲击波压力峰值和爆距的关系。同时对几种反蛙人武器系统的毁伤效果进行了分析,为今后反蛙人武器系统的设计提供参考。     

燃烧、爆炸危险品分级程序的建立及验证

分析了联合国关于危险货物运输制定的分级程序及美国国防部关于弹药和炸药危险品的分级程序,结合火炸药特别是当前高能固体推进剂的特点,以及火炸药及制品在制造、运输、储存和使用中所存在的状态,建立了科学的、系统的、适合我国国情并与国际接轨的燃烧、爆炸危险品危险性分级程序和试验方法;针对典型R-2H、FG20推进剂和不敏感AFX-757炸药,利用本文建立的“燃烧、爆炸危险品危险性分级程序和试验方法”进行了危险性分级,结果与国外文献报道的危险性级别相一致。