全文获取类型
收费全文 | 3412篇 |
免费 | 530篇 |
国内免费 | 12篇 |
专业分类
电工技术 | 5篇 |
综合类 | 62篇 |
化学工业 | 2971篇 |
金属工艺 | 8篇 |
机械仪表 | 16篇 |
建筑科学 | 6篇 |
矿业工程 | 4篇 |
能源动力 | 17篇 |
轻工业 | 74篇 |
石油天然气 | 47篇 |
无线电 | 194篇 |
一般工业技术 | 511篇 |
冶金工业 | 3篇 |
原子能技术 | 29篇 |
自动化技术 | 7篇 |
出版年
2024年 | 14篇 |
2023年 | 27篇 |
2022年 | 16篇 |
2021年 | 128篇 |
2020年 | 92篇 |
2019年 | 88篇 |
2018年 | 107篇 |
2017年 | 121篇 |
2016年 | 151篇 |
2015年 | 147篇 |
2014年 | 197篇 |
2013年 | 277篇 |
2012年 | 196篇 |
2011年 | 177篇 |
2010年 | 153篇 |
2009年 | 208篇 |
2008年 | 195篇 |
2007年 | 188篇 |
2006年 | 213篇 |
2005年 | 177篇 |
2004年 | 191篇 |
2003年 | 149篇 |
2002年 | 128篇 |
2001年 | 77篇 |
2000年 | 76篇 |
1999年 | 81篇 |
1998年 | 52篇 |
1997年 | 56篇 |
1996年 | 44篇 |
1995年 | 34篇 |
1994年 | 31篇 |
1993年 | 20篇 |
1992年 | 17篇 |
1991年 | 15篇 |
1990年 | 12篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 19篇 |
1984年 | 15篇 |
1983年 | 13篇 |
1982年 | 19篇 |
排序方式: 共有3954条查询结果,搜索用时 0 毫秒
1.
2.
Role of chain symmetry and hydrogen bonding in segmented copolymers with monodisperse hard segments 总被引:3,自引:0,他引:3
Thermoplastic segmented polyurethane and polyurea copolymers whose monodisperse hard segments are based on only a single diisocyanate molecule are discussed. The solid-state structure-property behavior of these materials demonstrates that a proper selection of the level of symmetry and/or cohesiveness of the hard microdomains may allow elimination of the traditional requirement of chain extension to obtain melt processable segmented urethanes, and more specifically, urea copolymers with useful structural properties. 相似文献
3.
Marta Fernndez-García Pedro Francisco Caamero Jos Luis de la Fuente 《Reactive and Functional Polymers》2008,68(9):1384-1391
Epoxy-functional spontaneous gradient copolymers of glycidyl methacrylate (G) and n-butyl acrylate (B) were synthesized via atom transfer radical polymerization (ATRP). The copolymerization reactions were carried out in toluene solution at 70 °C, using methyl 2-bromopropionate (MBrP) as initiator and copper chloride with N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The kinetic behaviour of the statistical copolymerizations was studied in a wide composition interval with molar fractions of G ranging from 0.10 to 0.75. The synthesized copolymers were characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. 1H NMR was employed to determine the copolymer composition, demonstrating the gradient character of the copolymers along the main chain in the whole monomer conversion interval. Apart from this, the sequence distribution and stereoregularity were analyzed. These microstructural experimental data agreed well with those calculated from Mayo-Lewis terminal model (MLTM) and a Bernoullian statistic with an isotacticity parameter of σG = 0.28 and a coisotacticity parameter of σ = 0.30. 相似文献
4.
O Prez‐Camacho S Sepúlveda‐Guzmn M Prez‐lvarez M García‐Zamora G Cadenas‐Pliego 《Polymer International》2005,54(12):1626-1631
New functionalized styrene–maleimide copolymers were prepared by free radical copolymerization of styrene (St) and N‐4‐carboxybutylmaleimide (NBMI) in chloroform, using 2,2′‐azobisisobutyronitrile (AIBN) as initiator. Monomer and copolymer characterization was carried out by 1H‐ and 13C‐NMR. Copolymer composition was determined by elemental analysis and Fourier‐transform infrared (FTIR) spectroscopy. The glass transition temperature (from DSC) and the thermogravimetric analysis (TGA) of the copolymers were consistent with the thermal behavior and stability observed for alternating St–maleimide copolymers. St–NBMI copolymers crosslinked with divinylbenzene (DVB) were also synthesized and their cation exchange properties evaluated in order to assess the capacity of the new copolymers to bind metallic ions. Copyright © 2005 Society of Chemical Industry 相似文献
5.
Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers. 相似文献
6.
The viscometric, turbidimetric and potentiometric properties of copolymers of acrylamide (AM) with 2-acrylamido-2-methylpropanedimethylammonium chloride (AMPDAC) were studied in aqueous solutions. The AMPDAC polymers exhibit poor salt tolerance and large, negative viscosity/temperature coefficients. Furthermore, the polymers were found to be sensitive to changes in pH. The AMPDAC polymers undergo phase separation in the presence of dianions as a function of temperature and AMPDAC composition. 相似文献
7.
介绍了苯乙烯类嵌段共聚物(SBC)的国内外生产和消费情况,分析了我国SBC的市场前景,提出了加大研发力度、提高SBC生产术、扩大生产规模、提高国内市场占有率,建设多功能装置等建议。 相似文献
8.
The bulk modification of SBS rubber with maleic anhydride in a mixing chamber of a Haake rheomixer was studied. The effect of temperature, maleic anhydride, and benzoyl peroxide concentrations on the grafting efficiency was evaluated. High grafting efficiency was achieved when the ratio of peroxide and maleic anhydride concentration was high. On the other hand, on this condition high insoluble fraction was generated. The addition of a diamine, 4,4′‐diaminediphenylmethane to the reaction mixture minimizes the amount of insoluble polymer. However, the grafted MAH content also decreases. The graft copolymer was characterized by infrared spectroscopy and the grafting extension was determined by titration. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2953–2960, 2002; DOI 10.1002/app.10355 相似文献
9.
Nuclear magnetic resonance (n.m.r.) studies of 19F nuclei in a random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T2 components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T1 appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T1 were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals. 相似文献
10.
Mohamed A. Mekewi 《Materials Research Innovations》2002,6(4):214-217
Polyisobutylene succinic anhydride-urea/polyamines (PIBSA) copolymers were synthesized as potential antioxidants and detergent
dispersant agents for lubricating oils samples (SAE-30). Homogeneity, thermal stability and dispersancy of the solutions were
determined. Fully soluble oil compounds that are thermally stable up to 250 °C were achieved.
The oxidation stability of lube oil samples in the presence of four designed PIBSA additives (varying in the number of amine
groups) was determined for a time period of up to 72 hours. The dependence of the additive efficiency on its concentration
was studied to achieve maximum stability. Some PIBSA additives at concentration 3.0 · 104 ppm exhibit the best results.
Dispersivity values were measured at predetermined oxidation times. The results proved reliable dispersion capability as the
nitrogen content of the additive is increased, i.e. the increase in the basic character of the additive leads to the increase
in the neutralization capability. Moreover, the designed PIBSA additives retain their efficiency after long oxidation times,
confirming their role as multifunctional nitrogen containing polymeric additive.
Electronic Publication 相似文献