5(4H)-Oxazolones react with ammonium acetate under microwave irradiation and using graphite as support in an eco-friendly process.
The reaction was carried out under solvent-free conditions and the imidazolones were obtained quantitatively. Moreover the
reaction time was reduced too. 相似文献
An experimental investigation was carried out to examine the tribological behavior of NAO (non-asbestos organic) type brake linings containing different volume ratios of graphite and antimony trisulfide (Sb2S3). A scale dynamometer was used for friction tests and particular emphases were given to the effect of applied pressure, sliding speed, and temperature on the coefficient of friction according to the relative amounts of the two solid lubricants. Results showed that the brake linings with both solid lubricants exhibited better friction stability and less speed sensitivity than the friction materials containing a single solid lubricant. In particular, the brake lining containing higher concentrations of graphite showed better fade resistance than others during high-temperature friction test. 相似文献
Thin film formation of graphite by chemical vapor deposition using 2-methyl-1,2′-naphthyl ketone as a starting material was carried out on Ni film substrates. On Ni films directly deposited on quartz glass, the graphite films were obtained when the Ni film thickness was above 1 000 Å and above 5 000 Å at 700 °C and 1 000 °C, respectively. Depositions on thinner Ni film substrates comprise amorphous carbon (a-C) or graphite tubes which was owing to the thermal coagulation of the Ni film into droplets. On the other hand, graphite film was obtained on the Ni film with thickness 10 Å when a-C was inserted between the Ni film and the quartz glass. The coagulation of the Ni film is considered to be avoided by inserting a-C layer. 相似文献
The objective of this study was to examine the effects of hygrothermal aging on the durability of a graphite/epoxy woven composite material system. The study was part of a larger project in which the objective was to evaluate and model the effects of moisture, temperature, and combined hygrothermal conditions on the strength and life of a graphite/epoxy woven composite material system. The results presented here represent an extension of the work by Patel and Case (Int. J. Fatigue 22 (2000) 809).
The hygrothermal aging consisted of cyclical temperature and moisture variations which were meant to simulate mission conditions for an advanced subsonic aircraft. Durability studies were carried out on the aged material system in the form of fatigue and residual strength testing under humid and elevated temperature environments. Damage mechanisms and failure modes were determined through fatigue testing, residual strength testing, and nondestructive evaluation.
Changes in physical appearance, thermal analysis results, fracture surfaces, and moisture diffusion behavior all supported the idea that the material was affected by the aging process. However, experimental testing also showed that the initial and residual tensile properties of the aged material were virtually unaffected by the imposed environmental aging (as compared to unaged material testing results), except when tested at elevated temperature. At elevated temperature, both the dynamic stiffness and residual strength were noticeably reduced from that at room temperature. 相似文献
In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)-THF-graphite intercalation compound (GIC). K-THF-GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to the interfacial interaction between the graphite nanolayers and the polymer, the composites exhibit higher glass transition temperature and higher thermal stability when compared to polystyrene. The percolation threshold in the conductivity of the composites is lesser than 8.2 wt% and the dielectric constant can reach as high as 136. 相似文献
This work studied the voltammetric response of graphite reinforcement electrodes made of different pencil lead hardness. The
studies showed that harder graphite leads, regardless of their manufacturer, are more appropriate as electrode material for
voltammetric purposes due to their higher peak currents, increasing sensitivity and reproducibility, with ΔEp closer to the theoretical value for a reversible system. 相似文献
The adsorption of molecular and atomic hydrogen as well as other molecules in the atmosphere on vacancies in the (0 0 0 1) graphite surface are investigated using density functional theory. Atomic hydrogen adsorbs with energies ranging from 4.7 to 2.3 eV. The validity of the model is confirmed by the good agreement between calculated vibrational spectra and those of high-resolution electron energy loss spectroscopy. It is shown that molecular hydrogen dissociates with a barrier of 1.1 eV on this model system. Water and oxygen also dissociate with respective barriers of 1.6 and 0.2 eV. Carbon dioxide and nitrogen have no interaction with the defect whereas carbon monoxide is incorporated into the vacancy with an activation energy of 1.5 eV. A comparison is made with the reactivity of graphene edges, both zigzag and armchair. 相似文献
A simple quasi-2D model for the temperature distribution in a graphite tube furnace is presented. The model is used to estimate
the temperature gradients in the furnace at temperatures above which contact sensors can be used, and to assist in the redesign
of the furnace heater element to improve the temperature gradients. The Thermogage graphite tube furnace is commonly used
in many NMIs as a blackbody source for radiation thermometer calibration and as a spectral irradiance standard. Although the
design is robust, easy to operate and can change temperature rapidly, it is limited by its effective emissivity of typically
99.5–99.8%. At NMIA, the temperature gradient along the tube is assessed using thermocouples up to about 1,500°C, and the
blackbody emissivity is calculated from this. However, at higher operating temperatures (up to 2,900°C), it is impractical
to measure the gradient, and we propose to numerically model the temperature distributions used to calculate emissivity. In
another paper at this conference, the model is used to design an optimized heater tube with improved temperature gradients.
In the model presented here, the 2-D temperature distribution is simplified to separate the axial and radial temperature distributions
within the heater tube and the surrounding insulation. Literature data for the temperature dependence of the electrical and
thermal conductivities of the graphite tube were coupled to models for the thermal conductivity of the felt insulation, particularly
including the effects of allowing for a gas mixture in the insulation. Experimental measurements of the temperature profile
up to 1,500°C and radial heat fluxes up to 2,200°C were compared to the theoretical predictions of the model and good agreement
was obtained. 相似文献
We report the production of carbon nanotubes by high dose of electron irradiation. The irradiation was performed with a 2 MeV Van de Graaff accelerator, while the irradiation conditions were the following: voltage 1.3 MeV, current 5 µA, dose rate 25 kGy/min, and total dosage 1000 kGy. The samples were analyzed in a high-resolution transmission electron microscope. The main features observed on the samples, were huge nanotubes of several nanometer long and few nanometer wide, which are capped at one end. It is good to point out, that at this level of irradiation, we were not able to find either onion-like or particle structures throughout the material, as it is usual in similar hexagonal structures. This behavior could be attributed to the level of irradiation used to create the nanotubes under investigation. 相似文献