Effects of heat treatment processes on microstructure and properties of 2·25Cr–1Mo–0·25V HSLA steels

Abstract

In the present paper, the effects of the heat treatment processes with two conditioning treatments and four quenching–tempering processes on the mechanical properties of 2·25Cr–1Mo–0·25V high strength low alloyed (HSLA) steel are investigated. The results show that the conditioning treatments have obvious effects on the low temperature impact energy but little effect on the tensile strength. The elevation of the final austenitising temperature increases the strength, whereas it results in the decrease in the low temperature impact energy due to the coarse microstructure. The results of the fracture surfaces analysis further make sure that the fracture surfaces of tensile specimens all exhibit ductile characters with a lot of dimples. However, the fracture surfaces of impact specimens exhibit two typical fracture characters, i.e. the ductile and brittle fracture surface corresponding to the fine and coarse microstructures respectively. In addition, the elongation and reduction in area seem to be insensitive to the heat treatments. Meanwhile, the impact fracture mode is more sensitive to the grain size and not to the low temperature impact energy.     

Coupled heat and fluid flow model and experimental verification of aluminium plate die casting

Abstract

The present work aims to forecast mould filling, void shape, location and size as well as columnar to equiaxed transition (CET) in commercial pure aluminium casting. A model coupling the momentum equations of the fluid flow and heat transfer equations is presented, in which metallostatic pressure, air gap and oxide layer are considered. Different casting parameters were investigated such as casting configuration by varying the plate thickness from 5 to 20 mm, melt superheat from 40 to 120°C, mould preheat up to 200°C and different pouring heads ranging from 0·3 to 0·6 m. Regarding the microstructure and void formation, the approach based on the Niyama criterion, was considered. The experimental verification of the model was achieved by gravity die casting in the form of a rectangular cavity. Voids inside aluminium plate were investigated by X-ray imaging. Microstructure and CET was investigated microscopically. The supposed model proves its validity for mould filling and in detecting the void features and CET.     

Development of precipitate size and volume fraction of niobium carbonitrides in stabilised stainless steel

Abstract

Niobium carbonitride (NbX) precipitates have been studied in a niobium stabilised austenitic stainless steel AISI type 347 with approximate nominal composition Fe–0.06C–17.5Cr–11.4Ni–0.8Nb. The steel was extruded to seamless tube, solution annealed at 1100°C for 3 min, water quenched, and subsequently isothermally aged at 700°C for times up to 70 000 h. Size distribution and volume fraction of the coarse distribution (1–10 µm) of NbX particles were measured using scanning electron microscopy (SEM). The fine distribution (～30 nm) was investigated using energy filtered transmission electron microscopy (EFTEM). Size distribution and volume fraction were determined using jump ratio images. Coarse NbX (～0.3% volume fraction) precipitates were formed during solidification and extrusion, and were little affected by solution annealing and isothermal aging. Fine NbX (～0.5% volume fraction) precipitates formed during solution annealing and grew during the first 800 h of aging. Precipitate size determination using EFTEM appears to give accurate results, while volume fraction determination requires homogeneous material for good results.     

Particle break-up during heat treatment of 3000 series aluminium alloys

Abstract

In wrought aluminium alloys, the fragmentation of coarse, iron bearing intermetallic particles by hot rolling is an important development in industrial processing. Here a model 3000 series alloy is used to show that fragmentation can occur prior to hot rolling, during the homogenisation heat treatment. Some fragmented particles display a curved morphology of break-up that results from matrix wetting of two phase (or 'duplex') interfaces in Al₆(Fe,Mn) particles partially transformed to an α-Al–(Fe,Mn)–Si phase. In contrast, samples rapidly heated to temperature in a fluidised bath show an angular break-up indicative of tensile stresses induced by thermal expansion mismatch between the intermetallic particles and aluminium matrix. Although this break-up should not be industrially significant, the transformation induced break-up by wetting may be. More generally, internal boundaries resulting from the transformation to α-Al–(Fe,Mn)–Si phase may be mechanically weak fracture initiation points during hot rolling.     

Plasticity induced transformation in a metastable β Ti-1023 alloy by controlled heat treatments

Abstract

Investigations into the possibility of improving the strength–ductility relation in a metastable β-titanium alloy (Ti–10V–2Fe–3Al) through plasticity induced transformation (PiTTi) have been carried out. Various heat treatments in the β and/or α+β condition were performed to study their influence on both the microstructure and solute partitioning, which eventually control the PiTTi effect. Stress induced martensite formation promoting such effect has been observed upon compression testing for β and β+(α+β) microstructures. The stress–strain curves exhibiting stress induced martensite show a ～20% increase in strength, while still retaining a reasonable ductility level. Microstructural parameters such as grain size and solute concentration (especially V) in β have been related to the alloy's ability to exhibit PiTTi.     

Effect of Sr on primary α-Fe phase in liquid Al-11.5Si-0.4Mg cast alloy

Abstract

The effect of Sr on the sedimentation of primary α-Fe phase has been investigated at superheating temperatures of 760 and 900 °C. A convection free experimental technique was used to aid in quantifying the primary α-Fe particles sedimented at 600 °C for 4 h. Sr marginally decreases the formed particle weight at normal melting temperature (760 °C), but greatly increases the particle weight at the superheating temperature of 900 °C. Sr refines primary α-Fe particles at both temperatures, causing the increase of the number of primary α-Fe particles, especially when superheated at 900 °C. In addition, Sr causes a decrease in the particle volume fraction but an increase in the number of the sedimented particles, and a great increase in the depth of the sediment in the mould at higher superheating temperatures. These observations are interpreted in terms of the precipitation of Fe rich particles on suspended oxide films, and the rigidisation of suspended films at higher temperatures, possibly as a result of their change in chemistry, but especially as a result of inflation of their doubled-over form by hydrogen, and the effect this has on the multiplication of growing iron rich precipitates as a result of their mechanically unstable substrate.     

Effect of ZnO coating of whiskers on thermal expansion properties of aluminium borate whisker reinforced aluminium composites

Abstract

The pure aluminium composites reinforced by ZnO coated aluminium borate whiskers were fabricated by squeeze casting. The microstructure of the composite was observed using an optical microscope and the thermal expansion behaviours of the composites were investigated in the range from 50 to 400°C. In addition, the effects of heat treatment and thermal cycling on the thermal expansion behaviours of the composite were also investigated. The results show that the coefficient of thermal expansion of as cast composites decreases with the ZnO coating content increasing. However, heat treatment time and thermal cycling lead to an increase in the CTE of the composite.     

Applicable conditions of instantaneous source used for welding heat conduction

Abstract

This paper deals with the sufficient conditions under which instantaneous heat source can be considered as welding heat source instead of moving source. Temperature rises calculated by instantaneous source and moving one were compared. The applicable conditions of the instantaneous heat source with errors of 1% and 5% were found. This enables us to select either moving or instantaneous source with information of welding speed, thermal diffusivity and the distance from the weld centre line to the interested location. Approximate equations to determine the maximum temperature rise using a moving source were proposed and the accuracy of their calculation was proved to be ～99%.     

1st Mediterranean Conference on Heat Treatment and Surface Engineering

Abstract

Energy and the environment are not only receiving mass public attention, but are also indisputably the main drivers for the development of present day scientific, industrial, economic and social progress. However, anyone attempting to review these topics faces two huge problems: the overwhelming volume of often conflicting information and the rapidly evolving national, international and global situation. Thus, the survey presented here, with heat treatment and surface engineering in mind, is a selection of ideas, discussion material and data that is designed to trigger focused discussion and substantive contributions.     

'Quench sensitivity' of 7075 aluminium alloy plates

Abstract

7075 aluminium alloy is widely used especially in those applications for which high mechanical performances are required. In the technical literature it is well known that the corrosion resistance and the mechanical properties of this material strongly depend on the cooling rate during quenching. This phenomenon is known as 'quench sensitivity'. The main aim of this paper is to investigate the influence of the cooling rate during quenching of samples taken from plates by varying the parameters of the heat treatment and the rolling direction (L, LT and ST). All the samples were heat treated in laboratory equipment to reach T6, T76 and T73 tempers. The samples were prisms (13 × 13 × 100 mm) and were quenched in water; the cooling rate was imposed by changing the water temperature or changing the polymer amount in a water agitated bath at 20°C. In each of the experimented condition, the cooling rate was measured by a thermocouple placed in the sample. Moreover, a finite element method (FEM) simulation was carried out in order to estimate the heat transfer coefficient during the cooling in all the experimented conditions. Tensile and intergranular corrosion tests were performed to point out the influence of the investigated cooling rates.