Ca3Co4O9 is a promising p-type thermoelectric oxide material having intrinsically low thermal conductivity. With low cost and opportunities for automatic large scale production, thick film technologies offer considerable potential for a new generation of micro-sized thermoelectric coolers or generators. Here, based on the chemical composition optimized by traditional solid state reaction for bulk samples, we present a viable approach to modulating the electrical transport properties of screen-printed calcium cobaltite thick films through control of the microstructural evolution by optimized heat-treatment. XRD and TEM analysis confirmed the formation of high-quality calcium cobaltite grains. By creating 2.0 at% cobalt deficiency in Ca2.7Bi0.3Co4O9+δ, the pressureless sintered ceramics reached the highest power factor of 98.0 μWm?1 K-2 at 823 K, through enhancement of electrical conductivity by reduction of poorly conducting secondary phases. Subsequently, textured thick films of Ca2.7Bi0.3Co3.92O9+δ were efficiently tailored by controlling the sintering temperature and holding time. Optimized Ca2.7Bi0.3Co3.92O9+δ thick films sintered at 1203 K for 8 h exhibited the maximum power factor of 55.5 μWm?1 K-2 at 673 K through microstructure control. 相似文献
Given the mounting concern about service levels and environmental sustainability, mould industry is facing growing pressure to improve delivery reliability and energy efficiency. While heat-treatment operation is a bottleneck that affects related performances in mould manufacturing. Effective production control of this operation is essential to improve the on-time delivery and reduce the energy consumption of the mould. The operation often involves parallel batch processors and incompatible jobs, which allows for simultaneous processing yet with same job family and different weights and due dates. This paper considers the batch process control of parallel processors for dealing with such non-identical jobs in dynamic environments. An event-driven look-ahead batching strategy called MLAB-DE has been proposed. In MLAB-DE, the individual decisions for each family excluding the effects of these decisions on other families are suggested firstly. Then each alternative decision by including its effects on all families is evaluated. MLAB-DE is used to control two kinds of conflicting objectives related to the delivery and energy performances and finally achieve trade-off based on two-level compromise programming model. Simulation study is conducted to verify the effectiveness of the MLAB-DE strategy and show that the results are promising as compared to benchmark rules. 相似文献
Fe-ZSM-5 zeolites comprise of three types (I, II and III) of iron (Fe3+) sites in both as synthesized (AS) and heat-treated states. Previous evidence could be confirmed by the assignment of ESR lines, registered in the X-band, stating: (i) type I framework Fe3+ sites (in Th oxygen coordination), where charge compensation occurs mainly by Na+ ions and the crystal field (cf) approximates cubic symmetry, produce resonances at near to g = 2.00; (ii) type II and probably type III binuclear Fe...Fe dioxo- and oxo-bridges manifest themselves in producing slightly distorted surroundings of axial symmetry, and the relevant powder-averaged subspectrum is superimposed on the previous one in the g 2.45–1.98 interval. As the temperature of the heat-treatment (HT) is raised, type II and III sites will be annihilated with preference, under concomitant production of amorphous Fe2O3 possessing molecular dispersity. (iii) The weak ESR signal (2–4%) at g 4.27 is attributed to Th coordinated framework sites in the surface layers (≈ 1 u.c. thick) under the influence of solid surface tension, giving rise to fully rhombic cf symmetry.
The size of the ejected Fe2O3 particles, as estimated from Mössbauer spectra (no hyperfine structure at 77 K) is less than 2.9 nm. The extremely large electron affinity of Fe3+ ions manifests itself in decreased ionicity (and unexpectedly dominant cubic symmetry), activity in biomimetic oxidations, autoreduction and spontaneous reoxidation etc.
In the liquid phase oxidation by hydrogen peroxide of n-hexane and cyclohexane the heat-treated Ti-ZSM-5 samples exhibited both activity- and selectivity dependence on HT. On the basis of experiences drawn from the heat-treatments proposal is made for the structures of the defect site (producing the 960 cm−1 IR signal) and the active centre of selective oxidation. The proposal seems to be in accord with the experimental observations (isotopic exchange, MAS-NMR behaviour etc.) published so far. 相似文献
Pt catalyst supported on Vulcan XC-72R containing 5 wt% NiO (Pt/NiO–C) showed larger electrochemical active surface area and higher electrochemical activity for methanol oxidation than Pt catalyst supported on Vulcan XC-72R using polyol method without NiO addition. Prepared Pt/NiO–C electrocatalyst was heat-treated at four temperatures (200, 400, 600, and 800 °C) in flowing N2. X-ray diffraction and temperature-programmed desorption results indicated that NiO was reduced to Ni in inert N2 during heat-treatments at temperatures above or equal to 400 °C, while oxygen from NiO reacted with carbon support due to the catalytic effect of Pt. The reduced Ni formed an alloy with Pt, which, according to the X-ray photoelectron spectroscopy data, resulted in a shift to a lower binding energy of Pt 4f electrons. The Pt/NiO–C electrocatalyst heat-treated at 400 °C showed the best activity in methanol oxidation due to the change in Pt electronic structure by Ni and the minimal aggregation of Pt particles. 相似文献