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1.
Starting from a microscopic Hamiltonian defined on a semi-infinite cubic lattice, and employing a mean-field approximation, the surface parameters relevant for wetting in confined ternary mixtures are derived. These are found in terms of the microscopic coupling constants, and yield a physical interpretation of their origins. In comparison with the standard expression for the surface free-energy density, several new terms arising from the derivation are identified. The influence of the surface parameters on a predicted unbinding transition in a mixture of oil, water, and amphiphile demonstrate that existing results are robust to the addition of the extra surface terms. 相似文献
2.
Consistent calculation of fugacities of fluid mixtures remains as one of the most important subjects in contemporary molecular
thermodynamics. In practice, equations of state (EOSs) and gE-models have been used. However, most EOSs are erroneous for condensed phases at high densities and gE-models are inapplicable for pressuresensitive systems. Recently to remedy the shortcomings in both approaches, there has
been a surge of new gE-EOS mixing rules. By equating any set of EOS and gE-models, the limitations in both approaches could be resolved significantly. However, the self-consistency in the underlying
concept of those mixing rules remains controversial. During the last several years, the present authors proposed a new lattice-fluid
EOS and its simplification relevant to phase equilibrium calculations. Without employing any gE-EOS mixing rule and with only two parameters for a pure component and one adjustable interaction energy parameter for a binary
mixture, results obtained to date demonstrated that the EOSs are quantitatively applicable to a great variety of phase equilibrium
properties of mixtures, especially, for complex and/or macromolecular systems. In the present article we summarize the EOSs
and extended the applications to liquid-liquid Equilibria. In part I, we discussed briefly the molecular thermodynamic aspects
of general derivation of the EOS and a brief discussion of applying the EOSs to pure fluids while the illustrative application
to various real mixture systems is discussed in part II. 相似文献
3.
In order to study water-gas transport processes in the gas-diffusion-layer (GDL) of a proton exchange membrane (PEM) fuel cell system, a multiphase, multiple-relaxation-time lattice Boltzmann model is presented in this work. The model is based on the mean-field diffuse interface theory and can handle the multiphase flows with large density ratios and various viscosities. By using the standard bounce back boundary condition and an approximate average scheme for the non-slip and wetting boundary walls, respectively, detailed liquid-gas transportation in the GDL, in which exact boundary condition is difficult to be implemented, can be simulated. Unlike most of lattice Boltzmann methods based on the Bhatnagar–Gross–Krook collision operator, the present model shows a viscosity-independent velocity field, which is very important in simulating multiphase flows where various viscosities coexist. We validate our model by simulating a static droplet on a wetting wall and compare with theoretical predictions. Then, we simulate a water-gas flow in the GDL of a PEM fuel cell and investigate the saturation-dependent transport properties under different conditions. The results are shown to be qualitatively consistent with the previous numerical and theoretical works. 相似文献
4.
The Gd substituting effects for La in La0.67Ca0.33MnO3 has been studied .With increasing the substituting amount of Gd,the phase transition temperature of metal-isolator for the samples decreases,the corresponding peak resistivity increases,the Curie temperature decreases monotonically.The substitution of La-Ca-Mn-O with 11% Gd for La improved the magnetoresistance ratio by an order of magnitude.The effects of substituting Gd can be explained in terms of the lattice effects.An irreversible MR behaviour was observed in Gd-substituting compounds.This effect became marked when the substituting amount of Gd was greater than 7%.A maximum irreversible increment of MR ratio as large as 91% was obtained when Gd substituting amount was 11%. 相似文献
5.
根据已经发表的实验数据,针对镓铝铟磷发光材料的提出了一组经验公式及相应的曲线,作为GaAlInP可见光材料设计的依据或参考。 相似文献
6.
7.
Vinit D. Makwana L. Javier Garces Jia Liu Jun Cai Young-Chan Son Steven L. Suib 《Catalysis Today》2003,85(2-4):225-233
Manganese oxides having a tunnel structure (OMS-2) have been utilized as selective catalysts for alcohol oxidation. In this study manganese oxide catalysts were synthesized in different media and modified by exchanging the tunnel cation by H+, using acid treatment or exchanging with NH4+ followed by thermolysis. Various alcohol oxidations were performed using these catalysts to ascertain the influence of synthesis method on their activity. A correlation is made between lattice oxygen instability and activity of the catalysts, which indicates involvement of the lattice oxygen in the mechanism. The exchange of the tunnel cation with the smaller H+ ions leads to weakening of the Mn–O bond, as verified by temperature programmed desorption (TPD) results. Only the chemisorbed oxygen on the surface (O−) and the lattice oxygen in the layers close to the surface is involved in the oxygen transfer during the reaction. 相似文献
8.
M. Kemiha 《Chemical engineering science》2006,61(12):4041-4047
The present work aims at understanding the behavior of individual bubbles in non-Newtonian fluids. By means of a Particle Image Velocimetry (PIV) device, the complete flow field around either a single non-spherical bubble rising in polyacrylamide (PAAm) solutions or a solid sphere settling down in the same fluids shows for the first time the similar coexistence of three distinct zones: a central downward flow behind the bubble or the sphere (negative wake), a conical upward flow surrounding the negative wake zone, and an upward flow zone in front of the bubble or the sphere. This excludes then the possible influence of the interface deformation on the negative wake. A theoretical lattice Boltzmann scheme coupled to a sixth-order Maxwell model was developed for computing the complex flow field around a solid sphere. The good agreement with the experimental measurements provides evidence that the physical mechanism responsible for the negative wake in such fluids could be related to the fluid's viscoelastic properties. 相似文献
9.
We constructed a probabilistic simulator that allows all the events in population dynamics such as death, birth, mutation,
and suppression/stimulation to be described by probabilistic rules. The simulator also facilitates a lattice used for expressing
distribution and diversity (number of distinct strains) of quasispecies. The simulator is used to investigate the diversity
threshold in HIV and T-cell interaction.
This work was presented in part at the 13th International Symposium on Artificial Life and Robotics, Oita, Japan, January
31–February 2, 2008 相似文献
10.
秀卢瑟福背散射-沟道技术(RBS-C)和X射线衍射技术(XRD)研究了Pt和注入YSZ(Y2O3稳定的ZrO2)后产生的损伤和退火过程中损伤的恢复及注入Pt的晶化,RBS-C分析表明YSZ室温下的存在较强自退火效应,XRD分析结果示出硫以铂的晶化产生很大影响。 相似文献